EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Question
Chapter 13, Problem 13.48P
Interpretation Introduction
(a)
Interpretation:
The structure of muscalure must be drawn with the correct geometry around the double bond.
Concept introduction:
cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.
Interpretation Introduction
(b)
Interpretation:
The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.
Concept introduction:
cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 13 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2PCh. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4PCh. 13.2 - Prob. 13.5PCh. 13.2 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.3 - Prob. 13.9PCh. 13.3 - Prob. 13.10P
Ch. 13.3 - Prob. 13.11PCh. 13.3 - Prob. 13.12PCh. 13.3 - Prob. 13.13PCh. 13.4 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.6 - Prob. 13.17PCh. 13.6 - Prob. 13.18PCh. 13.6 - Prob. 13.19PCh. 13.7 - Prob. 13.20PCh. 13.8 - Prob. 13.21PCh. 13.8 - Prob. 13.22PCh. 13.10 - Give the IUPAC name of each compound.
Ch. 13.10 - Prob. 13.24PCh. 13.11 - Prob. 13.25PCh. 13.12 - Prob. 13.26PCh. 13.13 - Prob. 13.27PCh. 13.13 - Prob. 13.28PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 13.30PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 13.32PCh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Prob. 13.36PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.44PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 13.51PCh. 13 - Prob. 13.52PCh. 13 - Prob. 13.53PCh. 13 - Prob. 13.54PCh. 13 - Prob. 13.55PCh. 13 - Prob. 13.56PCh. 13 - Prob. 13.57PCh. 13 - Prob. 13.58PCh. 13 - Prob. 13.59PCh. 13 - Prob. 13.60PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 13.62PCh. 13 - Prob. 13.63PCh. 13 - Prob. 13.64PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 13.66PCh. 13 - Prob. 13.67PCh. 13 - Prob. 13.68PCh. 13 - Prob. 13.69PCh. 13 - Prob. 13.70PCh. 13 - Prob. 13.71PCh. 13 - Prob. 13.72PCh. 13 - Prob. 13.73PCh. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76PCh. 13 - Prob. 13.77PCh. 13 - Prob. 13.78PCh. 13 - Prob. 13.79PCh. 13 - Prob. 13.80PCh. 13 - Prob. 13.81PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.85PCh. 13 - Prob. 13.86PCh. 13 - Prob. 13.87PCh. 13 - Prob. 13.88PCh. 13 - Prob. 13.89PCh. 13 - Prob. 13.90PCh. 13 - Prob. 13.91PCh. 13 - Prob. 13.92PCh. 13 - Prob. 13.93PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 13.95PCh. 13 - Prob. 13.96PCh. 13 - Prob. 13.97PCh. 13 - Prob. 13.98PCh. 13 - Prob. 13.99PCh. 13 - Prob. 13.100PCh. 13 - Prob. 13.101PCh. 13 - Prob. 13.102PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 13.104PCh. 13 - Prob. 13.105PCh. 13 - Prob. 13.106PCh. 13 - Prob. 13.107CPCh. 13 - Prob. 13.108CP
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