Chapter 13, Problem 13.62P

Interpretation Introduction

(a)

Interpretation:

The product formed should be determined on the reaction of following alkene with ${\text{H}}_{\text{2}}\text{O}$ in the presence of ${\text{H}}_{\text{2}}{\text{SO}}_{\text{4}}$ :

Concept Introduction:

A chemical reaction is the symbolic representation of the conversion of substances to new substances.

  $\begin{array}{l}\text{ A + B }\stackrel{}{\to }\text{ C}\\ \text{Reactant }\stackrel{}{\to }\text{ Product}\end{array}$

In a chemical reaction, the substance which is involved in conversion is said to be reactant, whereas, the newly formed substance is known as a product. Both reactants and products must be separated by an arrow.

Hydration reaction is an addition reaction in which the hydrogen and hydroxyl group (-OH) are bonded on un-statured carbon atoms of alkene to form alcohol.

Answer to Problem 13.62P

Explanation of Solution

To get the hydration product of any alkene, three steps must be followed:

• Locate the position of C=C in the molecule.
• Break the H-OH bond of the reagent.
• Add the -OH group atom to double-bonded C atom to form new C−OH single bonds in the molecule.
• Add one H atom to another double-bonded C atom to form new C−H single bonds in the molecule.
• The reaction follows the Markovnikov rule which states that the H atom of H-OH will bond to that double-bonded C atom which has more number of H atoms.

Hence, the hydration product is:

.

Interpretation Introduction

(b)

Interpretation:

The product formed should be determined on the reaction of following alkene with ${\text{H}}_{\text{2}}\text{O}$ in the presence of ${\text{H}}_{\text{2}}{\text{SO}}_{\text{4}}$ :

(CH₃)₃ -C =C -(CH₃)₂

Concept Introduction:

A chemical reaction is the symbolic representation of the conversion of substances to new substances.

  $\begin{array}{l}\text{ A + B }\stackrel{}{\to }\text{ C}\\ \text{Reactant }\stackrel{}{\to }\text{ Product}\end{array}$

In a chemical reaction, the substance which is involved in conversion is said to be reactant, whereas, the newly formed substance is known as a product. Both reactants and products must be separated by an arrow.

Hydration reaction is an addition reaction in which the hydrogen and hydroxyl group (-OH) are bonded on un-statured carbon atoms of alkene to form alcohol.

Answer to Problem 13.62P

Explanation of Solution

To get the hydration product of any alkene, three steps must be followed;

• Locate the position of C=C in the molecule.
• Break the H-OH bond of the reagent.
• Add the -OH group atom to double-bonded C atom to form new C−OH single bonds in the molecule.
• Add one H atom to another double-bonded C atom to form new C−H single bonds in the molecule.
• The reaction follows the Markovnikov rule which states that the H atom of H-OH will bond to that double-bonded C atom which has more number of H atoms.

Hence, the hydration product is:

Interpretation Introduction

(c)

Interpretation:

The product formed should be determined on the reaction of following alkene with ${\text{H}}_{\text{2}}\text{O}$ in the presence of ${\text{H}}_{\text{2}}{\text{SO}}_{\text{4}}$ :

Concept Introduction:

A chemical reaction is the symbolic representation of the conversion of substances to new substances.

  $\begin{array}{l}\text{ A + B }\stackrel{}{\to }\text{ C}\\ \text{Reactant }\stackrel{}{\to }\text{ Product}\end{array}$

In a chemical reaction, the substance which is involved in conversion is said to be reactant, whereas, the newly formed substance is known as a product. Both reactants and products must be separated by an arrow.

Hydration reaction is an addition reaction in which the hydrogen and hydroxyl group (-OH) are bonded on un-statured carbon atoms of alkene to form alcohol.

Answer to Problem 13.62P

Explanation of Solution

To get the hydration product of any alkene, three steps must be followed;

• Locate the position of C=C in the molecule.
• Break the H-OH bond of the reagent.
• Add the -OH group atom to double-bonded C atom to form new C−OH single bonds in the molecule.
• Add one H atom to another double-bonded C atom to form new C−H single bonds in the molecule.
• The reaction follows the Markovnikov rule which states that the H atom of H-OH will bond to that double-bonded C atom which has more number of H atoms.

Hence, the hydration product is:

Interpretation Introduction

(d)

Interpretation:

The product formed should be determined on the reaction of following alkene with ${\text{H}}_{\text{2}}\text{O}$ in the presence of ${\text{H}}_{\text{2}}{\text{SO}}_{\text{4}}$ :

Concept Introduction:

A chemical reaction is the symbolic representation of the conversion of substances to new substances.

  $\begin{array}{l}\text{ A + B }\stackrel{}{\to }\text{ C}\\ \text{Reactant }\stackrel{}{\to }\text{ Product}\end{array}$

In a chemical reaction, the substance which is involved in conversion is said to be reactant, whereas, the newly formed substance is known as a product. Both reactants and products must be separated by an arrow.

Hydration reaction is an addition reaction in which the hydrogen and hydroxyl group (-OH) are bonded on un-statured carbon atoms of alkene to form alcohol.

Answer to Problem 13.62P

Explanation of Solution

To get the hydration product of any alkene, three steps must be followed;

• Locate the position of C=C in the molecule.
• Break the H-OH bond of the reagent.
• Add the -OH group atom to double-bonded C atom to form new C−OH single bonds in the molecule.
• Add one H atom to another double-bonded C atom to form new C−H single bonds in the molecule.
• The reaction follows the Markovnikov rule which states that the H atom of H-OH will bond to that double-bonded C atom which has more number of H atoms.

Hence the hydration product is: