(a) Interpretation: The name of the aromatic compound given below needs to be deduced: Concept Introduction: Aromatic compounds are predominantly characterized by the presence of a benzene (C 6 H 6 )ring The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH 3 which gives toluene), amino (-NH 2 which forms aniline), hydroxyl (-OH which forms phenol) and so on. If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

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Answer 1

Question

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

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4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeak

None

3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

Answer 2

Question

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

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Answer 3

Question

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

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Answer 4

Question

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

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Answer 5

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 6

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 7

Chapter 13, Problem 13.79P

Interpretation Introduction

(a)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl (-CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The name of the aromatic compound given below needs to be deduced:

Concept Introduction:

Aromatic compounds are predominantly characterized by the presence of a benzene (C₆H₆)ring
The parent ring can be identified based on the principal functional groups attached to the carbon atoms in the ring. These groups could be methyl ( -CH₃ which gives toluene), amino (-NH₂ which forms aniline), hydroxyl (-OH which forms phenol) and so on.
If two or more substituents are present in the ring, the substituents are named in an alphabetical order and the ring is numbered such that the first substituent gets the lowest number order.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4P Ch. 13.2 - Prob. 13.5P Ch. 13.2 - Prob. 13.6P Ch. 13.3 - Prob. 13.7P Ch. 13.3 - Prob. 13.8P Ch. 13.3 - Prob. 13.9P Ch. 13.3 - Prob. 13.10P

Solution Summary: The author explains that aromatic compounds are predominantly characterized by the presence of a benzene (C 6 H 6 )ring.

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