Concept explainers
(a)
Interpretation: The molecular structure and at least two different possible structures with same central atom of
Concept Introduction:
Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.
The sum of valence electrons must be arranged in such a way that all atoms must get octet configuration (8 electrons).
(b)
Interpretation: The molecular structure and at least two different possible structures with same central atom of
Concept Introduction:
Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.
The sum of valence electrons must be arranged in such a way that all atoms must get octet configuration (8 electrons).
(c)
Interpretation: The molecular structure and at least two different possible structures with same central atom of
Concept Introduction:
Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.
The sum of valence electrons must be arranged in such a way that all atoms must get octet configuration (8 electrons).
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EBK CHEMICAL PRINCIPLES
- Describe the molecular structure around the indicated atom or atoms: (a) the sulfur atom in sulfuric acid, H2SO4[(HO)2SO2] (b) the chlorine atom in chloric acid, HClO3[HOClO2] (c) the oxygen atom in hydrogen peroxide, HNO3[HONO2] (d) the nitrogen atom in nitric acid, HNO3[HONO2] (e) the oxygen atom in the OH group in nitric acid, HNO3[HONO2] (f) the central oxygen atom in the ozone molecule, O3 (g) each of the carbon atoms in propyne, CH3CCH (h) the carbon atom in Freon, CCl2F2 (i) each of the carbon atoms in aliene, H2CCH2arrow_forwardUsing the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in CS2.arrow_forwardUsing the standard enthalpy of formation data in Appendix G, show how the standard enthalpy of formation of HCl(g) can be used to determine the bond energy.arrow_forward
- In Section 12.10 of your text, the term “effective pairs" is used. What does this mean?arrow_forwarda. How many sticks did you need to make the skeleton structure?____________ b. How many sticks are left over? ____________ If your model is to obey the octet rule, each ball must have four sticks in it except for hydrogen atom balls, which need and can only have one. Each atom in an octet rule species is surrounded by four pairs of electrons. c. How many holes remain to be filled? ____________ Fill them with the remaining sticks, which represent nonbonding electron pairs. Draw the complete Lewis structure for NH2Cl using lines for bonds and pairs of dots for nonbonding electrons.arrow_forwardConsider the molecular structures illustrated in the previous exercise. For each structure, give an example compound that has that arrangement of atoms.arrow_forward
- A common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called methyl cyanoacrylate, the main ingredient in Super Glue. Draw a complete Lewis structure for methyl cyanoacrylate in which all atoms have a formal charge of zero.arrow_forwardescribe the type of bonding that exists in the Cl2(g)molecule. How does this type of bonding differ from that found in the HCl(g)molecule? How is it similar?arrow_forwardHow does the bond energy of HCl(g) differ from the standard enthalpy of formation of HCl(g)?arrow_forward
- For three simple molecules of your own choice, apply the rules for writing Lewis structures. Write your discussion as if you are explaining the method to someone who is not familiar with Lewis structures.arrow_forwardrite the Lewis structure for each of the following atoms. msp;a.He(Z=2)d.Ne(Z=10)b.Br(Z=35)e.I(Z=53)c.Sr(Z=38)f.Ra(Z=88)arrow_forwardCompare your answers from parts a and b of Exercise 69 of Chapter 3 with H values calculated for each reaction using standard enthalpies of formation in Appendix 4. Do enthalpy changes calculated from bond energies give a reasonable estimate of the actual values?arrow_forward
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