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- Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.What is the bond order for the lowest excited state of H2+ ? From this single result, propose a general statement about unstable diatomic molecules and bond orders.Use molecular orbital arguments to decide whether or not the difluoride dianion, F22, should exist as a stable ion.
- 11. What is Electromagnetic radiation? 12. What are the conditions for a molecule to be Raman active?Identify the group to which the naphthalene molecule belongs and locate the symmetry elements in a drawing of the molecule.The BF3 molecule belongs to the point group D3h. List the symmetry elements of the group and locate them in a drawing of the molecule.
- The ClO2 molecule (which belongs to the group C2v) was trapped in a solid. Its ground state is known to be B1. Light polarized parallel to the y-axis (parallel to the OO separation) excited the molecule to an upper state. What is the symmetry species of that state?4) The structure of triphenylene is shown below. If the molecule lies in the xy plane, determine the representation of all of the 2p, orbitals in a minimal basis set.Use symmetry properties to determine whether or not the integral ∫pxzpzdτ is necessarily zero in a molecule with symmetry D3h.

