(a)
Interpretation:
Degree of freedom for
Concept Introduction:
The Gibbs phase rule provides the relation between number of chemically independent component and the number of independent phases for a given system. When temperature and pressure of the system can be changed, it is defined as:
Here,
Answer to Problem 10.41P
For temperature
For temperature
Explanation of Solution
The phase diagram given for the Tl-Pb solution is given as:
For
For the given system, the pressure is assumed to be constant. Thus, the formula used to calculate degree of freedom is:
For temperature
Apply equation (1) and calculate degree of freedom as:
For temperature
Apply equation (1) and calculate degree of freedom as:
(b)
Interpretation:
Degree of freedom for
Concept Introduction:
The Gibbs phase rule provides the relation between number of chemically independent component and the number of independent phases for a given system. When temperature and pressure of the system can be changed, it is defined as:
Here,
Answer to Problem 10.41P
For temperature
For temperature
Explanation of Solution
The phase diagram given for the Tl-Pb solution is given as:
For
For the given system, the pressure is assumed to be constant. Thus, the formula used to calculate degree of freedom is:
For temperature
Apply equation (1) and calculate degree of freedom as:
For temperature
Apply equation (1) and calculate degree of freedom as:
(c)
Interpretation:
Degree of freedom for
Concept Introduction:
The Gibbs phase rule provides the relation between number of chemically independent component and the number of independent phases for a given system. When temperature and pressure of the system can be changed, it is defined as:
Here,
Answer to Problem 10.41P
For temperature
For temperature
Explanation of Solution
The phase diagram given for the Tl-Pb solution is given as:
For
For the given system, the pressure is assumed to be constant. Thus, the formula used to calculate degree of freedom is:
For temperature
Apply equation (1) and calculate degree of freedom as:
For temperature
Apply equation (1) and calculate degree of freedom as:
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