Essentials Of Materials Science And Engineering
Essentials Of Materials Science And Engineering
4th Edition
ISBN: 9781337670845
Author: ASKELAND
Publisher: Cengage
Question
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Chapter 10, Problem 10.44P
Interpretation Introduction

(a)

Interpretation:

The liquidus temperature, solidus temperature, and freezing range for NiO- 30 mol% MgO ceramic composition are to be determined.

Concept Introduction:

On the temperature-composition graph of an alloy, the curve above which the alloy exist in the liquid phase is the liquidus curve. The temperature at this curve is maximum known as liquidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Solidus curve is the locus of the temperature on the temperature composition graph of an alloy, beyond which the alloy is completely in solid phase. The temperature at this curve is minimum known as solidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Freezing range for an alloy is the difference of the liquidus and the solidus temperature of an alloy. In this range, the alloy melt starts to crystallize at liquidus temperature and solidifies when reaches solidus temperature.

Expert Solution
Check Mark

Answer to Problem 10.44P

Liquidus temperature, TL=2350C

Solidus temperature, TS=2160C

Freezing range, FR=190C

Explanation of Solution

The equilibrium phase diagram for the NiO-MgO system is shown below as:

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  1

For NiO- 30 mol% MgO, the straight line from 30 mol% is drawn as shown. Liquidus temperature (TL) is represented by point 'a' where the line touches the upper curve. Solidus temperature (TS) is represented by point 'b' where the line touches the lower curve.

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  2

  TL=2350CTS=2160C

The freezing range (FR) for this ceramic composition will be:

  FR=TLTS=23502160=190C

Interpretation Introduction

(b)

Interpretation:

The liquidus temperature, solidus temperature, and freezing range for NiO- 45 mol% MgO ceramic composition are to be determined.

Concept Introduction:

On the temperature-composition graph of an alloy, the curve above which the alloy exist in the liquid phase is the liquidus curve. The temperature at this curve is maximum known as liquidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Solidus curve is the locus of the temperature on the temperature composition graph of an alloy, beyond which the alloy is completely in solid phase. The temperature at this curve is minimum known as solidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Freezing range for an alloy is the difference of the liquidus and the solidus temperature of an alloy. In this range, the alloy melt starts to crystallize at liquidus temperature and solidifies when reaches solidus temperature.

Expert Solution
Check Mark

Answer to Problem 10.44P

Liquidus temperature, TL=2460C

Solidus temperature, TS=2250C

Freezing range, FR=210C

Explanation of Solution

The equilibrium phase diagram for the NiO-MgO system is shown below as:

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  3

For NiO- 45 mol% MgO, the straight line from 45 mol% is drawn as shown. Liquidus temperature (TL) is represented by point 'a' where the line touches the upper curve. Solidus temperature (TS) is represented by point 'b' where the line touches the lower curve.

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  4

  TL=2460CTS=2250C

The freezing range (FR) for this ceramic composition will be:

  FR=TLTS=24602250=210C

Interpretation Introduction

(c)

Interpretation:

The liquidus temperature, solidus temperature, and freezing range for NiO- 60 mol% MgO ceramic composition are to be determined.

Concept Introduction:

On the temperature-composition graph of an alloy, the curve above which the alloy exist in the liquid phase is the liquidus curve. The temperature at this curve is maximum known as liquidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Solidus curve is the locus of the temperature on the temperature composition graph of an alloy, beyond which the alloy is completely in solid phase. The temperature at this curve is minimum known as solidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Freezing range for an alloy is the difference of the liquidus and the solidus temperature of an alloy. In this range, the alloy melt starts to crystallize at liquidus temperature and solidifies when reaches solidus temperature.

Expert Solution
Check Mark

Answer to Problem 10.44P

Liquidus temperature, TL=2590C

Solidus temperature, TS=2380C

Freezing range, FR=210C

Explanation of Solution

The equilibrium phase diagram for the NiO-MgO system is shown below as:

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  5

For NiO- 60 mol% MgO, the straight line from 60 mol% is drawn as shown. Liquidus temperature (TL) is represented by point 'a' where the line touches the upper curve. Solidus temperature (TS) is represented by point 'b' where the line touches the lower curve.

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  6

  TL=2590CTS=2380C

The freezing range (FR) for this ceramic composition will be:

  FR=TLTS=25902380=210C

Interpretation Introduction

(d)

Interpretation:

The liquidus temperature, solidus temperature, and freezing range for NiO- 85 mol% MgO ceramic composition are to be determined.

Concept Introduction:

On the temperature-composition graph of an alloy, the curve above which the alloy exist in the liquid phase is the liquidus curve. The temperature at this curve is maximum known as liquidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Solidus curve is the locus of the temperature on the temperature composition graph of an alloy, beyond which the alloy is completely in solid phase. The temperature at this curve is minimum known as solidus temperature at which the crystals in the alloy can coexist with its melt in the thermodynamic equilibrium.

Freezing range for an alloy is the difference of the liquidus and the solidus temperature of an alloy. In this range, the alloy melt starts to crystallize at liquidus temperature and solidifies when reaches solidus temperature.

Expert Solution
Check Mark

Answer to Problem 10.44P

Liquidus temperature, TL=2740C

Solidus temperature, TS=2620C

Freezing range, FR=120C

Explanation of Solution

The equilibrium phase diagram for the NiO-MgO system is shown below as:

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  7

For NiO- 85 mol% MgO, the straight line from 85 mol% is drawn as shown. Liquidus temperature (TL) is represented by point 'a' where the line touches the upper curve. Solidus temperature (TS) is represented by point 'b' where the line touches the lower curve.

Essentials Of Materials Science And Engineering, Chapter 10, Problem 10.44P , additional homework tip  8

  TL=2740CTS=2620C

The freezing range (FR) for this ceramic composition will be:

  FR=TLTS=27402620=120C

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Chapter 10 Solutions

Essentials Of Materials Science And Engineering

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