O-0005 Safety_ CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I_II_2
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O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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O-0005 Safety
Due
No due date
Points
14
Questions
14
Available
Sep 5 at 12a.m. - Dec 6 at 11:59p.m.
Time Limit
30 Minutes
Allowed Attempts
Unlimited
Instructions
Attempt History
Attempt
Time
Score
KEPT
Attempt 2
6 minutes
13.38 out of 14
LATEST
Attempt 2
6 minutes
13.38 out of 14
Attempt 1
9 minutes
8 out of 14
Correct answers are hidden.
Score for this attempt:
13.38
out of 14
Submitted Oct 22 at 11:50p.m.
This attempt took 6 minutes.
Provide the correct answer to each of the following safety questions. You answer correctly to 80% of the
questions of this quiz in order to perform the experiment in the organic laboratory.
Take the Quiz Again
1 / 1 pts
Question 1
You want to start your reaction, but you realize that the stirplate is not
working. What is the fits thing you should do?
Call the laboratory technicial and ask them to check all the plates in the lab.
Call the lab director and ask them to look into the problem.
10/22/23, 11:50 PM
O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Call 911
Call your TA and ask them to solve the problem.
Check if it is plugged into the wall socket.
1 / 1 pts
Question 2
The heating source (Thermowell, heating mantle, oil bath) must
NEVER
be
directly plugged into the wall socket. It should be plugged into a power
regulator, and the regulator in turn should be plugged into the wall socket.
True
False
1 / 1 pts
Question 3
When assembling a reflux condenser, the tubing should be connected such
that the water flows against gravity.
True
10/22/23, 11:50 PM
O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
https://canvas.ubc.ca/courses/122851/quizzes/652167
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False
Yes! This is correct.
Make sure you keep the water flow against gravity.
1 / 1 pts
Question 4
What would you use to monitor the temperature of your oil bath when the
procedure calls for a careful control of the reaction temperature?
The lab instructor's thermic vision
Digital thermometer
Mercury thermometer
The palm of your hand to feel the heat irradiated from the bath
1 / 1 pts
Question 5
Match the laboratoy equipment or glassware with their correct name.
a.
Reflux condenser
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b.
Stir plate
c.
Round bottom flask
d.
Lab jack
e.
Three prong clamp
1 / 1 pts
Question 6
What type of glassware/piece of equipment would you use to add a solid
reactant to a round bottom flask to prevent the solid to contaminate the walls
of the glass joint?
Büchner funnel
Glass funnel
Hirsch funnel
Plastic solids' funnel
1 / 1 pts
Question 7
Where should you dispose of the drying agent (Na
SO
or MgSO
) once you
have finished the extraction/drying process?
2
4
4
In the halogenated waste in the waste fumehood.
The solid waste containter in the waste fumehood.
10/22/23, 11:50 PM
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In the non-halogenated waste in the waste fumehood.
In the trash can at the end of the bench.
1 / 1 pts
Question 8
Where should you dispose of the discarded aqueous layers collected after
any separation or extraction?
Halogenated waste in fumehood area
Non-halogenated waste in fumehood area
Solid waste in fumehood area
Down the drain with lots of cold running water.
1 / 1 pts
Question 9
If you spill 100 mL DCM on your bench, the best course of action is:
To call 911 and evacuate the lab as DCM is extremely dangerous
No action is necessary, it will evaporate quickly on its own
To use paper towels to absorb as much as possible and leave it in the fume
hood to dry
To move away all heat sources as DCM is flammable and then let it evaporate
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1 / 1 pts
Question 10
A student forgot to add 3M HCl at the end of the reaction. What problem can
this lead to?
Unreacted sodium borohydride can reduce the nitro group
Some product will remain deprotonated and stay in the aqueous layer
Aldol reaction can occur under basic conditions
Some borohydride will not be quenched and can be extracted into DCM
1 / 1 pts
Question 11
A student added too much 3M HCl to their reaction mixture at the end of the
reaction. What problem can this lead to?
The amino group can get protonated, rendering the product water-soluble
The product will decompose under strong acidic conditions
The nitro group can be reduced under acidic conditions
Too much hydrogen will be generated from unreacted borohydride, which is a
safety issue
1 / 1 pts
Question 12
What is the maximum volume of solution that can be concentrated in a 100
mL round bottom flask (RBF) on the rotary evaporator?
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10 mL at a time.
50 mL
25 mL
Any volume, it does not make a difference.
100 mL
0.38 / 1 pts
Question 13
Partial
Partial
One of the most common procedures in organic synthesis is the removal of
solvent at reduced pressure using a rotary evaporator.
Correctly match the steps to the order in which they should be done to safely
perform the rotary evaporation in the lab.
e.g.
Step 1. Connect the round bottom flask to the rotovap trap and hold it in
place.
Step 2...
Sep 6. Look at the condenser and look for the point where no more solvent
is dripping.
Setp 7...
Step 11. Disconnect the RBF from the rotary evaporator.
Step 2.
Connect the vaccum tub
Step 3.
Move the red lever to a
Step 4.
Start the rotation.
Step 5.
10/22/23, 11:50 PM
O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Lower the RBF into the w
Step 7.
Stop the rotation.
Step 8.
Move the red lever to a v
Step 9.
Hold your RBF with you
Step 10.
Remove the RBF from t
1 / 1 pts
Question 14
In organic chemistry, rotary evaporation is used to remove organic solvents
under reduced pressure. You can do so in one go or in several iterations.
Between iterations, it does not matter if there's a little solvent left in the flask,
it can be removed on the next iteration. Only when you are "rotovapping"
your last batch you want to ensure no solvent (or only traces) are left.
How would you ensure that all the solvent has been removed from your flask
in the last instance of your rotary evaporation?
Add drying agent to the flast to ensure no water is present in the sample
After the solvent has stopped dripping on the condenser, wait 50 min. before
you disconnect the flask from the rotovap.
After the solvent has stopped dripping on the condenser, wait 5 min. before
you disconnect the flask from the rotovap.
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Let the flask sit on the bench top for 30 min. so any solvent evaporates on its
own
Quiz Score:
13.38
out of 14
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The enolate of a ketone can be treated with an ester to give a diketone. Drawa mechanism for this Claisen-like reaction and explain
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.1. Refer to the table of standard reduction potentials.
Standard Reduction Potentials at 25 C
Reduction Half-Reaction
(V)
FAg + 2 €
H2O{aq) + 2 H*(aq)+ 2 6
Mno,taq) + 8 H*(aq) + 5 &
Clalg) + 2 e
CrOFMaq)+ 14 H*(aq) + 6 6-
Ozlg + 4 H*(aq) + 4 &
Bra() + 26
Ag*(aq) + e
Fe*(aq) + e
Ozl9) + 2 H'(aq) + 2 €
2(s)+ 26
Ozlg) + 2 HO) + 46
Cu (aq) + 2 €
Sn" (ag)+ 2 6
2 P(aq)
2 H2O()
→ Mn(aq) + 4 H;0()
→2 cr(aq)
2 Cr (aq)+ 7 H0()
→2 HO()
2 Br(aq)
Ag(s)
» Fe*(aq)
→H;Oz(aq)
→2 F(aq)
→4 OH"(aq)
2.87
1.78
1.51
1.36
1.33
3.
1.23
1.09
0.80
0.77…
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6 1
III |
.5.
For a reaction in which E° = -0.100 V and n = 1 mol electrons / mol, calculate AG°. State
+
your assumptions, if any, about temperature.
.6.
For a reaction in which E° = 0.100 V andn = 1 mol electrons / mol, calculate AG° at 25°C.
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MnO, (aq) + 8H*(aq) + 5e → Mn²*(aq) + 4 H,O(1)
Al(s) → Alš*(aq) + 3 e
+
.ЗА.
Assign oxidation numbers to all metals whether they be elemental, monatomic ion, or in
a polyatomic ion, in questions (1) and (2),
.3B. Tell what is being oxidized and what is being reduced in each reaction in questions (1) and
(2).
.3C. Identify each half-reaction in question (2) as oxidation half-reaction or reduction
half-reaction.
.4. Do you need to know the temperature to calculate AG° from E°? Explain.
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A.) 0.193 s
B.) 64.4 s
C.) 129 s
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An unknown solid substance is heated according to the temperature versus time graph below.
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- es-2021S2 Allison.E CHEM X 2.ga.us/d21/Ims/quizzing/user/attempt/quiz_start_frame_auto.d2l?ou=2593077&isprv=&drc%3D1&qi=2478023&cfql=0&dnb%3D08fi lancer O Khan Academy E DeltaMath musictheory.net - E. Ca Desmos | Scientific. g Final Exam Ciara Smith: Attempt 1 D View hint for Question 18 Question 19 (3 points) Explain how OCompound A and Compound B will dissolve in water using the correct vocabulary including solvation, dissociatic n, ionic, and covalent. O Mg Cl CH Compound A Compound B hp 二arrow_forwardBb Take Test: QUI A Ims.uhb.edu.sa/webapps/assessment/take/take.jsp?cours... لا تعيد السمكات إلى ا. . . الاثاد M Gmail O YouTube Human Biology Ch... A Apps Remaining Time: 15 minutes, 04 seconds. * Question Completion Status: 0.5 points Saved Question 6 Find the major product of following dehydration. OH CH3 CH,-CH-CH-CH2-CH3 + H20 CH3 OA CH2=CH-ĊH-CH2-CH3 OCH3 O B. CH3-C=c-CH2-CH3 OC. CH3-C-CH,- -CH2-CH2-CH3 O CH3 OD. CH3-C-CH-CH2-CH3 CH3 CH3-CH=C-CH2-CH3 » A Moving to another question will save this response. Question 6 of 10> .w. MacEarrow_forward11:15 .l .l 5.00 KB/S A O (12 4 app.teachermade.com/fill/13c37t (4) C Q Q T TI 4 v Save for Later I'm Done A. John Dalton was an English chemist. His Dalton's Atomic Theory ideas form the atomic theory of matter. Here are his ideas. • All elements are composed (made up) of atoms. It is impossible to divide or destroy an atom. • All atoms of the same elements are alike. (One Atoms of element X Atoms of ement Y Compound of elemeite XandY atom of oxygenis like another atom of oxygen.) • Atoms of different elements are different. (An atom of oxygen is different from an atom of hydrogen.) • Atoms of different elements combine to form a compound. These atoms have to be in definite whole number ratios. For example, water is a compound made up of 2 atoms of 1. What is the name of John Dalton's theory? 2. What are elements made of? 3. An atom of hydrogen and an atom of carbon are 4. What are compounds made of? 5. The ratio of atoms in HCI is: Atomic Structure J. J. Thomson was an English…arrow_forward
- 4. For each example below, draw at least one possible isomer that is consistent with the molecular formula and the associated IR spectrum. a. MW 82, C6H10 80 60- 40- 20- 4000 b. MW 116, C6H12O2 80- 60- 20- 3500 4000 3500 9262 2943 3000 2837 2500 2000 2000 -9044 1653 1500 1468 1500 1437 1373 5221 6677 1080 1000 719 640arrow_forward00:40 A < 50 8 allall 85% Due Date for Submission: Friday, 25th October @ 4:06 PM UNIVERSITY OF PAPUA NEW GUINEA SCHOOL OF NATURAL AND PHYSICAL SCIENCES CHEMISTRY DISCIPLINE 1.10203 Chemistry 1B - Assignment No. 3 Please note that all assignments must be submitted in handwritten form; printed submissions will not be accepted. Additionally, ensure that you submit your work directly to your assigned tutor. Failure to do so will result in a zero mark. This process has been streamlined to prevent misplaced assignments and to avoid complaints at the end of the semester. If you have submitted your work to the wrong tutor, retrieve it and submit it to the correct one to avoid any penalties or issues later on. Name: ID#: 1. Study the following reactions and draw their reaction mechanisms A (a) (b) Edit < CH3CH2CH2CI AICI 3 CH2CH2CH3 CH3CH2CCI AICI3 Ова CH2CH3 Group:, H CH3 CH3 Score: Page 1 of 6 Annotate Fill & Sign Convert All Oarrow_forward4,6,7,8) Question 19 of 20 (5 points) Question Attempt: 1 of 1 Time Remaining: 30:47 Hannah 10 = 11 = 12 =13 =14 =15 = 16 17 18 19 20 Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced. (You can edit both sides of the equation to balance it, if you need to.) do Note: you are writing the molecular, and not the net ionic equation. - CaBr, (aq) + H,O(1) Submit Assignment Continue Accessibility Privacy Center 2021 McGraw Hill LLC All Rights Reserved. Terms of Use IIarrow_forward
- 1-arr In a study of the gas phase decomposition of phosphine at 120 °C PH3(g)- →1/4 P4(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.50×10² s1 and a y-intercept of -3.24. Based on this plot, the reaction i v O order in PH, and the half life for the reaction is seconds. zero first secondarrow_forwardAb GL B art 3 SHOW WORK ond Shipp: Attempt 1 Hu/d21/Ims/quizzing/user/attempt/quiz_start_frame_auto.d2l?ou=5956136&isprv=&drc=0&qi=5726766&cfql= Answer units ▷ Add attachments to support your work Question 4 (0.5 points) SHOW YOUR WORK. G **N*-*OO If 35.45 mL of 0.8121 M sodium carbonate solution reacts with excess lead (III) nitrate solution to form aqueous sodium nitrate and solid lead (III) carbonate, how many grams of lead (III) carbonate is formed? On your paper with your name and date: 1. Go from ionic compound name to formula (review Chp 5 as much as needed) 2. Balance the equation (review Chp 7 if needed). 3. Do the calculation showing ALL units, just like I did in solution stoichiometry lecture. a #arrow_forward2. An 84 kg University of Toledo groundskeeper who is spraying a 100 mg/L solution of the insecticide dieldrin (MW = 381; logP = 4.56) on some trees exposes 100 cm“ of his skin to the solution over a 4 hr period. Dieldrin has a half-life of about 6 months, a volume of distribution of about 40 L/kg, and a dermal permeability of about 3 x 10° cm/sec. (a) Estimate the absorption rate during the exposure period assuming the blood concentration is much lower than the skin concentration (i.e., take the blood level to be zero in the skin absorption equation). (b) Estimate how it takes after exposure begins for the groundskeeper's plasma dieldrin levels to reach 1 ng/L. (c) Estimate the maximum plasma dieldrin concentration in ng/L that will occur in this groundskeeper due to this exposure. (d) Estimate how long it will take after exposure ends for the groundskeeper's plasma dieldrin levels to drop back down to 1 ng/L. %3Darrow_forward
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