O-0005 Safety_ CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I_II_3
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Chemistry
Date
Oct 30, 2023
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9
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O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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O-0005 Safety
Due
No due date
Points
14
Questions
14
Available
Sep 5 at 12a.m. - Dec 6 at 11:59p.m.
Time Limit
30 Minutes
Allowed Attempts
Unlimited
Instructions
Attempt History
Attempt
Time
Score
KEPT
Attempt 3
5 minutes
14 out of 14
LATEST
Attempt 3
5 minutes
14 out of 14
Attempt 2
6 minutes
13.38 out of 14
Attempt 1
9 minutes
8 out of 14
Correct answers are hidden.
Score for this attempt: 14
out of 14
Submitted Oct 22 at 11:55p.m.
This attempt took 5 minutes.
Provide the correct answer to each of the following safety questions. You answer correctly to 80% of the
questions of this quiz in order to perform the experiment in the organic laboratory.
Take the Quiz Again
1 / 1 pts
Question 1
You want to start your reaction, but you realize that the stirplate is not
working. What is the fits thing you should do?
Call your TA and ask them to solve the problem.
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O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Call the laboratory technicial and ask them to check all the plates in the
lab.
Call the lab director and ask them to look into the problem. Call 911 Check if it is plugged into the wall socket. 1 / 1 pts
Question 2
When assembling a reflux condenser, the tubing should be connected
such that the water flows against gravity.
True False
10/22/23, 11:55 PM
O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Yes! This is correct.
Make sure you keep the water flow against gravity.
1 / 1 pts
Question 3
What would you use to monitor the temperature of your oil bath when the
procedure calls for a careful control of the reaction temperature?
The palm of your hand to feel the heat irradiated from the bath The lab instructor's thermic vision Digital thermometer Mercury thermometer 1 / 1 pts
Question 4
How many clamps are necessary to safely hold a reflux apparatus in
place?
2 4 1 3
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1 / 1 pts
Question 5
You want to set up a reaction where you are required to maintain the
temperature within a small temperature range. Which type of heat source
should you use?
Oil bath Microwave reactor Heat gun Heating mantle Thermowell 1 / 1 pts
Question 6
What type of glassware/piece of equipment would you use to add a solid
reactant to a round bottom flask to prevent the solid to contaminate the
walls of the glass joint?
Hirsch funnel Büchner funnel Plastic solids' funnel Glass funnel 1 / 1 pts
Question 7
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O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Where should you dispose of the drying agent (Na
SO
or MgSO
) once
you have finished the extraction/drying process?
2
4
4
In the non-halogenated waste in the waste fumehood. The solid waste containter in the waste fumehood. In the trash can at the end of the bench. In the halogenated waste in the waste fumehood. 1 / 1 pts
Question 8
Where should you dispose of the discarded aqueous layers collected after
any separation or extraction?
Halogenated waste in fumehood area Non-halogenated waste in fumehood area Down the drain with lots of cold running water. Solid waste in fumehood area 1 / 1 pts
Question 9
If you spill 100 mL DCM on your bench, the best course of action is:
To use paper towels to absorb as much as possible and leave it in the fume
hood to dry
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No action is necessary, it will evaporate quickly on its own To call 911 and evacuate the lab as DCM is extremely dangerous To move away all heat sources as DCM is flammable and then let it
evaporate
1 / 1 pts
Question 10
A student forgot to add 3M HCl at the end of the reaction. What problem
can this lead to?
Some product will remain deprotonated and stay in the aqueous layer Unreacted sodium borohydride can reduce the nitro group Aldol reaction can occur under basic conditions Some borohydride will not be quenched and can be extracted into DCM 1 / 1 pts
Question 11
A student added too much 3M HCl to their reaction mixture at the end of
the reaction. What problem can this lead to?
The amino group can get protonated, rendering the product water-soluble Too much hydrogen will be generated from unreacted borohydride, which is
a safety issue
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The product will decompose under strong acidic conditions The nitro group can be reduced under acidic conditions 1 / 1 pts
Question 12
What is the maximum volume of solution that can be concentrated in a
100 mL round bottom flask (RBF) on the rotary evaporator?
50 mL 25 mL 100 mL Any volume, it does not make a difference. 10 mL at a time. 1 / 1 pts
Question 13
One of the most common procedures in organic synthesis is the removal
of solvent at reduced pressure using a rotary evaporator.
Correctly match the steps to the order in which they should be done to
safely perform the rotary evaporation in the lab.
e.g.
Step 1. Connect the round bottom flask to the rotovap trap and hold it in
place.
Step 2...
Sep 6. Look at the condenser and look for the point where no more
solvent is dripping.
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O-0005 Safety: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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Setp 7...
Step 11. Disconnect the RBF from the rotary evaporator.
Step 2.
Connect the vaccum tu
Step 3.
Move the red lever to a
Step 4.
Start the rotation.
Step 5.
Lower the RBF into the
Step 7.
Remove the RBF from Step 8.
Stop the rotation.
Step 9.
Move the red lever to a
Step 10.
Hold your RBF with you
1 / 1 pts
Question 14
What specific fault in the glassware should you look for before you decide
to use a round bottom flask for rotary evaporation?
Any star crack in the flask Residual label adhesive
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Dirt or water stains Any marker stains Quiz Score: 14
out of 14
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A. John Dalton was an English chemist. His
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It is impossible to divide or destroy an atom.
• All atoms of the same elements are alike. (One
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Atoms of
ement Y
Compound of
elemeite XandY
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1. What is the name of John Dalton's theory?
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Atomic Structure
J. J. Thomson was an English…
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4,6,7,8)
Question 19 of 20 (5 points) Question Attempt: 1 of 1
Time Remaining: 30:47
Hannah
10
= 11
= 12
=13
=14
=15
= 16
17
18
19
20
Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced. (You can edit
both sides of the equation to balance it, if you need to.)
do
Note: you are writing the molecular, and not the net ionic equation.
-
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II
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4. For each example below, draw at least one possible isomer that is consistent with the
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80
60-
40-
20-
4000
b. MW 116, C6H12O2
80-
60-
20-
3500
4000
3500
9262
2943
3000
2837
2500
2000
2000
-9044
1653
1500
1468
1500
1437
1373
5221
6677
1080
1000
719
640
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00:40 A
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allall 85%
Due Date for Submission: Friday, 25th October @ 4:06 PM
UNIVERSITY OF PAPUA NEW GUINEA
SCHOOL OF NATURAL AND PHYSICAL SCIENCES
CHEMISTRY DISCIPLINE
1.10203 Chemistry 1B - Assignment No. 3
Please note that all assignments must be submitted in handwritten form; printed submissions will not be accepted.
Additionally, ensure that you submit your work directly to your assigned tutor. Failure to do so will result in a zero
mark. This process has been streamlined to prevent misplaced assignments and to avoid complaints at the end of
the semester. If you have submitted your work to the wrong tutor, retrieve it and submit it to the correct one to
avoid any penalties or issues later on.
Name:
ID#:
1. Study the following reactions and draw their reaction mechanisms
A
(a)
(b)
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CH3CH2CH2CI
AICI 3
CH2CH2CH3
CH3CH2CCI
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Group:,
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Score:
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1-arr
In a study of the gas phase decomposition of phosphine at 120 °C
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O order in PH, and the half life for the reaction is
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zero
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Round your answer to a whole number.
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Enter the answer that belongs in the green box.
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Question 8 of 8
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The enolate of a ketone can be treated with an ester to give a diketone. Drawa mechanism for this Claisen-like reaction and explain
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For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen
explicitly in your products. Do not use abbreviations such as Me or Ph.
Me
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5
10
15
20
Rate of volume change (mL/hr)
Rate of volume change(
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White Light Volume (ml)
2.8
3.8
4.7
5.6
6.6
1
final volume(mL)-initial volume(mL)
Time (min)
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2.4
2
1.6
1.2
x 60(
-X
min
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Complete the following steps:
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Elodea in white light. Record in Lall
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2023VVA Chemistry.7b.FA1
An unknown solid substance is heated according to the temperature versus time graph below.
Temperature (°C)
70
40
30
20
288 8 2
0
0
5
15
Time (min)
20
00
4 of 5
1
2
3
4
5
25
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2
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4
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16
7
8
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1
III I
III 1 I
2
3 1
I 4
5 II II
6 1
III |
.5.
For a reaction in which E° = -0.100 V and n = 1 mol electrons / mol, calculate AG°. State
+
your assumptions, if any, about temperature.
.6.
For a reaction in which E° = 0.100 V andn = 1 mol electrons / mol, calculate AG° at 25°C.
Dictionary
CC
Aa
...
!!!
II
III
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III I
III 1 I
2
3 1
I 4
5 II II
6 1
III |
MnO, (aq) + 8H*(aq) + 5e → Mn²*(aq) + 4 H,O(1)
Al(s) → Alš*(aq) + 3 e
+
.ЗА.
Assign oxidation numbers to all metals whether they be elemental, monatomic ion, or in
a polyatomic ion, in questions (1) and (2),
.3B. Tell what is being oxidized and what is being reduced in each reaction in questions (1) and
(2).
.3C. Identify each half-reaction in question (2) as oxidation half-reaction or reduction
half-reaction.
.4. Do you need to know the temperature to calculate AG° from E°? Explain.
>
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I 7 II I|
.1. Refer to the table of standard reduction potentials.
Standard Reduction Potentials at 25 C
Reduction Half-Reaction
(V)
FAg + 2 €
H2O{aq) + 2 H*(aq)+ 2 6
Mno,taq) + 8 H*(aq) + 5 &
Clalg) + 2 e
CrOFMaq)+ 14 H*(aq) + 6 6-
Ozlg + 4 H*(aq) + 4 &
Bra() + 26
Ag*(aq) + e
Fe*(aq) + e
Ozl9) + 2 H'(aq) + 2 €
2(s)+ 26
Ozlg) + 2 HO) + 46
Cu (aq) + 2 €
Sn" (ag)+ 2 6
2 P(aq)
2 H2O()
→ Mn(aq) + 4 H;0()
→2 cr(aq)
2 Cr (aq)+ 7 H0()
→2 HO()
2 Br(aq)
Ag(s)
» Fe*(aq)
→H;Oz(aq)
→2 F(aq)
→4 OH"(aq)
2.87
1.78
1.51
1.36
1.33
3.
1.23
1.09
0.80
0.77…
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!
Required information
The diameter of an oxygen (O2) molecule is approximately 0.300 nm.
For an oxygen molecule in air at atmospheric pressure and 14.7°C, estimate the total distance traveled during a 1.00-s time interval.
m
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- Answer question number 7 on the attached documentarrow_forward26) The floor tiles in SE 27 are about 1 square foot and the lab is about 25 tiles wide and about 36 tiles from front to back. When the emergency shower was demonstrated, in 10. seconds the water in the trash can was about 1 foot deep. One student estimated this was 2.5 gallons. Estimate how deep the room will get in inches after a 15 minute shower. List 3 simplifving assumptions you make in this calculation rea L-36 Tile fiDw ill it cost2 The density of gold is 27l An artist plans to apply gold leaf to a painting with an area of 2.32 f? and a thickness of 1.50arrow_forwardWhat safety rules did Andrew break?arrow_forward
- es-2021S2 Allison.E CHEM X 2.ga.us/d21/Ims/quizzing/user/attempt/quiz_start_frame_auto.d2l?ou=2593077&isprv=&drc%3D1&qi=2478023&cfql=0&dnb%3D08fi lancer O Khan Academy E DeltaMath musictheory.net - E. Ca Desmos | Scientific. g Final Exam Ciara Smith: Attempt 1 D View hint for Question 18 Question 19 (3 points) Explain how OCompound A and Compound B will dissolve in water using the correct vocabulary including solvation, dissociatic n, ionic, and covalent. O Mg Cl CH Compound A Compound B hp 二arrow_forwardBb Take Test: QUI A Ims.uhb.edu.sa/webapps/assessment/take/take.jsp?cours... لا تعيد السمكات إلى ا. . . الاثاد M Gmail O YouTube Human Biology Ch... A Apps Remaining Time: 15 minutes, 04 seconds. * Question Completion Status: 0.5 points Saved Question 6 Find the major product of following dehydration. OH CH3 CH,-CH-CH-CH2-CH3 + H20 CH3 OA CH2=CH-ĊH-CH2-CH3 OCH3 O B. CH3-C=c-CH2-CH3 OC. CH3-C-CH,- -CH2-CH2-CH3 O CH3 OD. CH3-C-CH-CH2-CH3 CH3 CH3-CH=C-CH2-CH3 » A Moving to another question will save this response. Question 6 of 10> .w. MacEarrow_forward11:15 .l .l 5.00 KB/S A O (12 4 app.teachermade.com/fill/13c37t (4) C Q Q T TI 4 v Save for Later I'm Done A. John Dalton was an English chemist. His Dalton's Atomic Theory ideas form the atomic theory of matter. Here are his ideas. • All elements are composed (made up) of atoms. It is impossible to divide or destroy an atom. • All atoms of the same elements are alike. (One Atoms of element X Atoms of ement Y Compound of elemeite XandY atom of oxygenis like another atom of oxygen.) • Atoms of different elements are different. (An atom of oxygen is different from an atom of hydrogen.) • Atoms of different elements combine to form a compound. These atoms have to be in definite whole number ratios. For example, water is a compound made up of 2 atoms of 1. What is the name of John Dalton's theory? 2. What are elements made of? 3. An atom of hydrogen and an atom of carbon are 4. What are compounds made of? 5. The ratio of atoms in HCI is: Atomic Structure J. J. Thomson was an English…arrow_forward
- 4,6,7,8) Question 19 of 20 (5 points) Question Attempt: 1 of 1 Time Remaining: 30:47 Hannah 10 = 11 = 12 =13 =14 =15 = 16 17 18 19 20 Predict the reactants of this chemical reaction. That is, fill in the left side of the chemical equation. Be sure the equation you submit is balanced. (You can edit both sides of the equation to balance it, if you need to.) do Note: you are writing the molecular, and not the net ionic equation. - CaBr, (aq) + H,O(1) Submit Assignment Continue Accessibility Privacy Center 2021 McGraw Hill LLC All Rights Reserved. Terms of Use IIarrow_forward4. For each example below, draw at least one possible isomer that is consistent with the molecular formula and the associated IR spectrum. a. MW 82, C6H10 80 60- 40- 20- 4000 b. MW 116, C6H12O2 80- 60- 20- 3500 4000 3500 9262 2943 3000 2837 2500 2000 2000 -9044 1653 1500 1468 1500 1437 1373 5221 6677 1080 1000 719 640arrow_forward00:40 A < 50 8 allall 85% Due Date for Submission: Friday, 25th October @ 4:06 PM UNIVERSITY OF PAPUA NEW GUINEA SCHOOL OF NATURAL AND PHYSICAL SCIENCES CHEMISTRY DISCIPLINE 1.10203 Chemistry 1B - Assignment No. 3 Please note that all assignments must be submitted in handwritten form; printed submissions will not be accepted. Additionally, ensure that you submit your work directly to your assigned tutor. Failure to do so will result in a zero mark. This process has been streamlined to prevent misplaced assignments and to avoid complaints at the end of the semester. If you have submitted your work to the wrong tutor, retrieve it and submit it to the correct one to avoid any penalties or issues later on. Name: ID#: 1. Study the following reactions and draw their reaction mechanisms A (a) (b) Edit < CH3CH2CH2CI AICI 3 CH2CH2CH3 CH3CH2CCI AICI3 Ова CH2CH3 Group:, H CH3 CH3 Score: Page 1 of 6 Annotate Fill & Sign Convert All Oarrow_forward
- 1-arr In a study of the gas phase decomposition of phosphine at 120 °C PH3(g)- →1/4 P4(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.50×10² s1 and a y-intercept of -3.24. Based on this plot, the reaction i v O order in PH, and the half life for the reaction is seconds. zero first secondarrow_forwardinstructure.com/courses/16017/quizzes/600409/take onds Press S... d Loading Desmos... Answer: Nicole Sneddon Cla... 1. °℃ 3 33 7.06 Conter X Math 7 2019-2020 L D 10 000 Image from Pixabay: https://pixabay.com/photos/petrol-equipment-fire-extinguisher-3079094/ There is 17.0 g of carbon dioxide gas stored in a cylinder with a volume of 16.0. A pressure gauge shows the pressure to be 3.00 atm. R=0.0821 Latm/(mol-K) In degrees Celsius, determine the temperature of the gas. Round your answer to a whole number. 7.06 Applic x M Ihbox (1,61: x 19,Unattempted. About Us - Levi S 3 | Garrow_forwardAb GL B art 3 SHOW WORK ond Shipp: Attempt 1 Hu/d21/Ims/quizzing/user/attempt/quiz_start_frame_auto.d2l?ou=5956136&isprv=&drc=0&qi=5726766&cfql= Answer units ▷ Add attachments to support your work Question 4 (0.5 points) SHOW YOUR WORK. G **N*-*OO If 35.45 mL of 0.8121 M sodium carbonate solution reacts with excess lead (III) nitrate solution to form aqueous sodium nitrate and solid lead (III) carbonate, how many grams of lead (III) carbonate is formed? On your paper with your name and date: 1. Go from ionic compound name to formula (review Chp 5 as much as needed) 2. Balance the equation (review Chp 7 if needed). 3. Do the calculation showing ALL units, just like I did in solution stoichiometry lecture. a #arrow_forward
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