O-007C Pre-lab_ CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I_II
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O-007C Pre-lab: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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O-007C Pre-lab
Due
No due date
Points
18
Questions
15
Available
Sep 5 at 12a.m. - Dec 6 at 11:59p.m.
Time Limit
30 Minutes
Allowed Attempts
2
Instructions
Attempt History
Attempt
Time
Score
KEPT
Attempt 2
10 minutes
18 out of 18
LATEST
Attempt 2
10 minutes
18 out of 18
Attempt 1
26 minutes
16 out of 18
Correct answers are hidden.
Score for this attempt: 18
out of 18
Submitted Oct 24 at 4:25a.m.
This attempt took 10 minutes.
Provide the correct answer to each of the following questions.
1 / 1 pts
Question 1
Match the laboratoy equipment or glassware with their correct name.
a.
10/24/23, 4:25 AM
O-007C Pre-lab: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
https://canvas.ubc.ca/courses/122851/quizzes/652127
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Reflux condenser
b.
Stir plate
c.
Round bottom flask
d.
Lab jack
e.
Three prong clamp
1 / 1 pts
Question 2
Answer 1:
TLC, which stands for Thin Layer Chromatography
, is an easy and fast
method to visualize different compounds in a liquid mixture. Like many
separation techniques in organic chemistry, TLC uses the differences in
polarity
between compounds for separation. The separation is
based on how the compounds in a mixture interact with the silica or
alumina of the stationary
phase and the solvent used as
mobile
phase. When the thin layer is made of silica,
nonpolar
substances will travel further up the plate as the
solvent
moves up the plate, compared to polar
substances, which will travel a smaller distance.
Chromatography
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Answer 2:
Answer 3:
Answer 4:
Answer 5:
Answer 6:
Answer 7:
polarity
stationary
mobile
nonpolar
solvent
polar
1 / 1 pts
Question 3
Any organic compound can be visualized on a TLC plate when the plate is
placed under UV light.
True False This is correct!
Only the organic compounds that contain conjugated double bonds in
their structure will be visible under the UV light.
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This is correct!
Only the organic compounds that contain conjugated double bonds
in their structure will be visible under the UV light.
1 / 1 pts
Question 4
The stain used as a secondary visualization method is ammonium
molybdate. What is the chemical formula of this compound?
NH MoO
4
2
(NH ) MoO
4 4
2
(NH ) Mo
4 4
(NH ) MoO
4 2
4
2 / 2 pts
Question 5
A graduate students want to do a large scale Fischer esterification of 6 g
of 2-chloro-4-nitrobenzoic acid. What amount of anhydrous ethanol should
they use for the reaction, considering the concentration of the acid is the
same as the concentration used in experiment O-007C of the 3rd-year
labs?
Give your answer in milliliters (mL) and rounded to the nearest integer.
99
10/24/23, 4:25 AM
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1 / 1 pts
Question 6
The reaction progress can be monitored using thin-layer chromatography.
Which compound would you predict will have the larger R value?
f
Both compounds will have the same R
f
It cannot be determined with the provided information. 4-nitrobenzoic acid ethyl 4-nitrobenzoate 2 / 2 pts
Question 7
What are the reasons for the brine wash of the organic layer?
To remove as much water as possible from the organic layer (trapped
droplets) before using a drying agent.
To optimize neutralize any base/acid left. To decrease the boiling point of the product. To break any emulsion that might have formed between the organic layer
and the aqueous layer.
To promote the recrystalization of the sample in the following step. 2 / 2 pts
Question 8
10/24/23, 4:25 AM
O-007C Pre-lab: CHEM 3XX ALL LABS 2023W1 Chemistry Integrated Laboratory I/II
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What is/are the role(s) of ethanol in the Fischer esterification reaction you
will perform?
Catalyst Nucleophile Electrohpile Solvent Acid 1 / 1 pts
Question 9
Which of these can help speed up the crystallization process?
Scratching the bottom of the flask with a glass rod All of the above Increasing the concentration of the solution Cooling down the solution
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1 / 1 pts
Question 10
What is the role of concentrated sulfuric acid in this reaction?
It protects the nitro group from the nucleophilic attack by ethanol It protonates the carbonyl group rendering it more electrophilic It protonates ethanol rendering it more nucleophilic It is a co-solvent 1 / 1 pts
Question 11
Why is it important to use anhydrous ethanol in this experiment?
Water can slow down the reaction Water can hydrolyze the ester product back to the starting acid Water would reduce the solubility of the starting material in ethanol A higher temperature is required to achieve reflux if water is present 1 / 1 pts
Question 12
Why is a large excess of ethanol used in this reaction?
Because some ethanol will be consumed by sulfuric acid
10/24/23, 4:25 AM
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Because ethanol acts as a base as well as anucleophile Because the solubility of 4-nitrobenzoic acid in ethanol is very low Because it helps shift the equilibrium towards the desired product 1 / 1 pts
Question 13
Carboxylic acids do not typically react with alcohols in the absence of a
Bronsted or Lewis acid. Why is this?
Because carboxylic acids are too acidic Because carboxylic acids are poor electrophiles Because alcohols are poor nucleophiles Because alcohols are too basic 1 / 1 pts
Question 14
An alternative way to convert a carboxylic acid into its ethyl ester consists
in reacting it with...
...ethylmagnesium bromide ...a base and ethyl iodide ...diazomethane ...an alkene and a base
10/24/23, 4:25 AM
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1 / 1 pts
Question 15
What distinctive change would you expect in the IR spectrum of the ester
product compared to the starting carboxylic acid? The appearance of a new signal around 1600 cm
-1
The appearance of a new broad signal around 3000 cm
-1
The disappearance of a broad signal around 3000 cm
-1
The disappearance of a signal around 1800 cm
-1
Quiz Score: 18
out of 18
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FAg + 2 €
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Find the major product of following dehydration.
OH CH3
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O CHEMICAL REACTIONS
Identifying the limiting reactant in a drawing of a mixture
The drawing below shows a mixture of molecules:
key
carbon
hydrogen
nitrogen
sulfur
oxygen
chlorine
Suppose the following chemical reaction can take place in this mixture:
CS,(9)+30,(9)
- CO2(9)+2 SO,(9)
Of which reactant are there the most initial moles? Enter its chemical formula:
Of which reactant are there the least initial moles? Enter its chemical formula:
Which reactant is the limiting reactant? Enter its chemical formula:
Explanation
Check
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References
Use the References to access important values if needed for this question.
For the following reaction, 24.7 grams of sulfur dioxide are allowed to react with 9.95 grams of oxygen
gas .
sulfur dioxide(g) + oxygen(g)
→ sulfur trioxide(g)
What is the maximum mass of sulfur trioxide that can be formed?
grams
What is the FORMULA for the limiting reagent?
grams
What mass of the excess reagent remains after the reaction is complete?
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