CHEMISTRY, AP EDITION-W/ACCESS (HS)9th EditionZUMDAHL Publisher: CENGAGE LISBN: 9781285732930
CHEMISTRY, AP EDITION-W/ACCESS (HS)
Solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS)
Problem 1RQ:
Characterize a system at chemical equilibrium with respect to each of the following a. the rates of...Problem 2RQ:
What is the law of mass action? Is it true that the value of K depends on the amounts of reactants...Problem 4RQ:
What is the difference between K and Kp? When doc K = Kp for a reaction? When does K Kp for a...Problem 5RQ:
What are homogeneous equilibria? Heterogeneous equilibria? What is the difference in writing K...Problem 6RQ:
Distinguish between the terms equilibrium constant and reaction quotient. When Q = K, what does this...Problem 7RQ:
Summarize the steps for solving equilibrium problems (see the beginning of Section 12-6). In...Problem 8RQ:
A common type of reaction we will study is that having a very small K value (K 1). Solving for...Problem 9RQ:
What is Le Chteliers principle? Consider the reaction 2NOCI(g)2NO(g)+Cl2(g) If this reaction is at...Problem 10RQ:
The only stress (change) that also changes the value of K is a change in temperature. For an...Problem 1ALQ:
Consider an equilibrium mixture of four chemicals (A, B, C, and D, all gases) reacting in a closed...Problem 2ALQ:
The boxes shown below represent a set of initial conditions for the reaction: Draw a quantitative...Problem 3ALQ:
For the reactionH2(g)+I2(g)2HI(g), consider two possibilities: (a) you mix 0.5 mole of each...Problem 4ALQ:
Given the reactionA(g)+B(g)C(g)+D(g), consider the following situations: i. You have 1.3 M A and 0.8...Problem 5ALQ:
Consider the reaction A(g)+2B(g)C(g)+D(g) in a 1.0-L rigid flask. Answer the following questions for...Problem 6ALQ:
Consider the reactionA(g)+B(g)C(g)+D(g). A friend asks the following: I know we have been told that...Problem 7ALQ:
Consider the following statements: Consider the reaction A(g)+B(g)C(g),for which at equilibrium [A]...Problem 8ALQ:
Le Chteliers principle is stated (Section 12-7) as follows: If a change is imposed on a system at...Problem 9ALQ:
The value of the equilibrium constant K depends on which of the following (more than one answer may...Problem 10Q:
Consider an initial mixture of N2 and H2 gases that can be represented as follows: The gases react...Problem 11Q:
Consider the following reaction: H2O(g)+CO(g)H2(g)+CO2(g) Amounts of H2O, CO, H2, and CO2 are put...Problem 12Q:
Consider the same reaction as in Question 11. In one experiment 1.0 mole of H2O(g) and 1.0 mole of...Problem 13Q:
Suppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this...Problem 14Q:
Suppose a reaction has the equilibrium constant K = 1.7 108 at a particular temperature. Will there...Problem 15Q:
Consider the following reaction at some temperature: H2O(g)+CO(g)H2(g)+CO2(g)K=2.0 Some molecules of...Problem 16Q:
Consider the following generic reaction: 2A2B(g)2A2(g)+B2(g) Some molecules of A2B are placed in a...Problem 17Q:
Explain the difference between K, Kp, and Q.Problem 18Q:
Consider the following reactions: H2(g)+I2(g)2HI(g)andH2(g)+I2(s)2HI(g) List two property...Problem 19Q:
For a typical equilibrium problem, the value of K and the initial reaction conditions are given for...Problem 20Q:
Which of the following statements is(are) true? Correct the false statement(s). a. When a reactant...Problem 21E:
Write the equilibrium expression (K) for each of the following gas-phase reactions. a....Problem 23E:
At a given temperature, K = 1.3 102 for the reaction N2(g)+3H2(g)2NH3(g) Calculate values of K for...Problem 24E:
For the reaction H2(g)+Br2(g)2HBr(g) Kp = 3.5 104 at 1495 K. What is the value of Kp for the...Problem 25E:
For the reaction 2NO(g)+2H2(g)N2(g)+2H2O(g) it is determined that, at equilibrium at a particular...Problem 26E:
At high temperatures, elemental nitrogen and oxygen react with each other to form nitrogen monoxide:...Problem 27E:
At a particular temperature, a 3.0-L flask contains 2.4 moles of Cl2, l.0 mole of NOCI, and 4.5 103...Problem 28E:
At a particular temperature a 2.00-L flask at equilibrium contains 2.80 104 mole of N2, 2.50 105...Problem 29E:
The following equilibrium pressures at a certain temperature were observed for the reaction...Problem 30E:
The following equilibrium pressures were observed at a certain temperature for the reaction...Problem 31E:
At 327c, the equilibrium concentrations are [CH3OH] = 0.15 M, [CO] = 0.24 M, and [H2] = 1.1 M for...Problem 32E:
At 1100 K, Kp = 0.25 for the reaction 2SO2(g)+O2(g)2SO3(g) What is the value of K at this...Problem 33E:
Write expressions for K and Kp for the following reactions. a. 2NH3(g)+CO2(g)N2CH4O(s)+H2O(g) b....Problem 35E:
For which reactions in Exercise 33 is Kp equal to KProblem 36E:
For which reactions in Exercise 34 is Kp equal to K?Problem 37E:
Consider the following reaction at a certain temperature: 4Fe(s)+3O2(g)2Fe2O3(s) An equilibrium...Problem 38E:
In a study of the reaction 3Fe(s)+4H2O(g)Fe3O4(s)+4H2(g) at 1200 K it was observed that when the...Problem 39E:
The equilibrium constant is 0.0900 at 25C for the reaction H2O(g)+Cl2O(g)2HOCl(g) For which of the...Problem 40E:
The equilibrium constant is 0.0900 at 25C for the reaction H2O(g)+Cl2O(g)2HOCl(g) For which of the...Problem 42E:
Ethyl acetate is synthesized in a nonreacting solvent (not water) according to the following...Problem 43E:
For the reaction 2H2O(g)2H2(g)+O2(g) K = 2.4 103 at a given temperature. At equilibrium in a 2.0-L...Problem 44E:
The reaction 2NO(g)+Br2(g)2NOBr(g) has Kp = 109 at 25C. If the equilibrium partial pressure of Br2...Problem 45E:
A 1.00-L flask was filled with 2.00 moles of gaseous SO2 and 2.00 moles of gaseous NO2 and heated....Problem 46E:
A sample of S8(g) is placed in an otherwise empty rigid container at 1325 K at an initial pressure...Problem 47E:
At a particular temperature, 12.0 moles of SO3 is placed into a 3.0-L rigid container, and the SO3...Problem 48E:
At a particular temperature, 8.0 moles of NO2 is placed into a 1.0-L container and the NO2...Problem 49E:
An initial mixture of nitrogen gas and hydrogen gas is reacted in a rigid container at a certain...Problem 50E:
Nitrogen gas (N2) reacts with hydrogen gas (H2) to form ammonia (NH3). At 200C in a closed...Problem 51E:
At a particular temperature, K = 3.75 for the reaction SO2(g)+NO2(g)SO3(g)+NO(g) If all four gases...Problem 53E:
At 2200C, Kp = 0.050 for the reaction N2(g)+O2(g)2NO(g) What is the partial pressure of NO in...Problem 54E:
At 25c, K = 0.090 for the reaction H2O(g)+Cl2O(g)2HOCI(g) Calculate the concentrations of all...Problem 55E:
At 1100 K, KP = 0.25 for the reaction 2SO2(g)+O2(g)2SO3(g) Calculate the equilibrium partial...Problem 56E:
At a particular temperature, Kp = 0.25 for the reaction N2O4(g)2NO2(g) a. A flask containing only...Problem 57E:
At 35C, K = 1.6 105 for the reaction 2NOCl(g)2NO(g)+Cl2(g) Calculate the concentrations of all...Problem 58E:
At a particular temperature, K = 4.0 107 for the reaction N2O4(g)2NO2(g) In an experiment, 1.0 mole...Problem 59E:
At a particular temperature, K = 2.0 106 for the reaction 2CO2(g)2CO(g)+O2(g) If 2.0 moles of CO2...Problem 60E:
Lexan is a plastic used to make compact discs, eyeglass lenses, and bullet-proof glass. One of the...Problem 63E:
Suppose the reaction system UO2(s)+4HF(g)UF4(g)+2H2O(g) has already reached equilibrium. Predict the...Problem 64E:
Predict the shift in the equilibrium position that will occur for each of the following reactions...Problem 65E:
An important reaction in the commercial production of hydrogen is CO(g)+H2O(g)H2(g)+CO2(g) How will...Problem 66E:
What will happen to the number of moles of SO3 in equilibrium with SO2 and O2 in the reaction...Problem 67E:
In which direction will the position of the equilibrium 2HI(g)H2(g)+I2(g) be shifted for each of the...Problem 69E:
Old-fashioned smelling salts consist of ammonium carbonate, (NH4)2CO3. The reaction for the...Problem 70E:
Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted directly using...Problem 72AE:
Given the following equilibrium constants at 427C,...Problem 73AE:
Consider the decomposition of the compound C5H6O3 as follows: C5H6O3(g)C2H6(g)+3CO(g) When a 5.63-g...Problem 74AE:
At 25C. Kp 1 1031 for the reaction a. Calculate the concentration of NO, in molecules/cm3, that can...Problem 75AE:
The gas arsine, AsH3, decomposes as follows: 2AsH3(g)2As(s)+3H2(g) In an experiment at a certain...Problem 76AE:
At a certain temperature, K = 9.1 10-4 for the reaction FeSCN2+(aq)Fe3+(aq)+SCN(aq) Calculate the...Problem 77AE:
At a certain temperature, K = 1.1 l03 for the reaction Fe3+(aq)+SCN(aq)FeSCN2+(aq) Calculate the...Problem 78AE:
For the reaction PCl5(g)PCl3(g)+Cl2(g) at 600. K, the equilibrium constant, Kp, is 11.5. Suppose...Problem 79AE:
At 25C, gaseous SO2Cl2 decomposes to SO2(g) and Cl2(g) to the extent that 12.5% of the original...Problem 80AE:
For the following reaction at a certain temperature H2(g)+F2(g)2HF(g) it is found that the...Problem 81AE:
Novelty devices for predicting rain contain cobalt(II) chloride and are based on the following...Problem 82AE:
Consider the reaction Fe3+(aq)+SCN(aq)FeSCN2+(aq) How will the equilibrium position shift if a....Problem 83AE:
Chromium(VI) forms two different oxyanions, the orange dichromate ion, Cr2O72 , and the yellow...Problem 85AE:
Suppose K = 4.5 103 at a certain temperature for the reaction PCl5(g)PCl3(g)+Cl2(g) If it is found...Problem 86AE:
For the reaction below, Kp = 1.16 at 800C. CaCO3(s)CaO(s)+CO2(g) If a 20.0-g sample of CaCO3 is put...Problem 87AE:
Many sugars undergo a process called mutarotation, in which the sugar molecules interconvert between...Problem 88AE:
Peptide decomposition is one of the key processes of digestion, where a peptide bond is broken into...Problem 90AE:
Methanol, a common laboratory solvent, poses a threat of blindness or death if consumed in...Problem 92CWP:
An equilibrium mixture contains 0.60 g solid carbon and the gases carbon dioxide and carbon monoxide...Problem 93CWP:
At a particular temperature, 8.1 moles of NO2 gas is placed in n 3.0-L container. Over time the NO2...Problem 94CWP:
A sample of solid ammonium chloride was placed in an evacuated chamber and then heated, causing it...Problem 95CWP:
In a given experiment, 5.2 moles of pure NOCl was placed in an otherwise empty 2.0-L container....Problem 96CWP:
For the reactionN2O4(g)2NO2(g),Kp=0.25 at a certain temperature. If 0.040 atm of N2O4 is reacted...Problem 97CWP:
Consider the following exothermic reaction at equilibrium: N2(g)+2H2(g)2NH3(g) Predict how the...Problem 98CWP:
For the following endothermic reaction at equilibrium: 2SO3(g)2SO2(g)+O2(g) which of the following...Problem 99CP:
A 1.604-g sample of methane (CH4) gas and 6.400 g oxygen gas are scaled into a 2.50-L vessel at 411C...Problem 100CP:
A 4.72-g sample of methanol (CH3OH) was placed in an otherwise empty 1.00-L flask and heated to...Problem 101CP:
At 35C, K = 1.6 105 for the reaction 2NOCl(g)2NO(g)+Cl2(g) If 2.0 moles of NO and 1.0 mole of Cl2...Problem 102CP:
Nitric oxide and bromine at initial partial pressures of 98.4 and 41.3 torr, respectively, were...Problem 103CP:
At 25C. Kp = 5.3 105 for the reaction N2(g)+3H2(g)2NH3(g) When a certain partial pressure of NH3(g)...Problem 104CP:
Consider the reaction P4(g)2P2(g) where Kp = 1.00 101 at 1325 K. In an experiment where P4(g) is...Problem 105CP:
The partial pressures of an equilibrium mixture of N2O4(g) and NO2(g) are PN2O4=0.34 atm and...Problem 106CP:
At 125C, KP = 0.25 for the reaction 2NaHCO3(s)Na2CO3(s)+CO2(g)+H2O(g) A 1.00-L flask containing 10.0...Problem 107CP:
A mixture of N2, H2, and NH3 is at equilibrium [according to the equationN2(g)+3H2(g)2NH3(g)] as...Problem 108CP:
Consider the decomposition equilibrium for dinitrogen pentoxide: 2N2O5(g)4NO2(g)+O2(g) At a certain...Problem 109CP:
An 8.00-g sample of SO3 was placed in an evacuated container, where it decomposed at 600C according...Problem 110CP:
A sample of iron(II) sulfate was heated in an evacuated container to 920 K, where the following...Problem 112CP:
A sample of N2O4(g) is placed in an empty cylinder at 25c. After equilibrium is reached the total...Problem 113CP:
A sample of gaseous nitrosyl bromide (NOBr) was placed in a container tiued with a frictionless,...Problem 114CP:
The equilibrium constant Kp for the reaction CCl4(g)C(s)+2Cl2(g) at 700C is 0.76. Determine the...Problem 115IP:
For the reaction NH3(g)+H2S(g)NH4HS(s) K = 400. at 35.0C. If 2.00 moles each of NH3, H2S, and NH4HS...Problem 116IP:
Given K = 3.50 at 45C for the reaction A(g)+B(g)C(g) and K = 7.10 at 45C for the reaction...Problem 117IP:
In a solution with carbon tetrachloride as the solvent, the compound VCl4. undergoes dimerization:...Browse All Chapters of This Textbook
Chapter 1 - Chemical FoundationsChapter 2 - Atoms, Molecules, And IonsChapter 3 - StoichiometryChapter 4 - Types Of Chemical Reactions And Solution StoichiometryChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - Atomic Structure And PeriodicityChapter 8 - Bonding: General ConceptsChapter 9 - Covalent Bonding: OrbitalsChapter 10 - Liquids And Solids
Chapter 11 - Properties Of SolutionsChapter 12 - Chemical KineticsChapter 13 - Chemical EquilibriumChapter 14 - Acids And BasesChapter 15 - Acid-base EquilibriaChapter 16 - Solubility And Complex Ion EquilibriaChapter 17 - Spontaneity, Entropy, And Free EnergyChapter 18 - ElectrochemistryChapter 19 - The Nucleus: A Chemist's ViewChapter 20 - The Representative ElementsChapter 21 - Transition Metals And Coordination ChemistryChapter 22 - Organic And Biological Molecules
Sample Solutions for this Textbook
We offer sample solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS) homework problems. See examples below:
Chapter 1, Problem 1RQChapter 1, Problem 30EChapter 1, Problem 35EChapter 1, Problem 36EChapter 1, Problem 38EChapter 1, Problem 45EChapter 1, Problem 57EChapter 1, Problem 59EChapter 1, Problem 60E
Chapter 1, Problem 63EChapter 1, Problem 64EChapter 1, Problem 73EChapter 1, Problem 113CPChapter 2, Problem 1RQChapter 2, Problem 64EChapter 2, Problem 67EChapter 2, Problem 68EExplanation: Atomic number given is 13. From the periodic table we can identify that the element...Chapter 2, Problem 71EExplanation: To determine: The naming of CuI The name of CuI is copper(I) iodide. In naming of...Explanation: To determine: The naming of HC2H3O2 The naming of HC2H3O2 is acetic acid. Rules for...To determine: The formula of of sulfur difluoride The formula of sulfur difluoride is SF2 Sulfur...Explanation: To determine: The formula of sodium oxide. The formula of sodium oxide is Na2O The...Chapter 2, Problem 86EChapter 2, Problem 88EExplanation: To determine: The formula and the name of the binary compound formed from Ca and N. The...Explanation: To determine: The explanation for the term “counting by weighing”. The stated concept,...Chapter 3, Problem 59EChapter 3, Problem 60EChapter 3, Problem 61EExplanation: Given The mass of P4O6 is 1.00 g . The molar mass of P4O6 is 219.866 g/mol . Formula...Chapter 3, Problem 64EChapter 3, Problem 67EChapter 3, Problem 68EChapter 3, Problem 71EChapter 3, Problem 73EChapter 3, Problem 76EChapter 3, Problem 79EChapter 3, Problem 100EChapter 3, Problem 109EChapter 3, Problem 119EChapter 3, Problem 121EChapter 3, Problem 124EChapter 3, Problem 150AEChapter 3, Problem 152CWPChapter 3, Problem 180IPChapter 4, Problem 1RQChapter 4, Problem 7RQExplanation: NaBr(s)→Na(aq)++Braq- Figure 1 Let us consider the above molecular-level pictures of...Explanation: Record the given data Moles of Sodium phosphate= 0.200 moles Volume of the solution=...Chapter 4, Problem 66EChapter 4, Problem 79EChapter 4, Problem 82EChapter 4, Problem 93AEChapter 4, Problem 121CPChapter 4, Problem 122CPChapter 4, Problem 123CPExplanation Record the given data Mass of the sample mixture = 0.205 g Mass of the precipitate =...Explanation: Given: Record the given data Upstream at which the stream rate flows = 5.00×104 L/s...Chapter 4, Problem 144MPChapter 4, Problem 145MPA barometer consists of Mercury column that is tipped inverted and positioned in a dish containing...Chapter 5, Problem 41EExplanation: The relation between pressures measured in the manometers containing mercury and...Explanation According to ideal gas equation, PV=nRT By rearranging the above equation, PVnT=R Since...Chapter 5, Problem 88EExplanation: To find: the mole fractions of CH4 and O2 in the given mixture if the partial pressure...Explanation To find: the number of moles of dimethyl hydrazine from its given mass. The number of...Explanation To determine: The partial pressure of carbon monoxide Partial pressure of carbon...Explanation To determine: The mixing ratio of benzene Mixing ratio of benzene = 9.47 × 10-3ppmv For...Explanation: The mass percent from the given data is, 26.1% Carbon13.1% Hydrogen61.0% Nitrogen Mass...Chapter 5, Problem 135AEExplanation To find: the empirical formula of the compound Convert the mass percent to gram 58.51%...Chapter 5, Problem 139AEChapter 5, Problem 152CPChapter 5, Problem 153CPExplanation To determine: Mass of hot air when the average molar mass of air 29.0g/mol Mass of hot...Chapter 5, Problem 162IPChapter 6, Problem 1RQChapter 6, Problem 20QChapter 6, Problem 34EChapter 6, Problem 50EChapter 6, Problem 52EChapter 6, Problem 79EChapter 6, Problem 80EExplanation: The balanced equation is: a) N2(g)→N2(l) In (a) the volume of products is decreases...Chapter 6, Problem 108AEChapter 6, Problem 115AEChapter 6, Problem 130CPChapter 6, Problem 131CPChapter 6, Problem 134IPChapter 6, Problem 135IPChapter 6, Problem 137MPChapter 7, Problem 1RQChapter 7, Problem 24QChapter 7, Problem 43EChapter 7, Problem 57EChapter 7, Problem 58EChapter 7, Problem 61EChapter 7, Problem 62EChapter 7, Problem 63EChapter 7, Problem 74EChapter 7, Problem 79EChapter 7, Problem 81EChapter 7, Problem 82EChapter 7, Problem 86EChapter 7, Problem 87EChapter 7, Problem 94EChapter 7, Problem 95EChapter 7, Problem 97EChapter 7, Problem 142AEChapter 7, Problem 171CPChapter 8, Problem 1RQExplanation: Refer to figure 3-4. The electro negativity of carbon (C) , nitrogen (N) , and oxygen...Explanation: Refer to figure 3-4 The electro negativity of Sodium (Na) Potassium (K) and Rubidium...Chapter 8, Problem 46EChapter 8, Problem 47EChapter 8, Problem 49EExplanation: In a periodic table the size of ions depends on the nuclear attraction on the valence...Chapter 8, Problem 54EChapter 8, Problem 62EChapter 8, Problem 81EChapter 8, Problem 84EChapter 8, Problem 89EChapter 8, Problem 101EChapter 8, Problem 102EChapter 8, Problem 129AEChapter 8, Problem 154CPChapter 8, Problem 155CPChapter 9, Problem 1RQChapter 9, Problem 23EChapter 9, Problem 24EChapter 9, Problem 26EChapter 9, Problem 29EChapter 9, Problem 30EChapter 9, Problem 39EChapter 9, Problem 52EChapter 9, Problem 53EChapter 9, Problem 63AEChapter 9, Problem 89CPChapter 10, Problem 1RQChapter 10, Problem 41EExplanation: CCl4 , CBr4, CF4 Identify the compound which has highest boiling point and justify it....Chapter 10, Problem 53EChapter 10, Problem 55EChapter 10, Problem 56EChapter 10, Problem 57EChapter 10, Problem 58EChapter 10, Problem 59EChapter 10, Problem 60EChapter 10, Problem 62EChapter 10, Problem 80EChapter 10, Problem 88EChapter 10, Problem 131CPChapter 10, Problem 146CPChapter 10, Problem 148IPExplanation: To explain molarity Molarity can be defined as moles of solute to litres of solution....Chapter 11, Problem 16SRChapter 11, Problem 31EExplanation: Record the given data Gram equivalent of HCl = 0.25 Molarity of HCl = 0.25 M To...Explanation: KrF2 8+2(7)=22e- KrF2 is dissolves in CCl4 . KrF2 is non-polar molecule that makes it...Chapter 11, Problem 55EChapter 11, Problem 79EExplanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: To find the Acetone and water polarity CH3COCH3 and H2O The electrostatic possible...Explanation: Record the given data, Freezing point of an aqueous solution =- 2.79°C To calculate...Mass of Sodium = 285-315 mg Mass of Potassium = 14.1-17.3 mg Mass of Calcium = 4.9-6.0 mg Mass of...Chapter 11, Problem 109AEChapter 11, Problem 120CPChapter 11, Problem 132IPChapter 12, Problem 1RQChapter 12, Problem 30EChapter 12, Problem 33EChapter 12, Problem 35EChapter 12, Problem 36EChapter 12, Problem 58EChapter 12, Problem 84AEChapter 12, Problem 86AEChapter 12, Problem 87AEChapter 12, Problem 91AEChapter 12, Problem 93AEChapter 12, Problem 105CPChapter 12, Problem 112CPChapter 13, Problem 1RQChapter 13, Problem 5ALQChapter 13, Problem 23EChapter 13, Problem 39EChapter 13, Problem 42EChapter 13, Problem 54EChapter 13, Problem 56EChapter 13, Problem 57EChapter 13, Problem 72AEChapter 13, Problem 73AEChapter 13, Problem 78AEChapter 13, Problem 104CPChapter 13, Problem 106CPChapter 14, Problem 1RQChapter 14, Problem 49EChapter 14, Problem 50EChapter 14, Problem 51EChapter 14, Problem 52EChapter 14, Problem 63EChapter 14, Problem 64EChapter 14, Problem 68EChapter 14, Problem 73EChapter 14, Problem 74EExplanation: To determine: The pH, [H+] and [OH−] of (C2H5)3N . The equilibrium constant expression...Chapter 14, Problem 101EChapter 14, Problem 107EChapter 14, Problem 108EChapter 14, Problem 109EChapter 14, Problem 119EChapter 14, Problem 120EChapter 14, Problem 123EChapter 14, Problem 126EChapter 14, Problem 151AEChapter 15, Problem 1RQChapter 15, Problem 7RQChapter 15, Problem 43EChapter 15, Problem 57EChapter 15, Problem 58EChapter 15, Problem 59EChapter 15, Problem 60EChapter 15, Problem 61EChapter 15, Problem 62EChapter 15, Problem 63EChapter 15, Problem 64EChapter 15, Problem 65EExplanation The value of pH of solution when 0.0 mL NaOH has been added is. 1.0_ . Given: The...Chapter 15, Problem 107CWPChapter 16, Problem 1RQExplanation To determine: The solubility product of CaC2O4 . The concentration of Ca2+ is 4.8×10−5...Chapter 16, Problem 22EChapter 16, Problem 27EChapter 16, Problem 28EChapter 16, Problem 35EChapter 16, Problem 36EChapter 16, Problem 37EChapter 16, Problem 40EChapter 16, Problem 53EChapter 16, Problem 70EChapter 16, Problem 102CPChapter 17, Problem 1RQChapter 17, Problem 53EChapter 17, Problem 54EChapter 17, Problem 63EChapter 17, Problem 64EChapter 17, Problem 68EChapter 17, Problem 70EChapter 17, Problem 72EChapter 17, Problem 74EChapter 17, Problem 78EChapter 17, Problem 86AEChapter 17, Problem 90AEChapter 17, Problem 119MPChapter 18, Problem 1RQChapter 18, Problem 16RORRExplanation: Given: I- (aq) + ClO- (aq) →I3− (aq) + Cl-(aq) To write the equations for two...Explanation: Given: Cu (s) + NO3- (aq) →Cu2+ (aq) + NO(g) To write the equations for two...Chapter 18, Problem 47EChapter 18, Problem 75EChapter 18, Problem 76EChapter 18, Problem 85EChapter 18, Problem 86EChapter 18, Problem 95EChapter 18, Problem 115AEChapter 18, Problem 117AEExplanation: Given The given reaction is, Fe(s)+HCl(aq)→HFeCl4(aq)+H2(g) . In this equation, the...Chapter 18, Problem 144CPExplanation The half cell reactions are, Anode: Hg→Hg2++2e− Eanodeο=0.242 V Cathode: 2Ag++2e−→2Ag...Chapter 18, Problem 153CPChapter 18, Problem 159MPExplanation (a) To define: The term thermodynamic stability. The thermodynamic stability is related...Explanation: Alpha particle is emitted. The parent nuclide is 232Th and the nuclide after the...Explanation The most stable isotope is 81Kr and the hottest one is 73Kr The nuclides having longer...Explanation Given The atomic mass of 232Pu is 3.85285×10−22 g . The mass of a neutron is...Explanation The atomic mass of 11H=1.0078 amu The mass of a neutron is 1.0087 amu . Mass of...Explanation Given The value of half life of 87Rb is 4.5×109 years . The decay constant is calculated...Explanation The decay constant is calculated by the formula given below. λ=0.693t1/2 Where t1/2 is...Explanation: The zirconium metal is capable of reducing water to form hydrogen gas at standard...Explanation The number of α and β particles produced are 4_ and 2_ . The mass number of 92238U is...Explanation The nuclear reaction for the synthesis of cobalt- 60 is, 2658Fe+201n→ 2760Co+ −10e . The...Chapter 20, Problem 1RQExplanation The valence electron configuration for halogens is ns2np5 . The common halogen elements...Explanation The value of ΔH° for the given reaction is 180 kJ_ . The stated reaction is,...Explanation: The compound XeO4 and IO4− ion are isoelectronic. The molecule xenon tetroxide (XeO4)...Explanation: The Lewis structure, molecular structure, bond angle and hybridization of central atom...Explanation Given Dimension of room is 10.0 m×10.0 m×10.0 m . Temperature is 25 °C . Pressure is...Explanation: Hydrogen gas is produced by reacting graphite with water. C(s)+H2O(g)→CO(g)+H2(g) The...Explanation: The number of moles of hydrogen gas is 0.249 mol_. Given Mass of alkaline earth metal...Explanation: Mass of radon (Ra) is 25 g_ . Given Mass of pitch-blende is 1.75×108 g . The conversion...Explanation Given Temperature is 900 K . Pressure of In(CH3)3 is 2.00 atm . Volume of In(CH3)3 is...Chapter 20, Problem 108IPChapter 20, Problem 109IPChapter 21, Problem 1RQExplanation: (I) To determine: The geometry and associated bond angles when a metal ion has a...Explanation: Atomic number of Nickel is 28 . Accordingly the electronic configuration is –...Explanation: Atomic number of Nickel is 22 . Accordingly the electronic configuration is –...EXPLANATION (a) To write: The electron configuration of metal ion in (NH4)2[Fe(H2O)2Cl4] . The...Explanation The complex ion is [Ru(NH3)5Cl]2+. This ion contains positive charge. Oxidation state of...Explanation The complex compound is [Co(NH3)6]Cl2 . Oxidation state of Chlorine ion (Cl−) is −1 ....Explanation The complex compound is [Cr(H2O)5Br]Br2 . Oxidation state of Bromine ion (Br−) is −1 ....Explanation The value of ΔH° for the given reaction is −11 kJ_ . For the reaction,...Explanation The reaction that takes place is, 3Fe2O3(s)+CO(g)→2Fe3O4(s)+CO2(g) Refer to Appendix 4....Explanation The given equations are, Co+3+e−→Co+2 Eο=1.82 V (1) Co2++3en→Co(en)32+ K=1.5×1012 (2)...Chapter 21, Problem 99IPChapter 22, Problem 1RQChapter 22, Problem 5RQExplanation: The type of isomerism that could be exhibited by C6H12 and an example that illustrates...Chapter 22, Problem 16EChapter 22, Problem 45EExplanation To determine: The monomer of the given polymer. The monomer is vinyl fluoride. It is an...Explanation The correct name of the compound is 2,3,5,6−Tetramethyl−octane whose structure is shown...Explanation The structure of the given compound 2,3,7,8−tetrachloro−dibenzo−p−dioxin is shown in...Chapter 22, Problem 130AEChapter 22, Problem 136AEExplanation The equilibrium constant for the given reaction is 6.88×10−13_ . The equilibrium...Chapter 22, Problem 148CPExplanation The structure of C5H12 is shown in Figure 1. The structure of C5H12 is, Figure 1 The...Explanation The structure of the polymer of ABS plastic is shown in figure 1. The reaction of Abs...Explanation Given Electronic configuration of M+2 is [Ar]3d10. So, atomic number of M is 30. In...Explanation The empirical formula of the given helicene is C5H3 . Helicene is an aromatic compound...The correct responses are urea and Ammonium cyanate. The first organic compound that is synthesized...Explanation Aldohexose is a six carbon aldehyde sugar with an aldehyde group on one end.
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