CHEMISTRY,AP EDITION-W/ACCESS (HS)
CHEMISTRY,AP EDITION-W/ACCESS (HS)
9th Edition
ISBN: 9781285732930
Author: ZUMDAHL
Publisher: CENGAGE L
Question
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Chapter 11, Problem 43E

a)

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

a)

Expert Solution
Check Mark

Answer to Problem 43E

Answer

KrF2 dissolves in CCl4

Explanation of Solution

KrF2

8+2(7)=22e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  1

KrF2 is dissolves in CCl4 . KrF2 is non-polar molecule that makes it soluble in non polar solvent

b)

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

b)

Expert Solution
Check Mark

Answer to Problem 43E

Answer

SF2 dissolves in Water

Explanation of Solution

SF2

6+2(7)=20e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  2

SF2 is dissolves in Water. SF2 is polar molecule; therefore it is soluble in Water.

c)

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

c)

Expert Solution
Check Mark

Answer to Problem 43E

Answer

SO2 dissolves in Water

Explanation of Solution

SO2

6+2(6)=18e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  3

SO2 is dissolves in Water. SO2 is polar molecule; therefore it is soluble in Water.

d).

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

d).

Expert Solution
Check Mark

Answer to Problem 43E

Answer

CO2 dissolves in CCl4

Explanation of Solution

CO2

4+2(6)=16e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  4

CO2 is dissolves in CCl4 . CO2 is non polar molecule that makes it soluble in non polar solvent

e)

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

e)

Expert Solution
Check Mark

Answer to Problem 43E

Answer

MgF2 dissolves in Water

Explanation of Solution

MgF2 is an ionic compound so it is soluble in water.

MgF2 is dissolves in Water. MgF2 is polar molecule; therefore it is soluble in Water.

f).

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

f).

Expert Solution
Check Mark

Answer to Problem 43E

Answer

CH2O dissolves in Water

Explanation of Solution

CH2O

4+2(1)+6=12e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  5

CH2O is dissolves in Water. CH2O is polar molecule; therefore it is soluble in Water.

g)

Interpretation Introduction

Interpretation: The dissolution of the following in water or CCl4 has to be predicted.

Concept Introduction:

The bonds involving the atoms with various electronegativites having a large dipole moment are called as polar solvents. Example of polar solvent is Water.

The bonds involving the atoms with same electronegativites are called as non polar solvents. Examples of non polar solvents are Gasoline, Carbon tetrachloride etc

Water is a polar solvent as well as dissolves polar solutes and ionic solutes. Carbon tetrachloride

( CCl4 ) is a non-polar solvent and dissolves non-polar solutes. To predict the split of the subsequent molecules, draw the correct Lewis structure and then determine if the entity bond dipoles cancel or not. But the bond dipoles are approved in such a manner that they cancel each other out, then the molecule is non-polar. If the bond dipoles do not withdraw each extra out, then the molecule is polar.

g)

Expert Solution
Check Mark

Answer to Problem 43E

Answer

C2H4 dissolves in CCl4

Explanation of Solution

C2H4

2(4)+4(1)=20e-

CHEMISTRY,AP EDITION-W/ACCESS (HS), Chapter 11, Problem 43E , additional homework tip  6

C2H4 is dissolves in CCl4 . C2H4 is non polar molecule that makes it soluble in non polar solvent

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Chapter 11 Solutions

CHEMISTRY,AP EDITION-W/ACCESS (HS)

Ch. 11 - Prob. 1ALQCh. 11 - Once again, consider Fig. 10-9. Suppose instead of...Ch. 11 - Prob. 3ALQCh. 11 - Prob. 4ALQCh. 11 - You have read that adding a solute to a solvent...Ch. 11 - You drop an ice cube (made from pure water) into a...Ch. 11 - Using the phase diagram for water and Raoults law,...Ch. 11 - You and your friend are each drinking cola from...Ch. 11 - Prob. 9ALQCh. 11 - Prob. 10ALQCh. 11 - Rubbing alcohol contains 585 g isopropanol...Ch. 11 - Prob. 12SRCh. 11 - Prob. 13SRCh. 11 - Prob. 14SRCh. 11 - Calculate the sodium ion concentration when 70.0...Ch. 11 - Write equations showing the ions present after the...Ch. 11 - Rationalize the temperature dependence of the...Ch. 11 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 11 - The two beakers in the sealed container...Ch. 11 - The following plot shows the vapor pressure of...Ch. 11 - When pure methanol is mixed with water, the...Ch. 11 - Prob. 22QCh. 11 - For an acid or a base, when is the normality of a...Ch. 11 - Prob. 24QCh. 11 - Prob. 25QCh. 11 - Prob. 26QCh. 11 - Explain the terms isotonic solution, crenation,...Ch. 11 - Prob. 28QCh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Common commercial acids and bases are aqueous...Ch. 11 - In lab you need to prepare at least 100 mL of each...Ch. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Calculate the molarity and mole fraction of...Ch. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - a. Use the following data to calculate the...Ch. 11 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - For each of the following pairs, predict which...Ch. 11 - Which ion in each of the following pairs would you...Ch. 11 - Rationalize the trend in water solubility for the...Ch. 11 - In flushing and cleaning columns used in liquid...Ch. 11 - The solubility of nitrogen in water is 8.21 104...Ch. 11 - Calculate the solubility of O2 in water at a...Ch. 11 - Glycerin, C3H8O3, is a nonvolatile liquid. What is...Ch. 11 - The vapor pressure of a solution containing 53.6 g...Ch. 11 - The normal boiling point of diethyl ether is...Ch. 11 - At a certain temperature, the vapor pressure of...Ch. 11 - A solution is made by dissolving 25.8 g urea...Ch. 11 - A solution of sodium chloride in water has a vapor...Ch. 11 - Prob. 57ECh. 11 - A solution is prepared by mixing 0.0300 mole of...Ch. 11 - What is the composition of a methanol...Ch. 11 - Benzene and toluene form an ideal solution....Ch. 11 - Which of the following will have the lowest total...Ch. 11 - Prob. 62ECh. 11 - Match the vapor pressure diagrams with the...Ch. 11 - The vapor pressures of several solutions of...Ch. 11 - A solution is prepared by dissolving 27.0 g urea,...Ch. 11 - A 2.00-g sample of a large biomolecule was...Ch. 11 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 11 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 11 - Prob. 69ECh. 11 - What volume of ethylene glycol (C2H6O2), a...Ch. 11 - Reserpine is a natural product isolated from the...Ch. 11 - A solution contains 3.75 g of a nonvolatile pure...Ch. 11 - a. Calculate the freezing-point depression and...Ch. 11 - Erythrocytes are red blood cells containing...Ch. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Consider the following solutions: 0.010 m Na3PO4...Ch. 11 - From the following: pure water solution of...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Consider the following representations of an ionic...Ch. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Use the following data for three aqueous solutions...Ch. 11 - The freezing-point depression of a 0.091-m...Ch. 11 - Prob. 89ECh. 11 - A 0.500-g sample of a compound is dissolved in...Ch. 11 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 11 - Prob. 92AECh. 11 - In Exercise 96 in Chapter 8, the pressure of CO2...Ch. 11 - Explain the following on the basis of the behavior...Ch. 11 - The term proof is defined as twice the percent by...Ch. 11 - Prob. 97AECh. 11 - Prob. 98AECh. 11 - A solution is made by mixing 50.0 g acetone...Ch. 11 - Prob. 100AECh. 11 - Thyroxine, an important hormone that controls the...Ch. 11 - Prob. 102AECh. 11 - An unknown compound contains only carbon,...Ch. 11 - Prob. 104AECh. 11 - Prob. 105AECh. 11 - Prob. 106AECh. 11 - Prob. 107AECh. 11 - Prob. 108AECh. 11 - Patients undergoing an upper gastrointestinal...Ch. 11 - Prob. 110CWPCh. 11 - The lattice energy of NaCl is 786 kJ/mol, and the...Ch. 11 - For each of the following pairs, predict which...Ch. 11 - The normal boiling point of methanol is 64.7C. A...Ch. 11 - A solution is prepared by mixing 1.000 mole of...Ch. 11 - Prob. 115CWPCh. 11 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 11 - A solid consists of a mixture of NaNO3 and...Ch. 11 - The vapor pressure of pure benzene is 750.0 torr...Ch. 11 - Prob. 119CPCh. 11 - Plants that thrive in salt water must have...Ch. 11 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 11 - Prob. 122CPCh. 11 - The vapor in equilibrium with a pentane-hexane...Ch. 11 - A forensic chemist is given a white solid that is...Ch. 11 - A 1.60-g sample of a mixture of naphthalene...Ch. 11 - Prob. 126CPCh. 11 - Prob. 127CPCh. 11 - You have a solution of two volatile liquids, A and...Ch. 11 - In some regions of the southwest United States,...Ch. 11 - Creatinine, C4H7N3O, is a by-product of muscle...Ch. 11 - An aqueous solution containing 0.250 mole of Q, a...Ch. 11 - Anthraquinone contains only carbon, hydrogen, and...
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