
(a)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(a)

Answer to Problem 83E
The formula of sulfur difluoride is SF2.
Explanation of Solution
To determine: The formula of of sulfur difluoride
The formula of sulfur difluoride is SF2
Sulfur belongs to the Group VI , the oxidation state of sulfur is +2.
Fluorine is a non-metal of the 7th group.
Oxidation state = Group number−8= 7−8=−1
In SF2 sulfur is cation and fluorine is mono-atomic anion. Here the oxidation state of sulfur is +2 because total charge on anion is −2. Since compound should be electrically neutral, the formula of the given compound is SF2
(b)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(b)

Answer to Problem 83E
The formula of sulfur hexafluoride is SF6
Explanation of Solution
To determine: The formula of sulfur hexafluoride
The formula of sulfur hexafluoride is SF6
Sulfur belongs to the Group VI , the oxidation state of sulfur is +2, +4, +6.
Fluorine is a non-metal of the 7th group.
Oxidation state = Group number−8= 7−8=−1
In SF6 sulfur is cation and fluorine is mono-atomic anion. Here the oxidation state of sulfur is +6 because total charge on anion is −6. Since compound should be electrically neutral, the formula of the given compound is SF6.
(c)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(c)

Answer to Problem 83E
The formula of NaH2PO4 is sodium dihydrogen phosphate.
Explanation of Solution
To determine: The formula of NaH2PO4
The formula of NaH2PO4 is sodium dihydrogen phosphate.
Sodium belongs to the Group I, hence the oxidation state of sodium is +1.
Dihydrogen phosphate is an anion having oxidation state −1
So, the formula of the given compound is NaH2PO4
(d)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(d)

Answer to Problem 83E
The formula of lithium nitride is Li3N
Explanation of Solution
To determine: The formula of lithium nitride
The formula of lithium nitride is Li3N
Lithium belongs to the Group I , the oxidation state of lithium is +1.
Nitrogen is a non-metal of the Vth group.
Oxidation state = Group number−8= 5−8=−3
So, the formula of the given compound is Li3N
(e)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(e)

Answer to Problem 83E
The formula of chromium (III) carbonate is Cr2(CO3)3
Explanation of Solution
To determine: The formula of chromium (III) carbonate.
The formula of chromium (III) carbonate is Cr2(CO3)3
Chromium belongs to the Group VI , the oxidation state of chromium is +3.
Carbonate is an anion having oxidation state −2
So, the formula of the given compound is Cr2(CO3)3
(f)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(f)

Answer to Problem 83E
The formula of tin (II) fluoride is SnF2
Explanation of Solution
To determine: The formula of tin (II) fluoride.
The formula of tin (II) fluoride is SnF2
Tin belongs to the Group 14, the oxidation state of tin is +2.
Fluorine is a non-metal of the 7th group.
Oxidation state = Group number−8= 7−8=−1
So, the formula of the given compound is SnF2
(g)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(g)

Answer to Problem 83E
The formula of ammonium acetate is CH3COONH4
Explanation of Solution
To determine: The formula of ammonium acetate.
The formula of ammonium acetate is CH3COONH4
The oxidation state of ammonium (NH4) is +1.
Acetate (CH3COO) is an anion having oxidation state −1
So, the formula of the given compound is CH3COONH4
(h)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(h)

Answer to Problem 83E
The formula of ammonium hydrogen sulfate is NH4HSO4
Explanation of Solution
To determine: The formula of ammonium hydrogen sulfate.
The formula of ammonium hydrogen sulfate is NH4HSO4
The oxidation state of ammonium (NH4) is +1.
Hydrogen sulfate (HSO4) is an anion having oxidation state −1
So, the formula of the given compound is NH4HSO4
(i)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(i)

Answer to Problem 83E
The formula of cobalt (III) nitrate.is Co(NO3)3
Explanation of Solution
To determine: The formula of cobalt (III) nitrate.
The formula of cobalt (III) nitrate.is Co(NO3)3
The oxidation state of cobalt (Co) is +3.
Nitrate (NO3) is an anion having oxidation state −1
So, the formula of the given compound is Co(NO3)3
(j)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(j)

Answer to Problem 83E
The formula of mercury (I) chloride is Hg2Cl2
Explanation of Solution
To determine: The formula of mercury (I) chloride.
The formula of mercury (I) chloride is Hg2Cl2
The oxidation state of mercury (Hg) is +1.
Chloride (Cl) is an anion having oxidation state −1
Two mercury and chlorine ions is joined to form mercury (I) chloride.
So, the formula of the given compound is Hg2Cl2
(k)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(k)

Answer to Problem 83E
The formula of potassium chlorate is KClO3
Explanation of Solution
To determine: The formula of potassium chlorate.
The formula of potassium chlorate is KClO3
The oxidation state of potassium (K) is +1.
Chlorate (ClO3) is an anion having oxidation state −1
So, the formula of the given compound is KClO3
(l)
Interpretation:
The formula of the binary compound formed from the given pairs of elements in each case is to be stated.
Concept introduction:
The oxidation state of an element corresponds to the group number of that element. In case of non-metals, the oxidation state can be calculated as, group number−8. While naming an ionic compound, the cation is named first followed by the naming of the anion. If the cation exhibits more than one oxidation state then the current oxidation state of the cation is to be mentioned.
(l)

Answer to Problem 83E
The formula of sodium hydride is NaH
Explanation of Solution
To determine: The formula of sodium hydride.
The formula of sodium hydride is NaH
The oxidation state of sodium (Na) is +1.
Hydride (H) is an anion having oxidation state −1
So, the formula of the given compound is NaH
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Chapter 2 Solutions
CHEMISTRY,AP EDITION-W/ACCESS (HS)
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