Solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
Problem 7QAP:
Oxalic acid, H2C2O4, is a poisonous compound found in rhubarb leaves. Draw the Lewis structure for...Problem 8QAP:
Radio astronomers have detected the isoformyl ion, HOC+ in outer space. Write the Lewis structure...Problem 9QAP:
Draw Lewis structures for the following species. (The skeleton is indicated by the way the molecule...Problem 10QAP:
Follow the directions of Question 9 for the following species: (a) (b) Br2C—CF2 (c) H3C—NH2Problem 11QAP:
Dinitrogen pentoxide, N2O5, when bubbled into water can form nitric acid. Its skeleton structure has...Problem 12QAP:
Formic acid is the irritating substance that gets on your skin when an ant bites. Its formula is...Problem 13QAP:
Two different molecules have the formula C2H2Cl2. Draw a Lewis structure for each molecule. (All the...Problem 14QAP:
Two different molecules have the formula C2H6O. One of the molecules has the oxygen atom bonded to...Problem 17QAP:
Write a Lewis structure for (a) XeF3+ (b) PCl4+ (c) BrF5 (d) HPO42- (no P—H or O—O bonds)Problem 19QAP:
Write reasonable Lewis structures for the following species, none of which follow the octet rule....Problem 20QAP:
Write reasonable Lewis structures for the following species, none of which follow the octet rule....Problem 22QAP:
Draw resonance structures for (a) SeO3 (b) CS32- (c) CNO-Problem 25QAP:
The skeleton structure for disulfur dinitride, S2N2, is Draw possible resonance forms of this...Problem 27QAP:
What is the formal charge on the indicated atom in each of the following species? (a) sulfur in SO2...Problem 29QAP:
Below are two different Lewis structures for nitrous acid (HNO2). Which is the better Lewis...Problem 30QAP:
Below are two different Lewis structures for the thiosulfate ion (S2O32-). Which is the better Lewis...Problem 33QAP:
Predict the geometry of the following species: (a) SeOF2 (b) TeF5- (c) ICl4- (d) RnF2Problem 35QAP:
Predict the geometry of the following species: (a) ClF2- (b) SeF5Br (c) SO32- (d) BrO2-Problem 37QAP:
Give all the ideal bond angles (109.5, 120, or 180) in the following molecules and ions. (The...Problem 40QAP:
An objectionable component of smog is acetyl peroxide, which has the following skeleton structure....Problem 41QAP:
The uracil molecule is one of the bases in DNA. Estimate the approximate values of the indicated...Problem 42QAP:
Niacin is one of the B vitamins (B3). Estimate the approximate values of the indicated bond angles....Problem 43QAP:
Which of the species with octets in Question 31 are dipoles?Problem 44QAP:
Which of the species with octets in Question 32 are dipoles?Problem 45QAP:
Which of the species with octets in Question 33 are dipoles?Problem 47QAP:
There are three compounds with the formula C2H2Cl2: and Which of these molecules are polar?Problem 48QAP:
There are two different molecules with the formula N2F2: Is either molecule polar? Explain.Problem 55QAP:
In each of the following polyatomic ions, the central atom has an expanded octet. Determine the...Problem 56QAP:
Follow the directions of Question 55 for the following polyatomic ions. (a) ClF4- (b) GeCl62- (c)...Problem 57QAP:
Give the hybridization of each atom (except H) in the solvent dimethylsulfoxide. (Unshared electron...Problem 58QAP:
Acrylonitrile, C3H3N is the building mer Orlon. Its Lewis structure is What is the hybridization of...Problem 59QAP:
What is the hybridization of nitrogen inProblem 60QAP:
What is the hybridization of carbon inProblem 61QAP:
Give the hybridization of the central atom (underlined in red). (a) COCl2 (b) HNO2 (c) (CH3)2CHCH3Problem 62QAP:
Give the hybridization of the central atom (underlined in red). (a) HOBrO3 (b) Cl2O (c) OPBr3Problem 67QAP:
In which of the following molecules does the sulfur have an expanded octet? For those that do, write...Problem 68QAP:
Consider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write...Problem 69QAP:
Consider acetyl salicylic acid, better known as aspirin. Its structure is (a) How many sigma and pi...Problem 70QAP:
Complete the table on next page.Problem 71QAP:
Given the following electro negativities C=2.5N=3.0S=2.6 what is the central atom in CNS-?Problem 72QAP:
Based on the concept of formal charge, what is the central atom in (a) HCN (do not include H as a...Problem 73QAP:
Describe the geometry of the species in which there are, around the central atom, (a) four single...Problem 74QAP:
Consider the following molecules: SiH4, PH3, H2S. In each case, a central atom is surrounded by four...Problem 76QAP:
In each of the following molecules, a central atom is surrounded by a total of three atoms or...Problem 78QAP:
A compound of chlorine and fluorine, CIFx, reacts at about 75C with uranium to produce uranium...Problem 79QAP:
Draw the Lewis structure and describe the geometry of the hydrazine molecule, N2H4. Would you expect...Problem 80QAP:
Consider the polyatomic ion IO65-. How many pairs of electrons are around the central iodine atom?...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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