Bundle: Chemistry: Principles and React...8th EditionWilliam L. Masterton, Cecile N. Hurley Publisher: Cengage LearningISBN: 9781305717497
Bundle: Chemistry: Principles and React...
Solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
Problem 1QAP:
A photon of violet light has a wavelength of 423 nm. Calculate (a) the frequency. (b) the energy in...Problem 2QAP:
Most retinal tears and detachments are treated by photocoagulation with a laser. A commonly used...Problem 3QAP:
A line in the spectrum of neon has a wavelength of 837.8 nm. (a) In what spectral range does the...Problem 4QAP:
Ozone absorbs energy with a frequency of 1.291015 s1. (a) What is the wavelength (in nm) of the...Problem 5QAP:
The ionization energy of rubidium is 403 kJ/mol. Do x-rays with a wavelength of 85 nm have...Problem 6QAP:
Energy from radiation can cause chemical bonds to break. To break the nitrogen-nitrogen bond in N2...Problem 7QAP:
Lasers are now used for the total or partial removal of skin tattoos. A laser with a wavelenth of...Problem 8QAP:
Your instructor may use a laser pointer while giving a lecture. The pointer uses a red-orange diode...Problem 9QAP:
Consider the transition from the energy levels n=5 to n=3. (a) What is the frequency of light...Problem 10QAP:
Consider the transition from the energy levels n=2 to n=5. (a) What is the wavelength associated...Problem 11QAP:
According to the Bohr model, the radius of a circular orbit is given by the equation r(innm)=0.0529...Problem 12QAP:
Calculate En for n=1,2,3, and 4 (R H=2.1801018J). Make a one-dimensional graph showing energy, at...Problem 13QAP:
For the Pfund series, nlo=5. (a) Calculate the wavelength in nanometers of a transition from n=7 to...Problem 14QAP:
In the Brackett series, nlo=4. (a) Calculate the wavelength in nanometers of a transition from n=6...Problem 15QAP:
A line in the Lyman series (nlo=1) occurs at 97.23 nm. Calculate nhi for the transition associated...Problem 16QAP:
In the Pfund series, nlo=5. Calculate the longest wavelength (in nanometers) possible for a...Problem 17QAP:
What are the possible values for m l for (a) the d sublevel? (b) the s sublevel? (c) all sublevels...Problem 18QAP:
What are the possible values for m l for (a) the d sublevel? (b) the s sublevel? (c) all sublevels...Problem 19QAP:
For the following pairs of orbitals, indicate which is lower in energy in a many-electron atom. (a)...Problem 20QAP:
For the following pairs of orbitals, indicate which is higher in energy in a many-electron atom. (a)...Problem 21QAP:
What type of electron orbital (i.e., s, p, d, or f) is designated by an electron with quantum...Problem 22QAP:
What type of electron orbital (i.e., s, p, d, or f) is designated by (a) n=3,l=1,m l =1?(b)...Problem 23QAP:
What is the total electron capacity for (a) n=3?(b) a 5s orbital? (c) an f subshell? (d) a 7p...Problem 24QAP:
Give the number of orbitals in (a) n=3(b) a 4p sublevel. (c) an f sublevel. (d) a d sublevel.Problem 25QAP:
How many electrons in an atom can following quantum number designations? (a) n=2,l=1,m l =0(b)...Problem 26QAP:
How many electrons in an atom can have the following quantum designation? (a) 1s (b) 4d, m l =0(c)...Problem 27QAP:
Given the following sets of quantum numbers, indicate those that could not occur and explain your...Problem 28QAP:
Given the following sets of electron quantum numbers, indicate those that could not occur, and...Problem 31QAP:
Write an abbreviated ground state electron configuration for (a) N(b) Nb(c) Na (d) Ni (e) NdProblem 33QAP:
Give the symbol of the element of lowest atomic number whose ground state has (a) a completed f...Problem 34QAP:
Give the symbol of the element of lowest atomic number that has (a) an f subshell with 7 electrons....Problem 35QAP:
What fraction of the total number of electrons is in p sublevels for the following atoms? (a) Al (b)...Problem 36QAP:
What fraction of the total number of electrons is in p sublevels in (a) Mg (b) Mn(c) MoProblem 37QAP:
Which of the following electron configurations (af) are for atoms in the ground state? In the...Problem 38QAP:
Which of the following electron configurations (ae) are for atoms in the ground state? In the...Problem 39QAP:
Write the orbital diagram for (a) Li(b) P(c) F(d) FeProblem 43QAP:
Write the symbol of (a) all the elements in which all the 4d orbitals are half-full. (b) all the...Problem 44QAP:
Write the symbols of (a) all the elements in period 5 that have at least two half-filled 5p...Problem 45QAP:
How many unpaired electrons are there in an atom of (a) phosphorus? (b) potassium? (c) plutonium...Problem 46QAP:
How many unpaired electrons are there in the following atoms? (a) aluminum (b) argon (c) arsenicProblem 47QAP:
In what main group(s) of the periodic table do elements have the following number of half-filled...Problem 48QAP:
Give the symbol of the main-group metals in period 4 with the following number of unpaired electrons...Problem 49QAP:
Write the ground state electron configuration for (a) Mg, Mg2+(b) N, N3- (c) Ti, Ti4+ (d) Sn2+ Sn4+Problem 50QAP:
Write the ground state electron configuration for the following atoms and ions. (a) F, F-(b) Sc,...Problem 51QAP:
How many unpaired electrons are there 111 the following ions? (a) V3+(b) Sn4+(c) I-(d) W4+Problem 52QAP:
How many unpaired electrons are there in the following ions? (a) Al3+(b) Cl-(c) Sr2+(d) Zr4+Problem 53QAP:
Arrange the elements Na, Si, and S in the order of (a) decreasing atomic radius. (b) increasing...Problem 54QAP:
Arrange the elements Mg, S, and Cl in order of (a) increasing atomic radius. (b) increasing first...Problem 55QAP:
Which of the four atoms Rb, Sr, Sb, or Cs (a) has the smallest atomic radius? (b) has the lowest...Problem 56QAP:
Which of the four atoms Na, P, Cl, or K (a) has the largest atomic radius? (b) has the highest...Problem 57QAP:
Select the larger member of each pair. (a) Ca and Ca2+ (b) Sr and Sr2+ (c) F and F- (d) Cu+ and Cu2+Problem 58QAP:
Select the smaller member of each pair. (a) P and P3- (b) V2+ and V4+ (c) K and K+ (d) Co and Co3+Problem 61QAP:
A lightbulb radiates 8.5% of the energy supplied to it as visible light. If the wavelength of the...Problem 62QAP:
The speed of a computer chip is measured by its frequency. Advanced Micro Devices (ADM) has...Problem 63QAP:
A carbon dioxide laser produces radiation of wavelength 10.6 micrometers (1micrometer=106meter)....Problem 64QAP:
Name and give the symbol of the element that has the characteristic given below. (a) Its electron...Problem 65QAP:
Compare the energies and frequencies of two photons, one with a short wavelength and the other with...Problem 66QAP:
Consider the following transitions 1. n=3 to n=1 2. n=2 to n=33. n=4 to n=34. n=3 to n=5(a) For...Problem 67QAP:
Write the symbol of each element described below. (a) largest atomic radius in Group 1 (b) smallest...Problem 68QAP:
Answer the following questions. (a) What characteristic of an atomic orbital does the quantum number...Problem 69QAP:
Explain in your own words what is meant by (a) the Pauli exclusion principle. (b) Hund's rule. (c) a...Problem 70QAP:
Explain the difference between (a) the Bohr model of the atom and the quantum mechanical model. (b)...Problem 71QAP:
Indicate whether each of the following statements is true or false. If false, correct the statement....Problem 72QAP:
Criticize or comment on the following statements: (a) The energy of a photon is inversely...Problem 73QAP:
No currently known elements contain electrons in g ( l=4) orbitals in the ground state. If an...Problem 75QAP:
Explain why (a) negative ions are larger than their corresponding atoms. (b) scandium, a transition...Problem 76QAP:
The energy of any one-electron species in its nth state (n=principalquantumnumber) is given by...Problem 77QAP:
In 1885, Johann Balmer, a mathematician, derived the following relation for the wavelength of lines...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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