Solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Problem 1CO:
Explain the economic importance of conversions between different forms of energy and the...Problem 7CO:
• explain Hess’s law in your own words.Problem 9.7PAE:
Define the term internal energy.Problem 9.8PAE:
How fast (in meters per second) must an iron ball with a mass of 56.6 g be traveling in order to...Problem 9.9PAE:
What is the kinetic energy of a single molecule of oxygen if it is traveling at 1.5103m/s ?Problem 9.10PAE:
9.10 The kinetic energy of molecules is often used to induce chemical reactions. The bond energy in...Problem 9.11PAE:
9.11 Analyze the units of the quantity (pressurevolume) and show that they are energy units,...Problem 9.12PAE:
9.12 How many kilojoules are equal to 3.27 L atm of work?Problem 9.15PAE:
9.15 Carry out the following conversions of energy units: (a) 14.3 Btu Into calories, (b) 1.4105 cal...Problem 9.16PAE:
9.16 According to Figure 9.2, the total energy supply in the United States in 2016 was 111.261015...Problem 9.17PAE:
9.17 If a machine does 4.8103kJ of work after an input of 7.31104kJ of heat, what is the change in...Problem 9.18PAE:
9.18 Calculate (a) q when a system does 54J of work and its energy decreases by 72 J and (b) E for a...Problem 9.21PAE:
9.21 Which type of energy heat or work, is valued more by society? What evidence supports your...Problem 9.22PAE:
9.12 PV-work occurs when volume changes and pressure remains constant. If volume is held constant,...Problem 9.24PAE:
9.29 In which case is heat added to the system: (a) E=43J , w=40J ; or (b) E=31J , w=34J ?Problem 9.26PAE:
9.26 Gas furnaces have achieved impressive efficiency levels largely through the addition of a...Problem 9.28PAE:
9.28 When an electrical appliance whose power usage is X watts is run for Y seconds, it uses joules...Problem 9.30PAE:
9.30 For the example of shallow water and sandy beaches, which material has a larger heat capacity...Problem 9.31PAE:
9.31 A metal radiator is made from 26.0 kg of iron. The specific heat of iron is 0.449Jg1C1 . How...Problem 9.32PAE:
9.32 The material typically used to heat metal radiators is water. If a boiler generates water at...Problem 9.33PAE:
9.33 Copper wires used to transport electrical current heat up because of the resistance of the...Problem 9.34PAE:
9.34 A copper nail and an iron nail of the same mass and initially at the same room temperature are...Problem 9.35PAE:
9.35 A piece of titanium metal with a mass of 20.8 g is heated in boiling water to 99.5°C and then...Problem 9.36PAE:
9.36 Define the term calibration.Problem 9.37PAE:
9.37 A calorimeter contained 75.0 g of water at 16.95°C. A 93.3-g sample of iron at 65.58°C was...Problem 9.38PAE:
9.38 The energy densities of various types of coal are listed below: Anthracite 35 kJ/g...Problem 9.39PAE:
9.39 How much thermal energy is required to heat all of the water in a swimming pool by 1°C if the...Problem 9.42PAE:
9.42 Why is enthalpy generally more useful than internal energy in the thermodynamics of real world...Problem 9.45PAE:
9.45 What happens to the temperature of a material as it undergoes an endothermic phase change? If...Problem 9.46PAE:
9.46 The heat of fusion of pure silicon is 43.4 kJ/mol. How much energy would be needed to melt a...Problem 9.47PAE:
9.47 If 14.8 kJ of heat is given off when 1.6 g of HCl condenses from vapor to liquid, what is Hcond...Problem 9.48PAE:
9.48 Calculate the energy required to convert 1.70 g of ice originally at 12.0 C into steam at 105...Problem 9.49PAE:
9.49 Hvap=31.3 kJ/mol for acetone. If 1.40 kg of water were vaporized to steam in a boiler, how much...Problem 9.50PAE:
9.50 When a 13.0-g sample of NaOH(s) dissolves in 400.0 mL of water in a coffee cup calorimeter, the...Problem 9.52PAE:
9.52 Write the formation reaction for each of the following substances. (a) CH4(g) , (b) C3H(l) ,...Problem 9.53PAE:
Explain why each of the following chemical equations is not a correct formation reaction: 4Al( s )+3...Problem 9.54PAE:
Which of the following are state functions? (a) the volume of a balloon, (b) the time it takes to...Problem 9.55PAE:
9.53 Using these reactions, find the standard enthalpy change for the formation of 1 mol of PhO(s)...Problem 9.56PAE:
9.54 The phase change between graphite and diamond is difficult to observe directly. Both substances...Problem 9.57PAE:
9.55 Hydrogen gas will react with either acetylene or ethylene gas. The thermochemical equations for...Problem 9.58PAE:
9.56 Using heats of formation tabulated in Appendix E, calculate the heats of reaction for the...Problem 9.59PAE:
9.57 The heat of combustion of butane is —2877 kJ/mol. Use this value to find the heat of formation...Problem 9.61PAE:
When a reaction is exothermic, is the sum of bond energies of products or of reactants greater?Problem 9.62PAE:
9.58 For the reaction C2H2(g)+2H2(g)C2H6,H=136 kJ. What are the ratios that can be defined between...Problem 9.63PAE:
9.59 For the reaction N2(g)+O2(g)2NO(g),H=180.5kJ . How much energy is needed to generate 35 moles...Problem 9.64PAE:
9.60 Nitroglycenne, C3H5(NO3)3( l ), is an explosive most often used in mine or quarry blasting. It...Problem 9.65PAE:
9.61 Silane, SiH4, burns according to the reaction, SiH4+2O2SiO2+2H2O , with H=1429 kJ. How much...Problem 9.66PAE:
9.62 Sulfur trioxide can be removed from the exhaust gases of power plants hy reaction with lime....Problem 9.67PAE:
9.63 Reactions of hydrocarhons are often studied in the petroleum industry. One example is...Problem 9.69PAE:
9.65 When 0.0157 g of a compound with a heat of combustion of —37.6 kJ/mol is burned in a...Problem 9.73PAE:
9.69 How are the roles of transmission substations and distribution substations in the electrical...Problem 9.74PAE:
9.70 Residential electric service in the United States generally operates at 120 V, but transmission...Problem 9.75PAE:
9.71 In recent years, the notion of a “smart grid” has emerged. Do a web search and research the...Problem 9.76PAE:
9.72 Although it can be a nuisance when a laptop computer freezes up and needs to be rebooted, we...Problem 9.77PAE:
9.85 The figure below shows a "self-cooling" beverage can. The can is equipped with an outer jacket...Problem 9.78PAE:
9.86 You make some iced tea by dropping 134 g of ice into 500.0 mL of warm tea in an insulated...Problem 9.79PAE:
A student performing a calorimetry experiment combined 100.0 ml. of 0.50 M HCI and 100.0 ml. of 0.50...Problem 9.80PAE:
The specific heat of gold is 0.13 J g-1K-1, and that of copper is 0.39 J g-1K-1. Suppose that we...Problem 9.81PAE:
9.87 What will be the final temperature of a mixture made from equal masses of the following: water...Problem 9.83PAE:
9.89 A sample of gas is 80.0% CH4 and 20.0% C2H6 by mass. What is the heat from the combustion of...Problem 9.84PAE:
9.90 Many engineering designs must incorporate ways to dissipate energy in the form of heat. Water...Problem 9.85PAE:
9.91 You want to heat the air in your house with natural gas (CH4). Assume your house has 275...Problem 9.89PAE:
9.95 How much heat is required to convert 250 g of water from liquid at 23°C: into steam at 107°C?...Problem 9.90PAE:
9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in...Problem 9.91PAE:
9.97 Suppose that the working fluid inside an industrial refrigerator absorbs 680 J of energy for...Problem 9.92PAE:
9.98 Hydrogen combines with oxygen in fuel cells according to the thermochemical equation...Problem 9.93PAE:
9.99 The chemical reaction BBr3(g)+BCl3(g)BBr2Cl(g)+BCl2Br(g) , has an enthalpy change very close to...Problem 9.94PAE:
9.100 Two baking sheets are made of different metals. You purchase both and bake a dozen cookies on...Problem 9.96PAE:
9.102 A runner generates 418 kJ of energy per kilometer from the cellular oxidation of food. The...Problem 9.97PAE:
9.103 One reason why the energy density of a fuel is important is that to move a vehicle one must...Browse All Chapters of This Textbook
Chapter 1 - Introduction To ChemistryChapter 2 - Atoms And MoleculesChapter 3 - Molecules, Moles, And Chemical EquationsChapter 4 - StoichiometryChapter 5 - GasesChapter 6 - The Periodic Table And Atomic StructureChapter 7 - Chemical Bonding And Molecular StructureChapter 8 - Molecules And MaterialsChapter 9 - Energy And ChemistryChapter 10 - Entropy And The Second Law Of Thermodynamics
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card homework problems. See examples below:
The increase in application of the aluminum is due to its properties such as strength,...Chapter 1, Problem 1.46PAEChapter 1, Problem 1.47PAEChapter 1, Problem 1.59PAEChapter 1, Problem 1.89PAEChapter 2, Problem 1CODue to isotopes of an element we cannot define atomic mass of the element. Each isotope is present...Place the ion in proper manner cation first then anion. Formation of cation from calcium atom:...Chapter 2, Problem 2.19PAE
In the periodic table, elements increase in metallic nature when approaching the “left” side of the...Chapter 3, Problem 1COChapter 3, Problem 3.16PAEChapter 3, Problem 3.34PAEChapter 3, Problem 3.35PAEChapter 3, Problem 3.43PAEChapter 3, Problem 3.64PAEChapter 3, Problem 3.65PAEChapter 3, Problem 3.66PAEMolarity is defined as the number of moles of solute in 1 L of solution. The final solution is 0.45...Chapter 3, Problem 3.98PAEChapter 4, Problem 1COChapter 4, Problem 4.7PAEChapter 4, Problem 4.10PAEChapter 4, Problem 4.14PAEChapter 4, Problem 4.15PAEChapter 4, Problem 4.26PAEChapter 4, Problem 4.31PAEChapter 4, Problem 4.49PAEChapter 4, Problem 4.72PAEGiven information: Total mass of Alloy = 7.264 g Total mass of H2(g) released out = 0.3284 g...Chapter 4, Problem 4.87PAEReactions given below take place to result the given products....The physical properties of gases are as follows: The gases have no fixed shape and volume. The...Chapter 5, Problem 5.33PAEChapter 5, Problem 5.43PAEChapter 5, Problem 5.47PAEChapter 5, Problem 5.65PAENo of moles of gas =mass of gas molar mass of CH4 =15.0 g16.0 g/m ( mass of CH4( given)=15.0 g)molar...The ideal gas equation is as follows: PV=nRT Or, PV=(mM) RT Or, M=mRT/PV =( 2.298 g)( 0.0821 atm...Chapter 5, Problem 5.89PAEThus, total number of moles = [0.40+0.50+0.30] mol = 1.20 mol = N1 As given total pressure = P = 740...Step 1: Write the chemical equation The SO2 and O2 react to produce SO3 according to the equation: 2...Chapter 5, Problem 5.103PAEChapter 6, Problem 1COChapter 6, Problem 16COPauli’s exclusion principle and Hund’s rule are useful in writing electronic configurations of atoms...Chapter 6, Problem 6.17PAEλ=( hCE)h=6.634×10−34JsC=3×108m/sE=6.0×10−19J Putting these values in above equation you get λ=(...Chapter 6, Problem 6.42PAEAtomic radius is the distance between center of nucleus and outermost electron shell. Atomic radius...Chapter 6, Problem 6.85PAEChapter 6, Problem 6.86PAEChapter 7, Problem 1COChapter 7, Problem 7.72PAEThe electronic configuration of I is [Kr]4d105s25p5. In the excited state, the configuration becomes...The electronic configuration of P is 3s23p33d0. In the excited state, the configuration becomes...The electronic configuration of Xeis 4d105s25p65d0. In the excited state, the configuration becomes...Chapter 7, Problem 7.76PAEIn the structure of diamond each carbon atom is linked to four other carbon atoms forming a three...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...Chapter 9, Problem 1COChapter 9, Problem 9.15PAEChapter 9, Problem 9.16PAEChapter 9, Problem 9.37PAEChapter 9, Problem 9.48PAEChapter 9, Problem 9.52PAEChapter 9, Problem 9.55PAEChapter 9, Problem 9.58PAEChapter 9, Problem 9.79PAEChapter 9, Problem 9.85PAEThe given reaction is: 3CO2(g)+Si3N4(s)→2SiO2(s)+2N2(g)+3C(s) Reaction enthalpy can be calculated...1 barrel of oil can produce 19.5 gallons = 73815.5 mL of gasoline We know, 1 gallon = 3785.41 mL...The causes to obstacles in the recovery and recycling of plastic solid waste in terms of economic,...Based on the thermodynamics third law, ’At absolute zero of temperature, the entropy of every...Chapter 10, Problem 10.47PAEChapter 10, Problem 10.69PAEThe change in Gibbs free energy of a reaction is calculated as follows: ΔG0 = sum of ΔG0 (product) -...Chapter 10, Problem 10.75PAEChapter 10, Problem 10.76PAEChapter 10, Problem 10.84PAEChapter 10, Problem 10.88PAEChapter 10, Problem 10.91PAEChapter 10, Problem 10.101PAEChapter 10, Problem 10.102PAEOzone also formed at ground level but the mechanism and kinetics are very different from that in...Chapter 11, Problem 11.6PAEChapter 11, Problem 11.20PAEChapter 11, Problem 11.24PAEChapter 11, Problem 11.30PAEChapter 11, Problem 11.33PAEChapter 11, Problem 11.35PAEChapter 11, Problem 11.36PAEChapter 11, Problem 11.49PAEGiven Information: The table containing the total pressures in the reaction vessel during the...Chapter 11, Problem 11.57PAEO(g)+N2(g)→NO(g)+ N(g) The rate of the equation for the reaction can be written as follows. R= −k...Chapter 11, Problem 11.70PAE(a) The molar ratio of the reactant molecules, products in balance equation is called stoichiometry....Chapter 12, Problem 1COUsing the formula K = [C]eqc[D]eqd[A]eqa[B]eqb we can calculate the values of equilibrium constants...Chapter 12, Problem 12.36PAEWhen the salt is dissolved in water, it forms the ions. When AgBr is dissolved in water, it...Let solubility of ZnCO3 is 3 then ZnCO 3 ( S ) Zn2+(aq)M C O 3 2− ( aq )M Initial concentration...AgCN(S)⇌Ag+(aq)+CN−(aq)KSP=[Ag+][CN−] Solubility of AgCN is 7.73×10−9M, it means that Concentration...Chapter 12, Problem 12.65PAEChapter 12, Problem 12.67PAECH3COOH(aq)+H2O(l)→CH3COO−(aq)+H3O+(aq) Rate of equilibrium expression...NH3(g)+H2O(l)→NH4+(aq)+OH−(aq) Apply the concept aA+bB⇌cC+dD Rate of equilibrium reaction...The given reaction is as follows:H2(g)+Cl2(g)⇌2HCl(g) First step is to calculate the value of...Here, sulfur dioxide, sodium chloride and water are formed when sodium hydrogen sulfite is reacted...For reaction S(s)+O2(g)⇌SO2(g) Enthalpy change (ΔH0)=ΔHf0[Product]−ΔHf0[Reactants]...There are different types of corrosion: Pitting corrosion: is the most destructive type of...Chapter 13, Problem 3COCell potential in standard condition: Measurement of standard electrode potential of Zn2+/Zn...Chapter 13, Problem 13.26PAEChapter 13, Problem 13.29PAEChapter 13, Problem 13.32PAEIn this reaction, Half-cell reaction at the anode Ga(s)→Ga3+(aq)+3e− Half-cell reaction at the...Chapter 13, Problem 13.39PAEChapter 13, Problem 13.43PAEChapter 13, Problem 13.49PAEChapter 13, Problem 13.104PAEUse the given data to calculate the following: 1st Step: Calculate the total amount of charge...Cosmic rays are divided into mainly three types: galactic cosmic rays, extragalactic cosmic rays and...Because this is an alpha decay, the helium nucleus is ejected with decrease in mass number by 4 and...Atomic numbers of thorium and radium are 90 and 88, respectively. Consider the transformation:...The 232Th radioactive series beginning with 232Th and ending with 208Pb. The sequence occurs as...Given information: The experimentally determined mass of 14C is 14.003242 u. Formula used: E =...Given information: Experimentally determined mass of 7Li is 7.016004 u. Formula used: E = (Δm)c2Δm =...Given information: Experimentally determined mass of 14N is 14.003074 u. Formula used: E = (Δm)c2...Formula used: E = (Δm)c2Δm = Mass defectc = Velocity of light Calculation: Let’s calculate the...92235U+01n→52137Te+4097Zr+201n Apply Einstein’s equation E=Δmc2 Δm= Mass of product − mass of...Write the balanced nuclear reaction. 92235U+01n→3890Sr+54143NP+301n Mass of reactant =mu+mn (putting...The total amount of electrical energy generated by all the nuclear reactors is...Calculating decay constant for A26l as follows: k=0.693t 1 2 k=0.6937.17× 105 yr=9.66×10−7 yr−1 Now,...
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