Bundle: Chemistry for Engineering Stude...3rd EditionLawrence S. Brown, Tom Holme Publisher: Cengage LearningISBN: 9781305367388
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Solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Problem 2CO:
. define the rate of a chemical reaction and express the rate in terms of the concentrations of...Problem 7CO:
. use a molecular perspective to explain the significance of the terms in the Arrhenius equation.Problem 11.3PAE:
In what region of the atmosphere is ozone considered a pollutant? In what region is it considered...Problem 11.4PAE:
What are the steps in the Chapman cycle? Explain the importance.Problem 11.5PAE:
What is the net chemical reaction associated with the Chapman cycle?Problem 11.10PAE:
For each of the following, suggest appropriate rate units Driving from one place to another Drying...Problem 11.11PAE:
For each of the following, suggest an appropriate rate unit. (a) Heart beating (b) Videotape...Problem 11.12PAE:
Rank the following in order of increasing reaction rate. (a) Dynamite exploding (b) Iron rusting (c)...Problem 11.14PAE:
Candle wax is a mixture of hydrocarbons. In the reaction of oxygen with candle w ax in Figure 11.2,...Problem 11.16PAE:
The reaction for the Haber process, the industrial production of ammonia, is N2(g)+3H2(g)2NH3(g)...Problem 11.17PAE:
11.17 Ammonia can react with oxygen to produce nitric oxide and water: 4NH3(g)+5O2(g)4NO(g)+6H2O(g)...Problem 11.18PAE:
The following data were obtained in the decomposition of H2O2(aq) to O2(g) and H2OThe rate at which...Problem 11.20PAE:
Experimental data are listed here for the reaction B: Time (s) IB] (mol/L) 0.00 0.000 10.0 0.326...Problem 11.21PAE:
Azomethane, CH3NNCH3, is not a stable compound, and once generated, it decomposes. The rate of...Problem 11.23PAE:
A reaction has the experimental rate equation Rate = k[A]2. How will the rate change if the...Problem 11.24PAE:
Second-order rate constants used in modeling atmospheric chemistry are commonly reported in units of...Problem 11.25PAE:
For each of the rate laws below, what is the order of the reaction with respect to the hypothetical...Problem 11.26PAE:
11.26 The reaction of C(Xg) with NO2(g) is second order in NO2and zero order in CO at temperatures...Problem 11.29PAE:
The hypothetical reaction, A + B —*C, has the rate law Rate = When [A] is doubled and [B] is held...Problem 11.30PAE:
The rate of the decomposition of hydrogen peroxide, H2O2, depends on the concentration of iodide ion...Problem 11.32PAE:
11.32 The following experimental data were obtained for the reaction 2A + 3 B—C + 2D [A](mol L 1)...Problem 11.33PAE:
The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution....Problem 11.34PAE:
11.34 Rate data were obtained at 25°C for the following reaction. What is the rate law expression...Problem 11.35PAE:
11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) + 2 H,O(g) at 1100°C, the following data have been...Problem 11.36PAE:
The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...Problem 11.39PAE:
The decomposition of N2O5 in solution in carbon tetrachloride is a first-order reaction: 2N2O5 —...Problem 11.40PAE:
In Exercise 11.39, if the initial concentration of N2Oj is 0.100 .\1. how long will it take for the...Problem 11.41PAE:
11.41 For a drug to be effective in treating an illness, its levels in the bloodstream must be...Problem 11.42PAE:
Amoxicillin is an antibiotic packaged as a powder. When it is used to treat babies and small...Problem 11.43PAE:
As with any drug, aspirin (acetylsalicylic acid) must remain in the bloodstream long enough to be...Problem 11.44PAE:
11.44 A possible reaction for the degradation of the pesticide DDT to a less harmful compound was...Problem 11.45PAE:
The initial concentration of the reactant in a tirst-order reaction A —» products is 0.64 rnol/L and...Problem 11.46PAE:
A substance undergoes first-order decomposition. After 40.0 min at 500°C, only 12.5% of the original...Problem 11.48PAE:
11.48 The following data were collected for the decomposition of NT),-: Time, f (min) [N2Os] (mol...Problem 11.49PAE:
The rate of photodecomposition of the herbicide piclo- ram in aqueous systems was determined by...Problem 11.51PAE:
11.51 Peroxyacetyl nitrate (PAN) has the chemical formula CtHjNOj and is an important lung irritant...Problem 11.53PAE:
Hydrogen peroxide (H20i) decomposes into water and oxygen: H,O2(aq) — H,O(f) + ^O2(g) Ordinarily...Problem 11.54PAE:
use the kineticmolecular theory to explain why an increase in temperature increases reaction rate.Problem 11.55PAE:
The activation energy for the reaction in which CO2 decomposes to CO and a free radical oxygen atom,...Problem 11.56PAE:
The labels on most pharmaceuticals state that the medicine should be stored in a cool, dark place....Problem 11.57PAE:
The following rate constants were obtained in an experiment in which the decomposition of gaseous...Problem 11.58PAE:
The table below presents measured rate constants for the reaction of NO with ozone at three...Problem 11.65PAE:
Describe how the Chapman cycle is a reaction mechanism. What is the molecularity of each reaction in...Problem 11.69PAE:
The following mechanism is proposed for a reaction: NO + Br2 —* NOBr2 (slow) NOBr2 + NO —»2 NOBr...Problem 11.70PAE:
11.64 HBr is oxidized in the following reaction: 4 HBr(g) + O2(g) —• 2 H2O(g) + 2 Br,(g) A proposed...Problem 11.72PAE:
If a textbook defined a catalyst as "a substance that increases the rate of a reaction," would that...Problem 11.75PAE:
What distinguishes homogeneous and heterogeneous catalysis?Problem 11.77PAE:
Based on the kinetic theory of matter, what would the action of a catalyst do to a reaction that is...Problem 11.79PAE:
In Chapter 3, we discussed the conversion of biomass into biofuels. One important area of research...Problem 11.80PAE:
The label on a bottle of 3% (by volume) hydrogen peroxide, H2O2, purchased at a grocery store,...Problem 11.95PAE:
11.93 On a particular day, the ozone level in Milwaukee exceeded the EPAs 1-hour standard of 0.12...Problem 11.97PAE:
The following is a thought experiment. Imagine that you put a little water in a test tube and add...Problem 11.98PAE:
The following statements relate to the reaction for the formation of HI: H2(g) + I2(g) -* 2 HI(g)...Problem 11.100PAE:
Experiments show that the reaction of nitrogen dioxide with fluorine, 2 NO2(g) + F2(g) —* 2 FNO2(g)...Problem 11.101PAE:
Substances that poison a catalyst pose a major concern for many engineering designs, including those...Problem 11.104PAE:
11.102 Suppose that you are studying a reaction and need to determine its rate law. Explain what you...Browse All Chapters of This Textbook
Chapter 1 - Introduction To ChemistryChapter 2 - Atoms And MoleculesChapter 3 - Molecules, Moles, And Chemical EquationsChapter 4 - StoichiometryChapter 5 - GasesChapter 6 - The Periodic Table And Atomic StructureChapter 7 - Chemical Bonding And Molecular StructureChapter 8 - Molecules And MaterialsChapter 9 - Energy And ChemistryChapter 10 - Entropy And The Second Law Of Thermodynamics
Sample Solutions for this Textbook
We offer sample solutions for Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card homework problems. See examples below:
The increase in application of the aluminum is due to its properties such as strength,...Chapter 1, Problem 1.46PAEChapter 1, Problem 1.47PAEChapter 1, Problem 1.59PAEChapter 1, Problem 1.89PAEChapter 2, Problem 1CODue to isotopes of an element we cannot define atomic mass of the element. Each isotope is present...Place the ion in proper manner cation first then anion. Formation of cation from calcium atom:...Chapter 2, Problem 2.19PAE
In the periodic table, elements increase in metallic nature when approaching the “left” side of the...Chapter 3, Problem 1COChapter 3, Problem 3.16PAEChapter 3, Problem 3.34PAEChapter 3, Problem 3.35PAEChapter 3, Problem 3.43PAEChapter 3, Problem 3.64PAEChapter 3, Problem 3.65PAEChapter 3, Problem 3.66PAEMolarity is defined as the number of moles of solute in 1 L of solution. The final solution is 0.45...Chapter 3, Problem 3.98PAEChapter 4, Problem 1COChapter 4, Problem 4.7PAEChapter 4, Problem 4.10PAEChapter 4, Problem 4.14PAEChapter 4, Problem 4.15PAEChapter 4, Problem 4.26PAEChapter 4, Problem 4.31PAEChapter 4, Problem 4.49PAEChapter 4, Problem 4.72PAEGiven information: Total mass of Alloy = 7.264 g Total mass of H2(g) released out = 0.3284 g...Chapter 4, Problem 4.87PAEReactions given below take place to result the given products....The physical properties of gases are as follows: The gases have no fixed shape and volume. The...Chapter 5, Problem 5.33PAEChapter 5, Problem 5.43PAEChapter 5, Problem 5.47PAEChapter 5, Problem 5.65PAENo of moles of gas =mass of gas molar mass of CH4 =15.0 g16.0 g/m ( mass of CH4( given)=15.0 g)molar...The ideal gas equation is as follows: PV=nRT Or, PV=(mM) RT Or, M=mRT/PV =( 2.298 g)( 0.0821 atm...Chapter 5, Problem 5.89PAEThus, total number of moles = [0.40+0.50+0.30] mol = 1.20 mol = N1 As given total pressure = P = 740...Step 1: Write the chemical equation The SO2 and O2 react to produce SO3 according to the equation: 2...Chapter 5, Problem 5.103PAEChapter 6, Problem 1COChapter 6, Problem 16COPauli’s exclusion principle and Hund’s rule are useful in writing electronic configurations of atoms...Chapter 6, Problem 6.17PAEλ=( hCE)h=6.634×10−34JsC=3×108m/sE=6.0×10−19J Putting these values in above equation you get λ=(...Chapter 6, Problem 6.42PAEAtomic radius is the distance between center of nucleus and outermost electron shell. Atomic radius...Chapter 6, Problem 6.85PAEChapter 6, Problem 6.86PAEChapter 7, Problem 1COChapter 7, Problem 7.72PAEThe electronic configuration of I is [Kr]4d105s25p5. In the excited state, the configuration becomes...The electronic configuration of P is 3s23p33d0. In the excited state, the configuration becomes...The electronic configuration of Xeis 4d105s25p65d0. In the excited state, the configuration becomes...Chapter 7, Problem 7.76PAEIn the structure of diamond each carbon atom is linked to four other carbon atoms forming a three...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...1 metric ton of silicon = 106 gm of silicon. On conversion of 106 gm of silicon to moles of silicon,...Chapter 9, Problem 1COChapter 9, Problem 9.15PAEChapter 9, Problem 9.16PAEChapter 9, Problem 9.37PAEChapter 9, Problem 9.48PAEChapter 9, Problem 9.52PAEChapter 9, Problem 9.55PAEChapter 9, Problem 9.58PAEChapter 9, Problem 9.79PAEChapter 9, Problem 9.85PAEThe given reaction is: 3CO2(g)+Si3N4(s)→2SiO2(s)+2N2(g)+3C(s) Reaction enthalpy can be calculated...1 barrel of oil can produce 19.5 gallons = 73815.5 mL of gasoline We know, 1 gallon = 3785.41 mL...The causes to obstacles in the recovery and recycling of plastic solid waste in terms of economic,...Based on the thermodynamics third law, ’At absolute zero of temperature, the entropy of every...Chapter 10, Problem 10.47PAEChapter 10, Problem 10.69PAEThe change in Gibbs free energy of a reaction is calculated as follows: ΔG0 = sum of ΔG0 (product) -...Chapter 10, Problem 10.75PAEChapter 10, Problem 10.76PAEChapter 10, Problem 10.84PAEChapter 10, Problem 10.88PAEChapter 10, Problem 10.91PAEChapter 10, Problem 10.101PAEChapter 10, Problem 10.102PAEOzone also formed at ground level but the mechanism and kinetics are very different from that in...Chapter 11, Problem 11.6PAEChapter 11, Problem 11.20PAEChapter 11, Problem 11.24PAEChapter 11, Problem 11.30PAEChapter 11, Problem 11.33PAEChapter 11, Problem 11.35PAEChapter 11, Problem 11.36PAEChapter 11, Problem 11.49PAEGiven Information: The table containing the total pressures in the reaction vessel during the...Chapter 11, Problem 11.57PAEO(g)+N2(g)→NO(g)+ N(g) The rate of the equation for the reaction can be written as follows. R= −k...Chapter 11, Problem 11.70PAE(a) The molar ratio of the reactant molecules, products in balance equation is called stoichiometry....Chapter 12, Problem 1COUsing the formula K = [C]eqc[D]eqd[A]eqa[B]eqb we can calculate the values of equilibrium constants...Chapter 12, Problem 12.36PAEWhen the salt is dissolved in water, it forms the ions. When AgBr is dissolved in water, it...Let solubility of ZnCO3 is 3 then ZnCO 3 ( S ) Zn2+(aq)M C O 3 2− ( aq )M Initial concentration...AgCN(S)⇌Ag+(aq)+CN−(aq)KSP=[Ag+][CN−] Solubility of AgCN is 7.73×10−9M, it means that Concentration...Chapter 12, Problem 12.65PAEChapter 12, Problem 12.67PAECH3COOH(aq)+H2O(l)→CH3COO−(aq)+H3O+(aq) Rate of equilibrium expression...NH3(g)+H2O(l)→NH4+(aq)+OH−(aq) Apply the concept aA+bB⇌cC+dD Rate of equilibrium reaction...The given reaction is as follows:H2(g)+Cl2(g)⇌2HCl(g) First step is to calculate the value of...Here, sulfur dioxide, sodium chloride and water are formed when sodium hydrogen sulfite is reacted...For reaction S(s)+O2(g)⇌SO2(g) Enthalpy change (ΔH0)=ΔHf0[Product]−ΔHf0[Reactants]...There are different types of corrosion: Pitting corrosion: is the most destructive type of...Chapter 13, Problem 3COCell potential in standard condition: Measurement of standard electrode potential of Zn2+/Zn...Chapter 13, Problem 13.26PAEChapter 13, Problem 13.29PAEChapter 13, Problem 13.32PAEIn this reaction, Half-cell reaction at the anode Ga(s)→Ga3+(aq)+3e− Half-cell reaction at the...Chapter 13, Problem 13.39PAEChapter 13, Problem 13.43PAEChapter 13, Problem 13.49PAEChapter 13, Problem 13.104PAEUse the given data to calculate the following: 1st Step: Calculate the total amount of charge...Cosmic rays are divided into mainly three types: galactic cosmic rays, extragalactic cosmic rays and...Because this is an alpha decay, the helium nucleus is ejected with decrease in mass number by 4 and...Atomic numbers of thorium and radium are 90 and 88, respectively. Consider the transformation:...The 232Th radioactive series beginning with 232Th and ending with 208Pb. The sequence occurs as...Given information: The experimentally determined mass of 14C is 14.003242 u. Formula used: E =...Given information: Experimentally determined mass of 7Li is 7.016004 u. Formula used: E = (Δm)c2Δm =...Given information: Experimentally determined mass of 14N is 14.003074 u. Formula used: E = (Δm)c2...Formula used: E = (Δm)c2Δm = Mass defectc = Velocity of light Calculation: Let’s calculate the...92235U+01n→52137Te+4097Zr+201n Apply Einstein’s equation E=Δmc2 Δm= Mass of product − mass of...Write the balanced nuclear reaction. 92235U+01n→3890Sr+54143NP+301n Mass of reactant =mu+mn (putting...The total amount of electrical energy generated by all the nuclear reactors is...Calculating decay constant for A26l as follows: k=0.693t 1 2 k=0.6937.17× 105 yr=9.66×10−7 yr−1 Now,...
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