ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
7th Edition
ISBN: 9781319403959
Author: ATKINS
Publisher: MAC HIGHER
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Chapter F, Problem J.8E
(a)
Interpretation Introduction
Interpretation:
The acid and base solutions that can be used to prepare lead(II) iodide has to be given and also the balanced chemical equation for the neutralization reaction has to be written.
Concept Introduction:
Reaction between the acid and base is known as a neutralization reaction. The product formed in neutralization reaction is salt and water. The net reaction that takes place between the acid and base solutions is that the formation of water from hydrogen ions and hydroxide ions. Neutralization reaction is the one that takes place between a strong acid and a metal hydroxide.
(b)
Interpretation Introduction
Interpretation:
The acid and base solutions that can be used to prepare cadmium sulfide has to be given and also the balanced chemical equation for the neutralization reaction has to be written.
Concept Introduction:
Refer part (a).
(c)
Interpretation Introduction
Interpretation:
The acid and base solutions that can be used to prepare magnesium sulfite has to be given and also the balanced chemical equation for the neutralization reaction has to be written.
Concept Introduction:
Refer part (a).
(d)
Interpretation Introduction
Interpretation:
The acid and base solutions that can be used to prepare iron(II) hypochlorite has to be given and also the balanced chemical equation for the neutralization reaction has to be written.
Concept Introduction:
Refer part (a).
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter F Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
Ch. F - Prob. A.1ASTCh. F - Prob. A.1BSTCh. F - Prob. A.2ASTCh. F - Prob. A.2BSTCh. F - Prob. A.3ASTCh. F - Prob. A.3BSTCh. F - Prob. A.4ASTCh. F - Prob. A.4BSTCh. F - Prob. A.5ASTCh. F - Prob. A.5BST
Ch. F - Prob. A.1ECh. F - Prob. A.2ECh. F - Prob. A.3ECh. F - Prob. A.4ECh. F - Prob. A.5ECh. F - Prob. A.6ECh. F - Prob. A.7ECh. F - Prob. A.8ECh. F - Prob. A.9ECh. F - Prob. A.10ECh. F - Prob. A.11ECh. F - Prob. A.12ECh. F - Prob. A.13ECh. F - Prob. A.14ECh. F - Prob. A.15ECh. F - Prob. A.16ECh. F - Prob. A.17ECh. F - Prob. A.18ECh. F - Prob. A.19ECh. F - Prob. A.20ECh. F - Prob. A.21ECh. F - Prob. A.22ECh. F - Prob. A.23ECh. F - Prob. A.24ECh. F - Prob. A.25ECh. F - Prob. A.26ECh. F - Prob. A.27ECh. F - Prob. A.28ECh. F - Prob. A.29ECh. F - Prob. A.30ECh. F - Prob. A.31ECh. F - Prob. A.32ECh. F - Prob. A.33ECh. F - Prob. A.34ECh. F - Prob. A.35ECh. F - Prob. A.36ECh. F - Prob. A.37ECh. F - Prob. A.38ECh. F - Prob. A.39ECh. F - Prob. A.40ECh. F - Prob. A.41ECh. F - Prob. A.42ECh. F - Prob. B.1ASTCh. F - Prob. B.1BSTCh. F - Prob. B.2ASTCh. F - Prob. B.2BSTCh. F - Prob. B.3ASTCh. F - Prob. B.3BSTCh. F - Prob. B.1ECh. F - Prob. B.2ECh. F - Prob. B.3ECh. F - Prob. B.4ECh. F - Prob. B.5ECh. F - Prob. B.6ECh. F - Prob. B.7ECh. F - Prob. B.8ECh. F - Prob. B.9ECh. F - Prob. B.10ECh. F - Prob. B.11ECh. F - Prob. B.12ECh. F - Prob. B.13ECh. F - Prob. B.14ECh. F - Prob. B.15ECh. F - Prob. B.16ECh. F - Prob. B.17ECh. F - Prob. B.18ECh. F - Prob. B.19ECh. F - Prob. B.20ECh. F - Prob. B.21ECh. F - Prob. B.22ECh. F - Prob. C.1ASTCh. F - Prob. C.1BSTCh. F - Prob. C.2ASTCh. F - Prob. C.2BSTCh. F - Prob. C.1ECh. F - Prob. C.2ECh. F - Prob. C.3ECh. F - Prob. C.4ECh. F - Prob. C.5ECh. F - Prob. C.6ECh. F - Prob. C.7ECh. F - Prob. C.8ECh. F - Prob. C.9ECh. F - Prob. C.10ECh. F - Prob. C.11ECh. F - Prob. C.12ECh. F - Prob. C.13ECh. F - Prob. C.14ECh. F - Prob. C.15ECh. F - Prob. C.16ECh. F - Prob. C.17ECh. F - Prob. C.18ECh. F - Prob. C.19ECh. F - Prob. C.20ECh. F - Prob. C.21ECh. F - Prob. C.22ECh. F - Prob. D.1ASTCh. F - Prob. D.1BSTCh. F - Prob. D.2ASTCh. F - Prob. D.2BSTCh. F - Prob. D.3ASTCh. F - Prob. D.3BSTCh. F - Prob. D.4ASTCh. F - Prob. D.4BSTCh. F - Prob. D.5ASTCh. F - Prob. D.5BSTCh. F - Prob. D.1ECh. F - Prob. D.2ECh. F - Prob. D.3ECh. F - Prob. D.4ECh. F - Prob. D.5ECh. F - Prob. D.6ECh. F - Prob. D.7ECh. F - Prob. D.8ECh. F - Prob. D.9ECh. F - Prob. D.10ECh. F - Prob. D.11ECh. F - Prob. D.12ECh. F - Prob. D.13ECh. F - Prob. D.14ECh. F - Prob. D.15ECh. F - Prob. D.16ECh. F - Prob. D.17ECh. F - Prob. D.18ECh. F - Prob. D.19ECh. F - Prob. D.20ECh. F - Prob. D.21ECh. F - Prob. D.22ECh. F - Prob. D.23ECh. F - Prob. D.24ECh. F - Prob. D.25ECh. F - Prob. D.26ECh. F - Prob. D.27ECh. F - Prob. D.28ECh. F - Prob. D.29ECh. F - Prob. D.30ECh. F - Prob. D.31ECh. F - Prob. D.32ECh. F - Prob. D.33ECh. F - Prob. D.34ECh. F - Prob. D.35ECh. F - Prob. D.36ECh. F - Prob. E.1ASTCh. F - Prob. E.1BSTCh. F - Prob. E.2ASTCh. F - Prob. E.2BSTCh. F - Prob. E.3ASTCh. F - Prob. E.3BSTCh. F - Prob. E.4ASTCh. F - Prob. E.4BSTCh. F - Prob. E.5ASTCh. F - Prob. E.5BSTCh. F - Prob. E.6ASTCh. F - Prob. E.6BSTCh. F - Prob. E.1ECh. F - Prob. E.2ECh. F - Prob. E.3ECh. F - Prob. E.4ECh. F - Prob. E.5ECh. F - Prob. E.6ECh. F - Prob. E.7ECh. F - Prob. E.8ECh. F - Prob. E.9ECh. F - Prob. E.10ECh. F - Prob. E.11ECh. F - Prob. E.12ECh. F - Prob. E.13ECh. F - Prob. E.14ECh. F - Prob. E.15ECh. F - Prob. E.16ECh. F - Prob. E.17ECh. F - Prob. E.18ECh. F - Prob. E.19ECh. F - Prob. E.20ECh. F - Prob. E.21ECh. F - Prob. E.22ECh. F - Prob. E.23ECh. F - Prob. E.24ECh. F - Prob. E.25ECh. F - Prob. E.26ECh. F - Prob. E.27ECh. F - Prob. E.28ECh. F - Prob. E.29ECh. F - Prob. E.30ECh. F - Prob. E.31ECh. F - Prob. E.32ECh. F - Prob. E.33ECh. F - Prob. E.34ECh. F - Prob. F.1ASTCh. F - Prob. F.1BSTCh. F - Prob. F.2ASTCh. F - Prob. F.2BSTCh. F - Prob. F.3ASTCh. F - Prob. F.3BSTCh. F - Prob. F.4ASTCh. F - Prob. F.4BSTCh. F - Prob. F.1ECh. F - Prob. F.2ECh. F - Prob. F.3ECh. F - Prob. F.4ECh. F - Prob. F.5ECh. F - Prob. F.6ECh. F - Prob. F.7ECh. F - Prob. F.8ECh. F - Prob. F.9ECh. F - Prob. F.10ECh. F - Prob. F.11ECh. F - Prob. F.12ECh. F - Prob. F.13ECh. F - Prob. F.14ECh. F - Prob. F.15ECh. F - Prob. F.16ECh. F - Prob. F.17ECh. F - Prob. F.18ECh. F - Prob. F.19ECh. F - Prob. F.20ECh. F - Prob. F.21ECh. F - Prob. F.22ECh. F - Prob. F.23ECh. F - Prob. F.24ECh. F - Prob. F.25ECh. F - Prob. F.26ECh. F - Prob. F.27ECh. F - Prob. F.28ECh. F - Prob. G.1ASTCh. F - Prob. G.1BSTCh. F - Prob. G.2ASTCh. F - Prob. G.2BSTCh. F - Prob. G.3ASTCh. F - Prob. G.3BSTCh. F - Prob. G.4ASTCh. F - Prob. G.4BSTCh. F - Prob. G.1ECh. F - Prob. G.2ECh. F - Prob. G.3ECh. F - Prob. G.4ECh. F - Prob. G.5ECh. F - Prob. G.6ECh. F - Prob. G.7ECh. F - Prob. G.8ECh. F - Prob. G.9ECh. F - Prob. G.10ECh. F - Prob. G.11ECh. F - Prob. G.12ECh. F - Prob. G.13ECh. F - Prob. G.14ECh. F - Prob. G.15ECh. F - Prob. G.16ECh. F - Prob. G.17ECh. F - Prob. G.18ECh. F - Prob. G.19ECh. F - Prob. G.20ECh. F - Prob. G.21ECh. F - Prob. G.22ECh. F - Prob. G.23ECh. F - Prob. G.24ECh. F - Prob. G.25ECh. F - Prob. G.27ECh. F - Prob. G.28ECh. F - Prob. G.30ECh. F - Prob. H.1ASTCh. F - Prob. H.1BSTCh. F - Prob. H.1ECh. F - Prob. H.2ECh. F - Prob. H.3ECh. F - Prob. H.4ECh. F - Prob. H.5ECh. F - Prob. H.6ECh. F - Prob. H.7ECh. F - Prob. H.8ECh. F - Prob. H.9ECh. F - Prob. H.10ECh. F - Prob. H.11ECh. F - Prob. H.12ECh. F - Prob. H.13ECh. F - Prob. H.14ECh. F - Prob. H.15ECh. F - Prob. H.16ECh. F - Prob. H.17ECh. F - Prob. H.18ECh. F - Prob. H.19ECh. F - Prob. H.20ECh. F - Prob. H.21ECh. F - Prob. H.22ECh. F - Prob. H.23ECh. F - Prob. H.24ECh. F - Prob. H.25ECh. F - Prob. H.26ECh. F - Prob. I.1ASTCh. F - Prob. I.1BSTCh. F - Prob. I.2ASTCh. F - Prob. I.2BSTCh. F - Prob. I.3ASTCh. F - Prob. I.3BSTCh. F - Prob. I.1ECh. F - Prob. I.2ECh. F - Prob. I.3ECh. F - Prob. I.4ECh. F - Prob. I.5ECh. F - Prob. I.6ECh. F - Prob. I.7ECh. F - Prob. I.8ECh. F - Prob. I.9ECh. F - Prob. I.10ECh. F - Prob. I.11ECh. F - Prob. I.12ECh. F - Prob. I.13ECh. F - Prob. I.14ECh. F - Prob. I.15ECh. F - Prob. I.16ECh. F - Prob. I.17ECh. F - Prob. I.18ECh. F - Prob. I.19ECh. F - Prob. I.20ECh. F - Prob. I.21ECh. F - Prob. I.22ECh. F - Prob. I.23ECh. F - Prob. I.24ECh. F - Prob. I.25ECh. F - Prob. I.26ECh. F - Prob. J.1ASTCh. F - Prob. J.1BSTCh. F - Prob. J.2ASTCh. F - Prob. J.2BSTCh. F - Prob. J.1ECh. F - Prob. J.2ECh. F - Prob. J.3ECh. F - Prob. J.4ECh. F - Prob. J.5ECh. F - Prob. J.6ECh. F - Prob. J.7ECh. F - Prob. J.8ECh. F - Prob. J.9ECh. F - Prob. J.10ECh. F - Prob. J.11ECh. F - Prob. J.12ECh. F - Prob. J.13ECh. F - Prob. J.14ECh. F - Prob. J.15ECh. F - Prob. J.16ECh. F - Prob. J.17ECh. F - Prob. J.18ECh. F - Prob. J.19ECh. F - Prob. J.20ECh. F - Prob. J.21ECh. F - Prob. J.22ECh. F - Prob. J.23ECh. F - Prob. J.24ECh. F - Prob. K.1ASTCh. F - Prob. K.1BSTCh. F - Prob. K.2ASTCh. F - Prob. K.2BSTCh. F - Prob. K.3ASTCh. F - Prob. K.3BSTCh. F - Prob. K.4ASTCh. F - Prob. K.4BSTCh. F - Prob. K.5ASTCh. F - Prob. K.5BSTCh. F - Prob. K.1ECh. F - Prob. K.2ECh. F - Prob. K.3ECh. F - Prob. K.4ECh. F - Prob. K.5ECh. F - Prob. K.6ECh. F - Prob. K.7ECh. F - Prob. K.8ECh. F - Prob. K.9ECh. F - Prob. K.10ECh. F - Prob. K.11ECh. F - Prob. K.12ECh. F - Prob. K.13ECh. F - Prob. K.14ECh. F - Prob. K.15ECh. F - Prob. K.16ECh. F - Prob. K.17ECh. F - Prob. K.18ECh. F - Prob. K.19ECh. F - Prob. K.20ECh. F - Prob. K.21ECh. F - Prob. K.22ECh. F - Prob. K.23ECh. F - Prob. K.24ECh. F - Prob. K.25ECh. F - Prob. K.26ECh. F - Prob. L.1ASTCh. F - Prob. L.1BSTCh. F - Prob. L.2ASTCh. F - Prob. L.2BSTCh. F - Prob. L.3ASTCh. F - Prob. L.3BSTCh. F - Prob. L.1ECh. F - Prob. L.2ECh. F - Prob. L.3ECh. F - Prob. L.4ECh. F - Prob. L.5ECh. F - Prob. L.6ECh. F - Prob. L.7ECh. F - Prob. L.8ECh. F - Prob. L.9ECh. F - Prob. L.10ECh. F - Prob. L.11ECh. F - Prob. L.12ECh. F - Prob. L.13ECh. F - Prob. L.14ECh. F - Prob. L.15ECh. F - Prob. L.16ECh. F - Prob. L.17ECh. F - Prob. L.18ECh. F - Prob. L.19ECh. F - Prob. L.20ECh. F - Prob. L.21ECh. F - Prob. L.22ECh. F - Prob. L.23ECh. F - Prob. L.24ECh. F - Prob. L.25ECh. F - Prob. L.29ECh. F - Prob. L.30ECh. F - Prob. L.31ECh. F - Prob. L.32ECh. F - Prob. L.33ECh. F - Prob. L.34ECh. F - Prob. L.35ECh. F - Prob. L.37ECh. F - Prob. L.38ECh. F - Prob. L.39ECh. F - Prob. L.40ECh. F - Prob. L.41ECh. F - Prob. L.42ECh. F - Prob. M.1ASTCh. F - Prob. M.1BSTCh. F - Prob. M.2ASTCh. F - Prob. M.2BSTCh. F - Prob. M.3ASTCh. F - Prob. M.3BSTCh. F - Prob. M.4ASTCh. F - Prob. M.4BSTCh. F - Prob. M.1ECh. F - Prob. M.2ECh. F - Prob. M.3ECh. F - Prob. M.4ECh. F - Prob. M.5ECh. F - Prob. M.6ECh. F - Prob. M.7ECh. F - Prob. M.8ECh. F - Prob. M.9ECh. F - Prob. M.10ECh. F - Prob. M.11ECh. F - Prob. M.12ECh. F - Prob. M.13ECh. F - Prob. M.14ECh. F - Prob. M.15ECh. F - Prob. M.16ECh. F - Prob. M.17ECh. F - Prob. M.18ECh. F - Prob. M.19ECh. F - Prob. M.20ECh. F - Prob. M.21ECh. F - Prob. M.22ECh. F - Prob. M.23ECh. F - Prob. M.25ECh. F - Prob. M.26ECh. F - Prob. M.27ECh. F - Prob. M.28E
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