ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
7th Edition
ISBN: 9781319403959
Author: ATKINS
Publisher: MAC HIGHER
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Chapter F, Problem G.30E
Interpretation Introduction
Interpretation:
Total mass of lead that is ingested per year from tap water has to be calculated.
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Problem 19 of 48
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Curved arrows are used to
illustrate the flow of electrons.
Use the reaction conditions
provided and follow the curved
arrows to draw the product of
this carbocation rearrangement.
Include all lone pairs and
charges as appropriate.
H
1,2-alkyl shift
+
Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
Below is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide (OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero
formal charges. In the third box, draw the two enantiomeric products that will be produced.
5th attempt
Please draw all four bonds at chiral centers.
Draw the two enantiomeric products that will be produced. Draw in any hydrogen at chiral centers.
1000
4th attempt
Feedback
Please draw all four bonds at chiral centers.
8.
R5
HO:
See Periodic Table
See Hint
H
Cl
Br
Jid See Periodic Table See Hint
Chapter F Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
Ch. F - Prob. A.1ASTCh. F - Prob. A.1BSTCh. F - Prob. A.2ASTCh. F - Prob. A.2BSTCh. F - Prob. A.3ASTCh. F - Prob. A.3BSTCh. F - Prob. A.4ASTCh. F - Prob. A.4BSTCh. F - Prob. A.5ASTCh. F - Prob. A.5BST
Ch. F - Prob. A.1ECh. F - Prob. A.2ECh. F - Prob. A.3ECh. F - Prob. A.4ECh. F - Prob. A.5ECh. F - Prob. A.6ECh. F - Prob. A.7ECh. F - Prob. A.8ECh. F - Prob. A.9ECh. F - Prob. A.10ECh. F - Prob. A.11ECh. F - Prob. A.12ECh. F - Prob. A.13ECh. F - Prob. A.14ECh. F - Prob. A.15ECh. F - Prob. A.16ECh. F - Prob. A.17ECh. F - Prob. A.18ECh. F - Prob. A.19ECh. F - Prob. A.20ECh. F - Prob. A.21ECh. F - Prob. A.22ECh. F - Prob. A.23ECh. F - Prob. A.24ECh. F - Prob. A.25ECh. F - Prob. A.26ECh. F - Prob. A.27ECh. F - Prob. A.28ECh. F - Prob. A.29ECh. F - Prob. A.30ECh. F - Prob. A.31ECh. F - Prob. A.32ECh. F - Prob. A.33ECh. F - Prob. A.34ECh. F - Prob. A.35ECh. F - Prob. A.36ECh. F - Prob. A.37ECh. F - Prob. A.38ECh. F - Prob. A.39ECh. F - Prob. A.40ECh. F - Prob. A.41ECh. F - Prob. A.42ECh. F - Prob. B.1ASTCh. F - Prob. B.1BSTCh. F - Prob. B.2ASTCh. F - Prob. B.2BSTCh. F - Prob. B.3ASTCh. F - Prob. B.3BSTCh. F - Prob. B.1ECh. F - Prob. B.2ECh. F - Prob. B.3ECh. F - Prob. B.4ECh. F - Prob. B.5ECh. F - Prob. B.6ECh. F - Prob. B.7ECh. F - Prob. B.8ECh. F - Prob. B.9ECh. F - Prob. B.10ECh. F - Prob. B.11ECh. F - Prob. B.12ECh. F - Prob. B.13ECh. F - Prob. B.14ECh. F - Prob. B.15ECh. F - Prob. B.16ECh. F - Prob. B.17ECh. F - Prob. B.18ECh. F - Prob. B.19ECh. F - Prob. B.20ECh. F - Prob. B.21ECh. F - Prob. B.22ECh. F - Prob. C.1ASTCh. F - Prob. C.1BSTCh. F - Prob. C.2ASTCh. F - Prob. C.2BSTCh. F - Prob. C.1ECh. F - Prob. C.2ECh. F - Prob. C.3ECh. F - Prob. C.4ECh. F - Prob. C.5ECh. F - Prob. C.6ECh. F - Prob. C.7ECh. F - Prob. C.8ECh. F - Prob. C.9ECh. F - Prob. C.10ECh. F - Prob. C.11ECh. F - Prob. C.12ECh. F - Prob. C.13ECh. F - Prob. C.14ECh. F - Prob. C.15ECh. F - Prob. C.16ECh. F - Prob. C.17ECh. F - Prob. C.18ECh. F - Prob. C.19ECh. F - Prob. C.20ECh. F - Prob. C.21ECh. F - Prob. C.22ECh. F - Prob. D.1ASTCh. F - Prob. D.1BSTCh. F - Prob. D.2ASTCh. F - Prob. D.2BSTCh. F - Prob. D.3ASTCh. F - Prob. D.3BSTCh. F - Prob. D.4ASTCh. F - Prob. D.4BSTCh. F - Prob. D.5ASTCh. F - Prob. D.5BSTCh. F - Prob. D.1ECh. F - Prob. D.2ECh. F - Prob. D.3ECh. F - Prob. D.4ECh. F - Prob. D.5ECh. F - Prob. D.6ECh. F - Prob. D.7ECh. F - Prob. D.8ECh. F - Prob. D.9ECh. F - Prob. D.10ECh. F - Prob. D.11ECh. F - Prob. D.12ECh. F - Prob. D.13ECh. F - Prob. D.14ECh. F - Prob. D.15ECh. F - Prob. D.16ECh. F - Prob. D.17ECh. F - Prob. D.18ECh. F - Prob. D.19ECh. F - Prob. D.20ECh. F - Prob. D.21ECh. F - Prob. D.22ECh. F - Prob. D.23ECh. F - Prob. D.24ECh. F - Prob. D.25ECh. F - Prob. D.26ECh. F - Prob. D.27ECh. F - Prob. D.28ECh. F - Prob. D.29ECh. F - Prob. D.30ECh. F - Prob. D.31ECh. F - Prob. D.32ECh. F - Prob. D.33ECh. F - Prob. D.34ECh. F - Prob. D.35ECh. F - Prob. D.36ECh. F - Prob. E.1ASTCh. F - Prob. E.1BSTCh. F - Prob. E.2ASTCh. F - Prob. E.2BSTCh. F - Prob. E.3ASTCh. F - Prob. E.3BSTCh. F - Prob. E.4ASTCh. F - Prob. E.4BSTCh. F - Prob. E.5ASTCh. F - Prob. E.5BSTCh. F - Prob. E.6ASTCh. F - Prob. E.6BSTCh. F - Prob. E.1ECh. F - Prob. E.2ECh. F - Prob. E.3ECh. F - Prob. E.4ECh. F - Prob. E.5ECh. F - Prob. E.6ECh. F - Prob. E.7ECh. F - Prob. E.8ECh. F - Prob. E.9ECh. F - Prob. E.10ECh. F - Prob. E.11ECh. F - Prob. E.12ECh. F - Prob. E.13ECh. F - Prob. E.14ECh. F - Prob. E.15ECh. F - Prob. E.16ECh. F - Prob. E.17ECh. F - Prob. E.18ECh. F - Prob. E.19ECh. F - Prob. E.20ECh. F - Prob. E.21ECh. F - Prob. E.22ECh. F - Prob. E.23ECh. F - Prob. E.24ECh. F - Prob. E.25ECh. F - Prob. E.26ECh. F - Prob. E.27ECh. F - Prob. E.28ECh. F - Prob. E.29ECh. F - Prob. E.30ECh. F - Prob. E.31ECh. F - Prob. E.32ECh. F - Prob. E.33ECh. F - Prob. E.34ECh. F - Prob. F.1ASTCh. F - Prob. F.1BSTCh. F - Prob. F.2ASTCh. F - Prob. F.2BSTCh. F - Prob. F.3ASTCh. F - Prob. F.3BSTCh. F - Prob. F.4ASTCh. F - Prob. F.4BSTCh. F - Prob. F.1ECh. F - Prob. F.2ECh. F - Prob. F.3ECh. F - Prob. F.4ECh. F - Prob. F.5ECh. F - Prob. F.6ECh. F - Prob. F.7ECh. F - Prob. F.8ECh. F - Prob. F.9ECh. F - Prob. F.10ECh. F - Prob. F.11ECh. F - Prob. F.12ECh. F - Prob. F.13ECh. F - Prob. F.14ECh. F - Prob. F.15ECh. F - Prob. F.16ECh. F - Prob. F.17ECh. F - Prob. F.18ECh. F - Prob. F.19ECh. F - Prob. F.20ECh. F - Prob. F.21ECh. F - Prob. F.22ECh. F - Prob. F.23ECh. F - Prob. F.24ECh. F - Prob. F.25ECh. F - Prob. F.26ECh. F - Prob. F.27ECh. F - Prob. F.28ECh. F - Prob. G.1ASTCh. F - Prob. G.1BSTCh. F - Prob. G.2ASTCh. F - Prob. G.2BSTCh. F - Prob. G.3ASTCh. F - Prob. G.3BSTCh. F - Prob. G.4ASTCh. F - Prob. G.4BSTCh. F - Prob. G.1ECh. F - Prob. G.2ECh. F - Prob. G.3ECh. F - Prob. G.4ECh. F - Prob. G.5ECh. F - Prob. G.6ECh. F - Prob. G.7ECh. F - Prob. G.8ECh. F - Prob. G.9ECh. F - Prob. G.10ECh. F - Prob. G.11ECh. F - Prob. G.12ECh. F - Prob. G.13ECh. F - Prob. G.14ECh. F - Prob. G.15ECh. F - Prob. G.16ECh. F - Prob. G.17ECh. F - Prob. G.18ECh. F - Prob. G.19ECh. F - Prob. G.20ECh. F - Prob. G.21ECh. F - Prob. G.22ECh. F - Prob. G.23ECh. F - Prob. G.24ECh. F - Prob. G.25ECh. F - Prob. G.27ECh. F - Prob. G.28ECh. F - Prob. G.30ECh. F - Prob. H.1ASTCh. F - Prob. H.1BSTCh. F - Prob. H.1ECh. F - Prob. H.2ECh. F - Prob. H.3ECh. F - Prob. H.4ECh. F - Prob. H.5ECh. F - Prob. H.6ECh. F - Prob. H.7ECh. F - Prob. H.8ECh. F - Prob. H.9ECh. F - Prob. H.10ECh. F - Prob. H.11ECh. F - Prob. H.12ECh. F - Prob. H.13ECh. F - Prob. H.14ECh. F - Prob. H.15ECh. F - Prob. H.16ECh. F - Prob. H.17ECh. F - Prob. H.18ECh. F - Prob. H.19ECh. F - Prob. H.20ECh. F - Prob. H.21ECh. F - Prob. H.22ECh. F - Prob. H.23ECh. F - Prob. H.24ECh. F - Prob. H.25ECh. F - Prob. H.26ECh. F - Prob. I.1ASTCh. F - Prob. I.1BSTCh. F - Prob. I.2ASTCh. F - Prob. I.2BSTCh. F - Prob. I.3ASTCh. F - Prob. I.3BSTCh. F - Prob. I.1ECh. F - Prob. I.2ECh. F - Prob. I.3ECh. F - Prob. I.4ECh. F - Prob. I.5ECh. F - Prob. I.6ECh. F - Prob. I.7ECh. F - Prob. I.8ECh. F - Prob. I.9ECh. F - Prob. I.10ECh. F - Prob. I.11ECh. F - Prob. I.12ECh. F - Prob. I.13ECh. F - Prob. I.14ECh. F - Prob. I.15ECh. F - Prob. I.16ECh. F - Prob. I.17ECh. F - Prob. I.18ECh. F - Prob. I.19ECh. F - Prob. I.20ECh. F - Prob. I.21ECh. F - Prob. I.22ECh. F - Prob. I.23ECh. F - Prob. I.24ECh. F - Prob. I.25ECh. F - Prob. I.26ECh. F - Prob. J.1ASTCh. F - Prob. J.1BSTCh. F - Prob. J.2ASTCh. F - Prob. J.2BSTCh. F - Prob. J.1ECh. F - Prob. J.2ECh. F - Prob. J.3ECh. F - Prob. J.4ECh. F - Prob. J.5ECh. F - Prob. J.6ECh. F - Prob. J.7ECh. F - Prob. J.8ECh. F - Prob. J.9ECh. F - Prob. J.10ECh. F - Prob. J.11ECh. F - Prob. J.12ECh. F - Prob. J.13ECh. F - Prob. J.14ECh. F - Prob. J.15ECh. F - Prob. J.16ECh. F - Prob. J.17ECh. F - Prob. J.18ECh. F - Prob. J.19ECh. F - Prob. J.20ECh. F - Prob. J.21ECh. F - Prob. J.22ECh. F - Prob. J.23ECh. F - Prob. J.24ECh. F - Prob. K.1ASTCh. F - Prob. K.1BSTCh. F - Prob. K.2ASTCh. F - Prob. K.2BSTCh. F - Prob. K.3ASTCh. F - Prob. K.3BSTCh. F - Prob. K.4ASTCh. F - Prob. K.4BSTCh. F - Prob. K.5ASTCh. F - Prob. K.5BSTCh. F - Prob. K.1ECh. F - Prob. K.2ECh. F - Prob. K.3ECh. F - Prob. K.4ECh. F - Prob. K.5ECh. F - Prob. K.6ECh. F - Prob. K.7ECh. F - Prob. K.8ECh. F - Prob. K.9ECh. F - Prob. K.10ECh. F - Prob. K.11ECh. F - Prob. K.12ECh. F - Prob. K.13ECh. F - Prob. K.14ECh. F - Prob. K.15ECh. F - Prob. K.16ECh. F - Prob. K.17ECh. F - Prob. K.18ECh. F - Prob. K.19ECh. F - Prob. K.20ECh. F - Prob. K.21ECh. F - Prob. K.22ECh. F - Prob. K.23ECh. F - Prob. K.24ECh. F - Prob. K.25ECh. F - Prob. K.26ECh. F - Prob. L.1ASTCh. F - Prob. L.1BSTCh. F - Prob. L.2ASTCh. F - Prob. L.2BSTCh. F - Prob. L.3ASTCh. F - Prob. L.3BSTCh. F - Prob. L.1ECh. F - Prob. L.2ECh. F - Prob. L.3ECh. F - Prob. L.4ECh. F - Prob. L.5ECh. F - Prob. L.6ECh. F - Prob. L.7ECh. F - Prob. L.8ECh. F - Prob. L.9ECh. F - Prob. L.10ECh. F - Prob. L.11ECh. F - Prob. L.12ECh. F - Prob. L.13ECh. F - Prob. L.14ECh. F - Prob. L.15ECh. F - Prob. L.16ECh. F - Prob. L.17ECh. F - Prob. L.18ECh. F - Prob. L.19ECh. F - Prob. L.20ECh. F - Prob. L.21ECh. F - Prob. L.22ECh. F - Prob. L.23ECh. F - Prob. L.24ECh. F - Prob. L.25ECh. F - Prob. L.29ECh. F - Prob. L.30ECh. F - Prob. L.31ECh. F - Prob. L.32ECh. F - Prob. L.33ECh. F - Prob. L.34ECh. F - Prob. L.35ECh. F - Prob. L.37ECh. F - Prob. L.38ECh. F - Prob. L.39ECh. F - Prob. L.40ECh. F - Prob. L.41ECh. F - Prob. L.42ECh. F - Prob. M.1ASTCh. F - Prob. M.1BSTCh. F - Prob. M.2ASTCh. F - Prob. M.2BSTCh. F - Prob. M.3ASTCh. F - Prob. M.3BSTCh. F - Prob. M.4ASTCh. F - Prob. M.4BSTCh. F - Prob. M.1ECh. F - Prob. M.2ECh. F - Prob. M.3ECh. F - Prob. M.4ECh. F - Prob. M.5ECh. F - Prob. M.6ECh. F - Prob. M.7ECh. F - Prob. M.8ECh. F - Prob. M.9ECh. F - Prob. M.10ECh. F - Prob. M.11ECh. F - Prob. M.12ECh. F - Prob. M.13ECh. F - Prob. M.14ECh. F - Prob. M.15ECh. F - Prob. M.16ECh. F - Prob. M.17ECh. F - Prob. M.18ECh. F - Prob. M.19ECh. F - Prob. M.20ECh. F - Prob. M.21ECh. F - Prob. M.22ECh. F - Prob. M.23ECh. F - Prob. M.25ECh. F - Prob. M.26ECh. F - Prob. M.27ECh. F - Prob. M.28E
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- Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.arrow_forward(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.arrow_forwardCan I please get help with #3 & 4? Thanks you so much!arrow_forward
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- (a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?arrow_forwardShow the curved arrow mechanism and both products for the reaction between methyl iodide and propoxide. 1st attempt NV H 10: H H 1 Add the missing curved arrow notation. H + See Periodic Tablearrow_forwardFirst I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.arrow_forward
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