Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter F, Problem F.4P
Interpretation Introduction
Interpretation:
The correct IUPAC name for shikimic acid is to be written.
Concept introduction:
To write the IUPAC name, the highest priority functional group is identified first and its suffix is added to a root. Then, other lower priority
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Draw the anti-Markovnikov product of the hydration of this alkene.
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter F Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. F - Prob. F.1PCh. F - Prob. F.2PCh. F - Prob. F.3PCh. F - Prob. F.4PCh. F - Prob. F.5PCh. F - Prob. F.6PCh. F - Prob. F.7PCh. F - Prob. F.8PCh. F - Prob. F.9PCh. F - Prob. F.10P
Ch. F - Prob. F.11PCh. F - Prob. F.12PCh. F - Prob. F.13PCh. F - Prob. F.14PCh. F - Prob. F.15PCh. F - Prob. F.16PCh. F - Prob. F.17PCh. F - Prob. F.18PCh. F - Prob. F.19PCh. F - Prob. F.20PCh. F - Prob. F.21PCh. F - Prob. F.22PCh. F - Prob. F.23PCh. F - Prob. F.24PCh. F - Prob. F.25PCh. F - Prob. F.26PCh. F - Prob. F.27PCh. F - Prob. F.28PCh. F - Prob. F.29PCh. F - Prob. F.30PCh. F - Prob. F.31PCh. F - Prob. F.32PCh. F - Prob. F.33PCh. F - Prob. F.34PCh. F - Prob. F.35P
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Nomenclature: Crash Course Chemistry #44; Author: CrashCourse;https://www.youtube.com/watch?v=U7wavimfNFE;License: Standard YouTube License, CC-BY