Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter A, Problem A.9P
Interpretation Introduction

Interpretation:

The IUPAC name of the molecule shown is to be written.

Concept introduction:

The root name of an alkane is determined on the basis of the longest chain of carbons. If the compound also contains a ring with more carbon atoms, then the root name is determined on the basis of number of the ring carbons, as a cycloalkane. If there are multiple substituents on the ring, the ring carbon with the greatest number of substituents is numbered 1. The rest of the ring carbons are then numbered so that the next substituent gets the lowest number. The substituents are named alphabetically. Their positions are indicated by numbers preceding the names. The numbers and names of substituents are separated by dashes. If the same substituent occurs more than once, the number is indicated by a prefix di-, tri- etc., with the positions of both indicated by appropriate numbers.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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