(a) Interpretation: The IUPAC name of the ter-butyl ethyl ether is to be written. Concept introduction: The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

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Answer 1

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Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

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Answer 3

Question

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

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Answer 4

Question

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

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Answer 5

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 6

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 7

Chapter A, Problem A.17P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ter-butyl ethyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the cyclohexyl methyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of sec-butyl propyl ether is to be written.

Concept introduction:

The IUPAC name of an ether is written in the form of alkoxyalkane. Out of the two alkyl groups attached to the oxygen atom, the longest carbon chain is considered as the root. The other alkyl group is written as an alkoxy substituent. The name of the alkoxy substituent is obtained by replacing the suffix –yl from the name of the alkyl group by the suffix –oxy.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

Solution Summary: The author explains that the IUPAC name of ter-butyl ether is written in the form of alkoxyalkane.

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