(a) Interpretation: The structure of 2-cyclopropoxypentane is to be drawn. Concept introduction: The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

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Answer 1

Question

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

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Draw the structure corresponding to each IUPAC name. a.3-ethyl-2-methylhexane b. sec-butylcyclopentane c.4-isopropyl-2,4,5-trimethylundecane d.cyclobutylcycloheptane e.3-ethyl-1,1-dimethylcyclohexane f. 4-butyl-1,1-diethylcyclooctane g.6-isopropyl-2,3-dimethyldodecane h. 2,2,6,6,7-pentamethyloctane i. cis-1-ethyl-3-methylcyclopentane j. trans-1-tert-butyl-4-ethylcyclohexane

Each of the following IUPAC names is incorrect. Explain why it is incorrect and give the correct IUPAC name. a. 4-methylpentane b. 2,3,3-trimethylbutane c. 1,3-dimethylpentane d. 3-methyl-5-ethylhexane e. 2-ethyl-2-methylcycloheptane f. 1,6-diethylcyclohexane

CH3 2. Give the structure corresponding to each IUPAC name. a. 3-ethyl-3-methylhexane b. 2-ethyl-1-methyl-3-propylcyclopentane c. 3-methylbutane d. 1-ethyl-2,3-dimethylcyclopentane e. 1,5-dimethylcyclohexane

Answer 2

Question

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

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Answer 3

Question

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

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Answer 4

Question

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

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Answer 5

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 6

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 7

Chapter A, Problem A.34P

Interpretation Introduction

(a)

Interpretation:

The structure of 2-cyclopropoxypentane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of 1, 2-dimethoxy-4-propylcyclohexane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of 4-(1, 1-dimethylethyl)-1, 2-dipropoxycyclooctane is to be drawn.

Concept introduction:

The root name of the longest carbon chain is the alkane name at the end of the compound’s name. The names of the substituents along with numbers indicate their positions on the longest carbon chain. A prefix of the substituent name shows their numbers. The oxygen atom is attached to the alkyl group. The name of the oxygen atom attached to the alkyl group is alkoxy group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

Solution Summary: The structure of 2-cyclopropoxypentane is Explanation: the root name of the longest carbon chain is the alkane name.

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