Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter A, Problem A.11P
Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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