(a) Interpretation: IUPAC name for the molecule is to be written. Concept introduction: In the IUPAC nomenclature , the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

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Answer 1

Question

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

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Answer 3

Question

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

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Answer 4

Question

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

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Answer 5

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 6

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 7

Chapter A, Problem A.25P

Interpretation Introduction

(a)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 8

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 9

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 10

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 11

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

In the IUPAC nomenclature, the longest continuous carbon chain is considered as the parent chain. The name of this corresponding parent chain will be the root of the molecule’s name. Identify the substituents and add the name of the substituent as a prefix to the left of the root. In case of two or more different substituents, the alphabetical order is considered. Number each carbon atom of the chain sequentially, beginning with C1 at one end of the chain, so that the carbon atom to which the substituent is bonded receives the lowest possible number. If each choice for C1 results in a tie for the locator number of the first substituent, then C1 is chosen so that the second substituent encountered has the lowest locator number. The number assigned to the carbon that is bonded to the substituent is called the locator number or locant. The locator number is written to the left of the substituent name and a hyphen is added to separate the locator number from the rest of the name.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

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