General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 9, Problem 9.84EP
Based on the diagrams,
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0
2.
Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the
two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction
energies in order to identify the lower energy conformer for each stereoisomer. Based on your
calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable.
[1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3
CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol)
all-cis-1,2,3-
1
all-cis-1,2,4-
2
None
Chapter 9 Solutions
General, Organic, and Biological Chemistry
Ch. 9.1 - Prob. 1QQCh. 9.1 - Prob. 2QQCh. 9.1 - Prob. 3QQCh. 9.2 - The proper assignment of oxidation numbers to the...Ch. 9.2 - The proper assignment of oxidation numbers to the...Ch. 9.2 - Prob. 3QQCh. 9.3 - Prob. 1QQCh. 9.3 - Prob. 2QQCh. 9.3 - Prob. 3QQCh. 9.3 - Prob. 4QQ
Ch. 9.3 - Prob. 5QQCh. 9.4 - Prob. 1QQCh. 9.4 - Prob. 2QQCh. 9.4 - Prob. 3QQCh. 9.5 - Prob. 1QQCh. 9.5 - Prob. 2QQCh. 9.5 - For endothermic chemical reactions the energy...Ch. 9.6 - Prob. 1QQCh. 9.6 - Prob. 2QQCh. 9.6 - Prob. 3QQCh. 9.7 - Prob. 1QQCh. 9.7 - Prob. 2QQCh. 9.7 - Prob. 3QQCh. 9.8 - Which of the following is the correct equilibrium...Ch. 9.8 - Prob. 2QQCh. 9.8 - Prob. 3QQCh. 9.9 - Prob. 1QQCh. 9.9 - Prob. 2QQCh. 9.9 - Prob. 3QQCh. 9.9 - Prob. 4QQCh. 9 - What is the general chemical equation for each of...Ch. 9 - What is the general chemical equation for each of...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Write the chemical formulas for the products...Ch. 9 - Write the chemical formulas for the products...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate to which of the following types of...Ch. 9 - Indicate to which of the following types of...Ch. 9 - What is the oxidation number of S in each of the...Ch. 9 - Prob. 9.12EPCh. 9 - Determine the oxidation number of the indicated...Ch. 9 - Determine the oxidation number of the indicated...Ch. 9 - Prob. 9.15EPCh. 9 - Prob. 9.16EPCh. 9 - What is the oxidation number of each element...Ch. 9 - What is the oxidation number of each element...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as (1) a...Ch. 9 - Prob. 9.22EPCh. 9 - Classify each of the following reactions using one...Ch. 9 - Classify each of the following reactions using one...Ch. 9 - Prob. 9.25EPCh. 9 - In each of the following changes is the reactant...Ch. 9 - Identify which substance is oxidized and which...Ch. 9 - Identify which substance is oxidized and which...Ch. 9 - Prob. 9.29EPCh. 9 - Prob. 9.30EPCh. 9 - Indicate whether each of the following substances...Ch. 9 - Indicate whether each of the following substances...Ch. 9 - Prob. 9.33EPCh. 9 - Prob. 9.34EPCh. 9 - What are the three central concepts associated...Ch. 9 - Why are most chemical reactions carried out either...Ch. 9 - What two factors determine whether a collision...Ch. 9 - What happens to the reactants in an ineffective...Ch. 9 - Which of the following reactions are endothermic,...Ch. 9 - Prob. 9.40EPCh. 9 - Should heat be added as a reactant or as a product...Ch. 9 - Should heat be added as a reactant or as a product...Ch. 9 - Prob. 9.43EPCh. 9 - Indicate whether each of the following is a...Ch. 9 - Sketch an energy diagram graph representing an...Ch. 9 - Sketch an energy diagram graph representing an...Ch. 9 - Using collision theory, indicate why each of the...Ch. 9 - Using collision theory, indicate why each of the...Ch. 9 - Substances burn more rapidly in pure oxygen than...Ch. 9 - Milk will sour in a couple of days when left at...Ch. 9 - Will each of the changes listed increase or...Ch. 9 - Will each of the changes listed increase or...Ch. 9 - For each of the changes listed will the rate of...Ch. 9 - For each of the changes listed will the rate of...Ch. 9 - Prob. 9.55EPCh. 9 - Draw an energy diagram graph for an endothermic...Ch. 9 - The characteristics of four reactions, each of...Ch. 9 - The characteristics of four reactions, each of...Ch. 9 - What condition must be met in order for a system...Ch. 9 - What relationship exists between the rates of the...Ch. 9 - What does the term reversible reaction mean?Ch. 9 - What does the notation denote when it is used in...Ch. 9 - Consider the following equilibrium system....Ch. 9 - Consider the following equilibrium system....Ch. 9 - Prob. 9.65EPCh. 9 - Sketch a graph showing how the rates of the...Ch. 9 - The following series of diagrams represent the...Ch. 9 - The following series of diagrams represent the...Ch. 9 - For the reaction A2 + 2B 2AB, diagram I depicts...Ch. 9 - For the reaction A2 + B2 2AB, diagram I depicts...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Prob. 9.74EPCh. 9 - Calculate the value of the equilibrium constant...Ch. 9 - Calculate the value of the equilibrium constant...Ch. 9 - Prob. 9.77EPCh. 9 - Use the given Keq value and the terminology in...Ch. 9 - Write a balanced chemical equation for a totally...Ch. 9 - Write a balanced chemical equation for a totally...Ch. 9 - The following four diagrams represent gaseous...Ch. 9 - Based on the diagrams, chemical reaction, and...Ch. 9 - The following four diagrams represent gaseous...Ch. 9 - Based on the diagrams, chemical reaction, and...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - For the generalized chemical reaction...Ch. 9 - For the generalized chemical reaction...Ch. 9 - Prob. 9.89EPCh. 9 - For the reaction C6H6(g)+3H2(g)C6H12(g)+heat...Ch. 9 - Consider the following chemical system at...Ch. 9 - Prob. 9.92EPCh. 9 - The following two diagrams represent the...Ch. 9 - The following two diagrams represent the...Ch. 9 - Indicate whether or not product formation...Ch. 9 - Prob. 9.96EPCh. 9 - Prob. 9.97EPCh. 9 - Indicate whether or not product formation...
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