Concept explainers
(a)
Interpretation: The substitution product (including stereochemistry) formed by the treatment of
Concept introduction: An alkoxide salt is required to prepare ether. The alkoxide salts are prepared when alcohols are treated with
(b)
Interpretation: The substitution product (including stereochemistry) formed by the treatment of
Concept introduction: Alcohols are converted into alkyl tosylates by treatment with
(c)
Interpretation: The substitution product (including stereochemistry) formed by the treatment of
Concept introduction: Alkyl bromides are obtained by the reaction of
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Chapter 9 Solutions
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- What is the major organic product of the following reaction? (a) (b) NaBH4 CH3CH₂OH ? (c) (d) OHarrow_forwardWrite the products of the following reactions:(a) CH3CH2CH (H3 )COOH + NaOH- ?(b) 2,2-Dimethylpentanoic acid + KOH-?arrow_forward|| CH2-С-NH 2 KOBr → (A); Product (A) is : C-0- CH3 (a) (b) (c) NH (d) NH 3.arrow_forward
- for the following compounds, give their IUPAC and common names:arrow_forwardThe action of heating one mole of water (containing a trace of acid catalyst) on one mole of compound Y produces one mole of CH,COOH and one mole of CH, CH,NH, The structure of Y is: Select one: O CHCNCCH, CH,CH,NHCH,CH, OH CH CHNHCH,CH, O CHCH,CNHCH; O CH;CH NHÖCH;arrow_forwardDraw the structural formula for the major product of the following reactions.arrow_forward
- 4 A) Name the following compound: OH B) Draw the following compound: (Z)-3-bromo-3-hexenoic acidarrow_forwardPlease draw: (a) trans-2,3-dibromo-2-hexene (b) 1-ethyl-3-methylcyclohexane (c) 4-isopropyl-3-octanolarrow_forwardA compound with formula C7H12O is treated with sodium borohydride in methanol to yield 2,2-dimethylcylopentanol. Write a reaction scheme showing the structures of the reactant, the reagents, and the product. Will the product be optically active? Explain.arrow_forward
- How will you convert:(i) Propene to propan-2-ol?(ii) Phenol to 2, 4, 6-trinitrophenol?arrow_forwardCitronellol ((3R)-3,7-dimethyloct-6-en-1-ol, C10H20O) is an organic fragrance found in the oil extracted from lemon grass. a) Name the two functional groups present in the molecule. b) When a few drops of bromine dissolved in hexane is added to a sample of citronellol the brown colour of the bromine rapidly disappears. i. What type of chemical reaction has occurred? ii. Draw the structure of the product formed. iii. Name the product. c) The product formed when citronellol is heated with a mixture of potassium dichromate and sulfuric acid gives a yellow/orange precipitate when shaken with Brady’s reagent (2,4-dinitrophenylhydrazine). It also shows a positive result with Fehling’s solution. i. What type of chemical reaction has occurred ? ii. What type of functional group is present in the product? d) Explain the type of stereoisomerism which may occur in citronellol.arrow_forwardDraw the reaction products of the following reactions of the compound 1-pentanol and name the compounds according to IUPAC! (a) B-elimination of H20 (b) SN reaction in the presence of hydrochloric acid (c) Condensation with acetic acid (d) Oxidation to the corresponding carbonyl compound (e) Condensation of two butanol moleculesarrow_forward
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