Interpretation: The alcoholic group,
Concept introduction: The
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- When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forward18-18 Propanoic acid and methyl acetate are constitutional isomers, and both are liquids at room temperature. One of these compounds has a boiling point of 141°C; the other has a boiling point of 57°C. Which compound has which boiling point? Explain.arrow_forward16-54 Several poisonous plants, including Atropa belladonna, contain the alkaloid atropine. The name “belladonna” (which means “beautiful lady”) probably comes from the fact that Roman women used extracts from this plant to make themselves more attractive. Atropine is widely used by ophthal mologists and optometrists to dilate the pupils for eye examination. Classify the amino group in atropine as primary, secondary, or tertiary. Locate all stereocenters in atropine. Account for the fact that atropine is almost insoluble in water (1 g in 455 mL of cold water) but atropine hydrogen sulfate is very soluble (1 g in 5 mL of cold water). Account for the fact that a dilute aqueous solution of atropine is basic (pH approximately 10.0).arrow_forward
- List the following compounds in order of increasing water solubility: a.ethoxyethane b.propanoic acid c.pentane d.1 butanolarrow_forwardWhich substances can react with potassium borohydride, converting the product into alkene alcohol (assuming complete reaction)?arrow_forwardDraw the organic products of the chlorination of propane in a limited supply of chlorine gas. Cl Cl H H HH H Н—с—с—с—н +с, — H H H Incorrectarrow_forward
- True or False:1. When isopropyl alcohol reacts with HCl, the resulting product is 2-chloropropane2. Nucleophilic molecules are electron-rich molecules that can "attack" electron deficient molecules3. Based on the physical property, hydroquinone has a lower boiling point compared to catecholarrow_forwardProvide arrow pushing mechanism, assume water is present.arrow_forwardDraw the products and balance the equation.arrow_forward
- Name, using an acceptable system of nomenclature, the major organic product of the following reaction: + H₂O H₂SO4 (hydration)arrow_forward1. Simple ketones, like acetone, are often used as industrial solvents for many organically based products such as adhesives and paints. They are considered "universal solvents," because they dissolve so many diverse materials. Explain why these chemicals are good solvents.arrow_forwardPredict the Product. Predict the major organic product(s) or reactant(s) for the following reactions. HO Fr Iz NaOH, H₂O, heat NaOH, H₂O, heatarrow_forward
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