(a) Interpretation: The products of the given reaction are to be drawn. Concept introduction: The reaction of alcohols with halogen acids ( HX ) is a general method to obtain 1 ο , 2 ο or 3 ο alkyl halides. This method is preferred due to the formation of H 2 O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

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Answer 1

Question

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)

Answer 2

Question

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

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Answer 3

Question

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

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Answer 4

Question

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

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Answer 5

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 6

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 7

Chapter 9, Problem 9.19P

Interpretation Introduction

(a)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 8

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 9

Interpretation Introduction

(b)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 10

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 11

Interpretation Introduction

(c)

Interpretation: The products of the given reaction are to be drawn.

Concept introduction: The reaction of alcohols with halogen acids (HX) is a general method to obtain 1ο, 2ο or 3ο alkyl halides. This method is preferred due to the formation of H2O as leaving group. The more substituted alcohols generally react rapidly with halogen acids.

Answer 12

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Answer 15

Ch. 9 - Draw all constitutional isomers having molecular...Ch. 9 - Prob. 9.2P Ch. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Prob. 9.5P Ch. 9 - Name CH33COCH3, a gasoline additive commonly...Ch. 9 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Draw the organic product of each reaction.

Solution Summary: The author explains that the reaction of alcohols with halogen acids (HX) is a general method to obtain alkyl

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