(a) Interpretation: An explanation for the formation of more stable carbocation by 1 , 2 -shift of given intermediate is to be stated. Concept introduction: A less stable carbocation undergoes 1, 2-shift , (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 1

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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1) The isoamyl acetate report requires eight paragraphs - four for comparison of isoamyl alcohol and isoamyl acetate (one paragraph each devoted to MS, HNMR, CNMR and IR) and four for comparison of acetic acid and isoamyl acetate ((one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of…

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Answer 2

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 3

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 4

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 5

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 6

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 7

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 8

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 9

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 10

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 11

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9 - Draw all constitutional isomers having molecular...Ch. 9 - Prob. 9.2P Ch. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Prob. 9.5P Ch. 9 - Name CH33COCH3, a gasoline additive commonly...Ch. 9 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Draw the organic product of each reaction.

Solution Summary: The author explains the formation of more stable carbocation by 1,2 -shift of given intermediate.

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