Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 9, Problem 9.18P
Explain how the reaction of (CH3)2CHCH(Cl) CH3 with H2O yields two substitution products,(CH3)2CHCH(OH) CH3 and (CH3)2C(OH) CH2CH3
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Suppose sodium sulfate has been gradually added to 100 mL of a solution containing calcium ions and strontium ions, both at 0.15 mol/L. Indicate the alternative that presents the percentage of strontium ions that will have precipitated when the calcium sulfate begins to precipitate.
Data: Kps of calcium sulfate: 2.4x10 ⁻ ⁵; Kps of strontium sulfate: 3.2x10 ⁻ ⁷
A) 20,2 %
B) 36,6 %
C) 62,9 %
D) 87,5 %
E) 98.7%
14:43 A
Candidate Identification
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14. The following diagrams represent
hypothetical membrane structures with
their components numbered from 1 to 6.
Based on the figures and your knowledge
of biological membranes, select the
correct alternative.
|
3
5
||
人
2
500000
6
A) Structures 1, 3, 5, 2 and 4 are present
in a constantly fluid arrangement that
allows the selectivity of the movement
○ of molecules. Structure 4, present
integrally or peripherally, is responsible
for this selection, while the quantity of 6
regulates the fluidity.
B) The membranes isolate the cell from
the environment, but allow the passage
of water-soluble molecules thanks to
the presence of 2 and 3. The membrane
in scheme is more fluid than that in
55
12. Mark the correct statement about
reactions a and b :
a.
Br
+ -OH
Br
b.
+ Br
H₂O
+
Br
-OH
+
H₂O
A) The reactions are elimination
reactions, with reaction "a" being of type
E2 and reaction "b" being of type E1.
B) Reaction "a" is an E2 type elimination
occurring in one step and reaction "b" is
an SN1 type substitution.
C) Both reactions can result in the
formation of carbocation, but in reaction
"b" the most stable carbocation will be
formed.
D) Both reactions occur at the same rate
○ and have the same number of reaction
steps.
E) Reaction "b" is an E2 type elimination
occurring in two steps and reaction "a" is
an SN2 type substitution.
Chapter 9 Solutions
Organic Chemistry-Package(Custom)
Ch. 9 - Draw all constitutional isomers having molecular...Ch. 9 - Prob. 9.2PCh. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Prob. 9.5PCh. 9 - Name CH33COCH3, a gasoline additive commonly...Ch. 9 - Name each epoxide.
a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Draw the organic product of each reaction.
Ch. 9 - Prob. 9.11PCh. 9 - Prob. 9.12PCh. 9 - Prob. 9.13PCh. 9 - Prob. 9.14PCh. 9 - Problem 9.13 Draw the structure of each...Ch. 9 - What other alkene is also formed along with Y in...Ch. 9 - Prob. 9.17PCh. 9 - Explain how the reaction of CH32CHCHCl CH3 with...Ch. 9 - Prob. 9.19PCh. 9 - Draw the products of each reaction, indicating the...Ch. 9 - Problem 9.19 What is the major product formed...Ch. 9 - Prob. 9.22PCh. 9 - Prob. 9.23PCh. 9 - Problem 9.22 Draw the organic products formed in...Ch. 9 - Problem 9.23 Draw two steps to convert into each...Ch. 9 - Draw the products of each reaction, and indicate...Ch. 9 - Draw the products of each reaction, and include...Ch. 9 - Draw the products formed when (S)-butan-2-ol is...Ch. 9 - Prob. 9.29PCh. 9 - Prob. 9.30PCh. 9 - Explain why the treatment of anisole with HBr...Ch. 9 - Prob. 9.32PCh. 9 - The cis and trans isomers of 2, 3-dimethyloxirane...Ch. 9 - Problem 9.36 Draw the product of each...Ch. 9 - 9.37 Name each compound depicted in the...Ch. 9 - Answer each question using the ball-and-stick...Ch. 9 - Prob. 9.37PCh. 9 - a. Draw the structure of 1, 2, and 3 alcohol with...Ch. 9 - Give IUPAC name for each alcohol. a....Ch. 9 - Name each ether and epoxide. a.b.c.d.Ch. 9 - Prob. 9.41PCh. 9 - Draw the eight constitutional isomers with...Ch. 9 - Rank each group of compounds in order of: a....Ch. 9 - Prob. 9.44PCh. 9 - 9.44 Why is the boiling point of higher than...Ch. 9 - Draw the organic products formed when CH3CH2CH2OH...Ch. 9 - Draw the organic products formed when 1-methyl...Ch. 9 - What alkenes are formed when each alcohol is...Ch. 9 - Prob. 9.49PCh. 9 - Prob. 9.50PCh. 9 - 9.48 Draw the products of each reaction and...Ch. 9 - Prob. 9.52PCh. 9 - 9.52 Draw a stepwise mechanism for the following...Ch. 9 - 9.53 Although alcohol V gives a single alkene W...Ch. 9 - Prob. 9.55PCh. 9 - Prob. 9.56PCh. 9 - Prob. 9.57PCh. 9 - When CH3CH2CH2CH2OH is treated with H2SO4 NaBr,...Ch. 9 - 9.57 Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 9.60PCh. 9 - Draw two different routes to each of the following...Ch. 9 - Prob. 9.62PCh. 9 - Prob. 9.63PCh. 9 - 9.62 Draw a stepwise mechanism for each...Ch. 9 - Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 9.66PCh. 9 - Draw the products of each reaction. a.c. b.d.Ch. 9 - When each halohydrin is treated with, a product of...Ch. 9 - Prob. 9.69PCh. 9 - Devise a stepwise mechanism for the following...Ch. 9 - Draw the products of each reaction, and indicate...Ch. 9 - Prepare each compound from CH3CH2CH2CH2OH. More...Ch. 9 - Prepare each compound from cyclopentanol. More...Ch. 9 - 9.72 Identify the reagents (a–h) needed to carry...Ch. 9 - Prob. 9.75PCh. 9 - 9.74 Treatment of with affords compound A and ....Ch. 9 - Prob. 9.77PCh. 9 - Prob. 9.78PCh. 9 - 9.77 Draw a stepwise, detailed mechanism for the...Ch. 9 - Dehydration of 1, 2, 2-trimethylcyclohexanol with...Ch. 9 - Prob. 9.81PCh. 9 - 9.80 Draw a stepwise mechanism for the following...Ch. 9 -
9.81 Aziridines are heterocycles that contain an...
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