Chemistry for Changing Times
Chemistry for Changing Times
14th Edition
ISBN: 9780134212777
Author: John W. Hill; Terry W. McCreary
Publisher: Pearson Education (US)
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Chapter 9, Problem 48P
Interpretation Introduction

Interpretation:

To identify the functional groups present in the molecule.

Concept Introduction:

Functional groups are important in organic chemistry, in order to identify several physical and chemical properties.

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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?  b. What is the purpose of the Na2SO4?  c. What equipment would you use to “concentrate [a solution] under reduced pressure”?

Chapter 9 Solutions

Chemistry for Changing Times

Ch. 9 - Prob. 11RQCh. 9 - Prob. 12RQCh. 9 - Prob. 13RQCh. 9 - Prob. 14RQCh. 9 - Prob. 15PCh. 9 - Prob. 16PCh. 9 - Prob. 17PCh. 9 - Prob. 18PCh. 9 - Prob. 19PCh. 9 - Prob. 20PCh. 9 - Prob. 21PCh. 9 - Prob. 22PCh. 9 - Prob. 23PCh. 9 - Prob. 24PCh. 9 - Prob. 25PCh. 9 - Prob. 26PCh. 9 - Prob. 27PCh. 9 - Prob. 28PCh. 9 - Prob. 29PCh. 9 - Prob. 30PCh. 9 - Prob. 31PCh. 9 - Write the structure for (a) methyl propyl ether,...Ch. 9 - Prob. 33PCh. 9 - Prob. 34PCh. 9 - Prob. 35PCh. 9 - Prob. 36PCh. 9 - Prob. 37PCh. 9 - Prob. 38PCh. 9 - Prob. 39PCh. 9 - Prob. 40PCh. 9 - Prob. 41PCh. 9 - Prob. 42PCh. 9 - Prob. 43PCh. 9 - Prob. 44PCh. 9 - Prob. 45PCh. 9 - Prob. 46PCh. 9 - Prob. 47PCh. 9 - Prob. 48PCh. 9 - Which of the following represents a heterocyclic...Ch. 9 - Which of the following represents a heterocyclic...Ch. 9 - Prob. 51APCh. 9 - Prob. 52APCh. 9 - Prob. 53APCh. 9 - Prob. 54APCh. 9 - Prob. 55APCh. 9 - Prob. 56APCh. 9 - Prob. 57APCh. 9 - Prob. 58APCh. 9 - Prob. 59APCh. 9 - Prob. 60APCh. 9 - Refer back to Section 6.3 Describe tee type of...Ch. 9 - Prob. 62APCh. 9 - Prob. 63APCh. 9 - Prob. 64APCh. 9 - Prob. 65APCh. 9 - Prob. 66APCh. 9 - Prob. 67APCh. 9 - Prob. 68APCh. 9 - Prob. 69APCh. 9 - Prob. 70APCh. 9 - Prob. 71APCh. 9 - Prob. 72APCh. 9 - Prob. 9.1CTECh. 9 - A news feature states that herbal remedies are...Ch. 9 - Prob. 9.3CTECh. 9 - Prob. 9.4CTECh. 9 - Prob. 9.5CTECh. 9 - Prob. 9.6CTECh. 9 - Prob. 1CGPCh. 9 - Prob. 2CGPCh. 9 - Prob. 3CGPCh. 9 - Prob. 4CGPCh. 9 - Prob. 5CGPCh. 9 - Prob. 6CGPCh. 9 - Prob. 1CHQCh. 9 - Prob. 2CHQCh. 9 - Prob. 3CHQ
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