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- Q1: The shrub ma huang contains two biologically active stereoisomers ephedrine and pseudoephedrine-with two stereogenic centers as shown in the given structure. Ephedrine is one component of a once popular combination drug used by body builders to increase energy and alertness, while pseudoephedrine is a nasal decongestant. a. Draw the structure of naturally occurring (-)-ephedrine, which has the 1R, 25 configuration. b. Draw the structure of naturally occurring (+)- pseudoephedrine, which has the 15,25 configuration. c. How are ephedrine and pseudoephedrine related? N, d. Draw all other stereoisomers of (-)-ephedrine and (+)-pseudoephedrine and give the R,S designation for all stereogenic centers. OH Ephedrine 15 2.5Classify each pair of compounds as either identical, constitutional isomers, stereoisomers, or not isomers.Jj.15.
- 1. Name each compound and determine the relationship between the pairs of compounds. O a. Name: b. Name: N C. Relationship between structures above: Conformational isomer or Structural isomer 2. Name: 3. Is the following structure the cis stereoisomer or the trans stereoisomer?What relationship exists between the following two structures? a. identical molecules c. stereoisomers O a O b Oc O d b. constitutional isomers d. different molecules Inr. Determine whether the molecules in each pair are the same or enantiomers. H H C CH;CH, a. CH3CH2 l CI CH3 CH3 H H b. H3C HOWCH, Cl но Но CH3 CH3 H CH c. CH3 H HC, CH3 CH3 H;C. H,C || CH2 CH3 CH2
- Are compounds with different placement of double/triple bonds considered stereoisomers or constitutional isomers?• Question 5: Label each stereogenic center as R or S. CH₂ a. CH₂CH₂ b. CH H 1 NH₂ H CH3 CH₂CH₂ T C. D CI CH3 d. Br C ICH₂ H e. f. H* HO C HOOC CH₂ HO CH(CH3)2 -C₂ C CH3 SH NH₂ H CH3 g. h. .CI CIHow are the following two compounds related to each other? H H3C KD H3C CH3 a) They are constitutional isomers of each other. O b) O c) H CH3 d) They are enantiomers of each other. They are stereoisomers of each other. They are functional isomers of each other.
