Answered: Br Multiple Steps

Science

Chemistry

Br Multiple Steps

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.87E: Pyrolysis involves heating compounds to break them into smaller molecules, and typically involves...

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Pyrolysis involves heating compounds to break them into smaller molecules, and typically involves free-radical chain reactions. Pyrolysis of crude oil fractions is a common method of making smaller hydrocarbons from large-chain hydrocarbons. Pyrolysis of ethane, C2H6, forms ethylene and hydrogen gases C2H4 and H2 as the primary products. Suggest a mechanism for this pyrolysis reaction, labeling your reactions as initiation, propagation, and termination steps.
Find the specific Rate constant
pdf is needed, but algebra & For an instantaneous rate of change, is used to denote geometry can be used to approximate the value. The symbol an instantaneous change in a value, 1) What is true about the reactant concentration over time? A[Reactant] constant? At d[Reactant] 3) Circle the time at which the magnitude of the (instantaneous rate of dt change) is the lowest (i.e., during which time is the tangential slope least negative? This is the time when the [reactant] is changing least over time) 0.20 Concentration of reactant vs time 0.15 Rate = -Slope = 1.06x10-2 M/sec jou 0.10 0.05 0.00 15 10. Time, sec. 20 25 https://wnww.chem.purdue.edugdhelphowfosolveilKineticsCalculaingRales.html
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Reaction Conc. Na2S203 Conc. HCI A Abs. A Time (s) Rate (A Abs./BA Time) 1.3686611 1.5360817 1.2267196 1.007568 |0.300349 |0.01870913 |0.02870913 1 0.10 M .30 М 1.358380874 2 0.10 M .15 M 5.114311671 3 0.050 M .30 M 65.56796601 4 0.025 M .30 M 0.9563164 11.3085840 3. What is the overall order of the reaction? Write the complete rate law for this reaction.
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1. A → B +B (rate constant = k1) 2. A +B → C+D (rate constant = k2 3. D → E+F (rate constant = k3) 4. F+A → D + G (rate constant = k Express the net change of [F] and [G]& (select 2 answers) а. d[F] = -k3[D]+k4[A][F] dt b. d[G] = -k4[A][F] dt d[E] = -k3[D] dt d[F] = k3[D]-k4[A][F] С. dt d. d[F] = k3[E][F]-k4[A][F] dt = k4[A][F] dt е. d[E] = k3[D] dt f. d[G] = k4[D][G] %3D dt d[E] = k3[E][F] dt
30- 25 22.285 20 atm 15. 10- 50 100 150 200 250 300 seconds created x10 Is BF, being created or destroyed by the chemical 3 destroyed reaction? neither created nor destroyed is being created or destroyed, what is the rate at If BF3 which it is being created or destroyed 80 seconds after the reaction starts? Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol. If BF, is being created or destroyed, what is the 3 average rate at which it is being created or destroyed during the first 80 seconds of the reaction? Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.