6. Show how you would accomplish the following transformations. (Show the steps and reagents/solvents needed) 2-methylpropene →2,2-dimethyloxiran I
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- Choose reagents to convert 2-cyclohexenone to the following compounds. Syntheses may require several steps. Use letters from the table to list reagents in the order used (first at the left). i 1. Li(CH2=CH)2Cu Reagents a 1. Li(CH3)2Cu 2. H3O+ e 1. Li(C6H5)2Cu 2. H3O+ b 1. NaBH4 f CH2l2/Zn(Cu) / ether j 2. H3O+ C NH3 / KOH g 1. CH3MgBr/dry ether k 2 H3O+ d H2NNH2/KOH h HN(CH3)2 HO CH3 a) b) OH N(CH3)2 2. H3O+ (C6H5)3P+-CH2 H₂ over Pd/C KMnO4/H3O+8) Show how the following conversions might be accomplished, including all reagents and intermediates. Br Y. OHConvert 2-pentanol into 2,3-dibromopentane. Draw structures of the starting material (2-pentanol) and final product (2,3-dibromopentane), and show the two reactions needed for this synthesis. Include the structure of the intermediate compound, and the reagents and conditions for each reaction. Then explain why 1,2-dibromopentane would not be a significant product of this synthesis.
- The following reaction can potentially produce three different cyclized products. 1. NaOMe, MeOH MeO cyclization products 2. acidic workup Provide the structures of the three cyclization products. Label the products as A, B, and C. Circle the major product. Five and six membered rings form preferentially over smaller and larger'rings.7 Which reagents and solvents can be used to synthesize (R)-2-cyanopentane from (R)-2- chloropentane? 8. Without changing reagent concentrations or amounts, what change could one make to the reaction shown below that would increase its reaction rate (explain your reasoning)? NaSCH2CH3 CH3CH2CH,CH,Br CH;CH,CH,CH,SCH,CH3 CH;OHThe following reaction is similar to the dehydration of 2-methylcyclohexanol. However, a significant amount of a tetrasubstituted alkene is expected. Predict the structure for this tetrasubstituted alkene. Also, using curved arrows, provide a reasonable mechanism for its formation. Но. H3PO4 ??? A (-H2O)
- Start from 2-methylcyclohexanol and show the steps and mechanisms for the following products. 3-methyl-cyclohexene, 1-methyl-cyclohexene, and Methylene-cyclohexane. How how all of these products were obtained FROM 2-methylcyclohexanol. Provide a description of the mechanism of each alkene product below each mechanism drawingWhen (CH3CH2)3CBr is added to CH3OH at room temperature, the major product is (CH3O)C(CH2CH3)3 and a minor product is CH3CH=C(CH2CH3)2. Propose a mechanism for the product that is formed by the substitution reaction. Use curved arrows to show the movement of electrons.Show how you might bring about the following conversions. For any conversion involving more than one step, show intermediate compound
- The following reaction can potentially produce three different cyclized products. 1. NaOMe, MeOH MeO cyclization products 2. acidic workup Provide the structures of the three cyclization products. Label the products as A, B, and C. Circle the major product. Five and six membered rings form preferentially over smaller and larger rings.5. Describe an efficient synthesis of 1-methyl-1-cyclohexanol from cyclohexanol. Show the structure of the reagents, reactants and products from each step. Cyclohexanol -------> -----> 1-methyl-1-cyclohexanolWhich reagent(s) IS NOT used in the synthesis problem shown below? H AH Note: This synthesis problem involves both alkene and alkyne reactions. If you're not sure how to start, make a list of objectives based on the changes you observe. Then consider the reagent options listed below, and use your notes to determine what each reagent does. O A. 1-iodoethane O B. NaH C. H2, Pb(OAc)2, Pd/CaCO3, quinoline O D. MCPBA O E. Na, NH3
