The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H 2 SO 4 has to be indicated. Concept introduction: Dehydration reaction: Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction. Carbocation: It is carbon ion that bears a positive charge on it. The increasing stability order of carbocation is as follows, Primary carbocation < secondary carbocation < tertiary carbocation

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Answer 1

Question

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

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Acetals are formed from the reaction of two alcohols with a carbonyl under acidic conditions. Acetal formation is faster with 1,2-ethanediol than with two methanol molecules. Choose the factor that explains the difference in reaction rates. A) The reaction with 1,2-ethanediol has a lower AH (enthalpy) of reaction. B) The reaction with 1,2-ethanediol has a higher AH (enthalpy) of reaction. C) The reaction with 1,2-ethanediol has a more favorable entropy of reaction.

Rank the alcohols in order of increasing reactivity when dehydrated with H2SO4.

Answer 2

Question

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

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Answer 3

Question

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

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Answer 4

Question

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Expert Solution & Answer

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Answer 5

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 6

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 7

Chapter 9, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 8

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 9

(b)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 10

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 11

(c)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 12

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 13

(d)

Interpretation Introduction

Interpretation:

The alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H2SO4 has to be indicated.

Concept introduction:

Dehydration reaction:

Removal of water molecule from the alcohol in the presence of strong acid like sulfuric acid is known as dehydration reaction.

Carbocation: It is carbon ion that bears a positive charge on it.

The increasing stability order of carbocation is as follows,

Primary carbocation < secondary carbocation < tertiary carbocation

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9.1 - Draw the structures of straight-chain alcohols...Ch. 9.1 - Prob. 2P Ch. 9.1 - Prob. 3P Ch. 9.2 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 9.2 - Prob. 5P Ch. 9.2 - The observed relative reactivities of primary,...Ch. 9.4 - Which of the following alcohols would dehydrate...Ch. 9.4 - Prob. 10P Ch. 9.4 - Prob. 11P Ch. 9.4 - Prob. 12P

Solution Summary: The author explains that the alcohol in the given pair that undergoes an elimination reaction more rapidly when heated with H_

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