3. Two solutions are prepared using the same solute:Solution A: 0.14 g of the solute dissolves in 15.4 g of t-butanolSolution B: 0.17 g of the solute dissolves in 12.7 g of cyclohexaneWhich solution has the greatest freezing point change? Show calculations and explain.

Explanation:Colligative properties: The properties of the solution that depend on the number of the…

Answered: 3. Two solutions are prepared using the…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter10: Solutions

Section: Chapter Questions

Problem 85QAP

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A 2.77 M NaOH solution in water has a density of 1.109 g/mL. Express the concentration of this solution (a) mass percentage. (b) mole fraction. (c) molality.
A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?
Vodka is advertised to be 80 proof. That means that the ethanol (C2H5OH) concentration is 40% (two significant figures) by volume. Assuming the density of the solution to be 1.0 g/mL, what is the freezing point of vodka? The density of ethanol is 0.789 g/mL.
Vapor-pressure lowering is a colligative property, as are freezing-point depression and boiling-point elevation. What is a colligative property? Why is the freezing point depressed for a solution as compared to the pure solvent? Why is the boiling point elevated for a solution as compared to the pure solvent? Explain how to calculate T for a freezing-point depression problem or a boiling-point elevation problem. Of the solvents listed in Table 10-5, which would have the largest freezing-point depression for a 0.50 molal solution? Which would have the smallest boiling-point elevation for a 0.50 molal solution? A common application of freezing-point depression and boiling-point elevation experiments is to provide a means to calculate the molar mass of a nonvolatile solute. What data are needed to calculate the molar mass of a nonvolatile solute? Explain how you would manipulate these data to calculate the molar mass of the nonvolatile solute.
Juice (d=1.0g/mL) from freshly harvested grapes has about 24% sucrose by mass. What is the molality of sucrose, C12H22O11, in the grape juice after 25% (by mass) of the water content has been removed? Assume a volume of 15.0 L.
The lattice enthalpy of sodium chloride, H for NaCl(s)Na+(g)+Cl(g) is 787 kJ/mol; the heat of solution in making up 1 M NaCl(aq) is +4.0 kJ/mol. From these data, obtain the sum of the heats of hydration of Na+ and Cl. That is obtain the sum of H values for Na+(g)Na+(aq)Cl(g)Cl(aq) If the heat of hydration of Cl is 338 kJ/mol, what is the heat of hydration of Na+?
A compound contains 42.9% C, 2.4% H, 16.6% N, and 38.1% O. The addition of 3.16 g of this compound to 75.0 mL of cyclohexane (d=0.779g/mL) gives a solution with a freezing point at 0.0C. Using Table 10.2, determine the molecular formula of the compound.
An aqueous solution containing 10.0 g of starch per liter has an osmotic pressure of 3.8 mm Hg at 25 C. (a) What is the average molar mass of starch? (The result is an average because not all starch molecules are identical.) (b) What is the freezing point of the solution? Would it be easy to determine the molecular weight of starch by measuring the freezing point depression? (Assume that the molarity and molality are the same for this solution.)
Which of the following will have the lowest total vapor pressure at 25C? a. pure water (vapor pressure = 23.8 torr at 25C) b. a solution of glucose in water with C6H12O6=0.01 c. a solution of sodium chloride in water with NaCl = 0.01 d. a solution of methanol in water with CH3OH=0.2 (Consider the vapor pressure of both methanol [143 torr at 25C] and water.)
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3. Two solutions are prepared using the same solute: Solution A: 0.14 g of the solute dissolves in 15.4 g of t-butanol Solution B: 0.17 g of the solute dissolves in 12.7 g of cyclohexane Which solution has the greatest freezing point change? Show calculations and explain.