(a)
Interpretation:
The product obtained when the given alcohol reacts with
Concept introduction:
Oxidation of alcohol:
An important reagent helpful in the oxidation of alcohols is
The mechanism involves the protonation of the oxygen in the first step. Then, removal of a proton from the carbon bonded to the
(b)
Interpretation:
The product obtained when the given alcohol reacts with
Concept introduction:
Oxidation of alcohol:
An important reagent helpful in the oxidation of alcohols is
Aldehydes are formed by the oxidation of primary alcohols and ketones are formed by the oxidation of secondary alcohols. Tertiary alcohol have no reaction with
The mechanism involves the protonation of the oxygen in the first step. Then, removal of a proton from the carbon bonded to the
(c)
Interpretation:
The product obtained when the given alcohol reacts with
Concept introduction:
Oxidation of alcohol:
An important reagent helpful in the oxidation of alcohols is
Aldehydes are formed by the oxidation of primary alcohols and ketones are formed by the oxidation of secondary alcohols. Tertiary alcohol have no reaction with
The mechanism involves the protonation of the oxygen in the first step. Then, removal of a proton from the carbon bonded to the
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Chapter 9 Solutions
Essential Organic Chemistry, Global Edition
- Which of the following forms a 1° alcohol when reacted with Grignard reagent? A. ketone B. carbon dioxide C. formaldehyde D. acyl halidearrow_forwardPhosgene (COCl2) was used as a poison gas in World War I. What product would be formed from the reaction of phosgene with each of the followingreagents?a. one equivalent of methanol b. excess methanol c. excess propylamine d. excess waterarrow_forward6arrow_forward
- 7. Write a balanced equation for the hydrogenation of each of the following aldehydes: a. 3-Methylpentanal b. 2-Hydroxypropanal c. 2,3-Dimethylpentanal d. 4-Chloropentanal e. 2-Methyl-3-pentanone f. 3-Hexanonearrow_forwardWhat test will allow you to distinguish between: a. benzyl alcohol and cyclohexanolb. benzyl alcohol and phenol c. cyclohexanol and 1-methylcyclohexanol d. o-cresol and anisolee. benzyl alcohol and anisolearrow_forwardWrite a balanced equation for the hydrogenation of eachof the following:a. Propanal (a three-carbon aldehyde)b. Propanone (a three-carbon ketone)c. 2,3-Dimethylheptanal (an aldehyde with a seven-carbon parent chain)d. 3-Methyl-4-heptanone (a ketone with a seven-carbonparent chain)arrow_forward
- 1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forwardWrite a balanced equation for the hydrogenation of eachof the following:a. Hexanal (a six-carbon aldehyde)b. 2-Hexanone (a six-carbon ketone)c. 2-Methylbutanal (an aldehyde with a four-carbon parent chain)d. 6-Ethyl-2-octanone (a ketone with an eight-carbon parent chain)arrow_forwardDraw the following: 1. a. 3-methyl-1-butanethiol (skunk scent) b. triphenylmethanol c. 4-(bromomethyl)-3-octanol d. 3-cyclopentenethiolarrow_forward
- The reaction of an alkyl halide with aceto acetic ester results to the production of alan O A. ketone O B. secondary alcohol C. primary alcohol O D. acidarrow_forwardWhat is the major organic product obtained from the following reaction? A. 3-hydroxypropanoic acid B. 3-oxopropanoic acid C. propanedioic acid D. 1,3-propanediolarrow_forwardShow how to convert cyclohexanol to these compounds. a. Cyclohexene b. Cyclohexane c. Cyclohexanone d. Bromocyclohexanearrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning