General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 8, Problem 8.78EP
(a)
Interpretation Introduction
Interpretation:
The characteristic of dispersed phase not being trapped by filter paper applies to whether a true solution, a colloidal dispersion, or a suspension has to be indicated.
Concept Introduction:
- It is a homogeneous mixture of two or more solutes and solvent.
- It is composed of particles having diameters less than one nanometer.
- Through filtration, solute particles cannot be obtained.
Colloidal dispersion:
- It is a heterogeneous system formed of a dispersed phase and a dispersion medium.
- It is composed of particles having diameters from one-hundred nanometers.
- Particles do not diffuse through parchment paper, but easily diffuse through filter paper.
Suspension:
- It is a mixture in which the solute does not get dissolved, but will be suspended in the liquid and float freely.
- The nature of solution will be heterogeneous.
- It is composed of particles having diameters greater than 1000 nanometers.
- Particles do not diffuse through parchment paper or through filter paper.
(b)
Interpretation Introduction
Interpretation:
The characteristic of dispersed phase settles immediately under the influence of gravity applies to whether a true solution, a colloidal dispersion, or a suspension has to be indicated.
Concept Introduction:
- It is a homogeneous mixture of two or more solutes and solvent.
- It is composed of particles having diameters less than one nanometer.
- Through filtration, solute particles cannot be obtained.
Colloidal dispersion:
- It is a heterogeneous system formed of a dispersed phase and a dispersion medium.
- It is composed of particles having diameters from one-hundred nanometers.
- Particles do not diffuse through parchment paper, but easily diffuse through filter paper.
Suspension:
- It is a mixture in which the solute does not get dissolved, but will be suspended in the liquid and float freely.
- The nature of solution will be heterogeneous.
- It is composed of particles having diameters greater than 1000 nanometers.
- Particles do not diffuse through parchment paper or through filter paper.
(c)
Interpretation Introduction
Interpretation:
The characteristic of dispersed phase scatters light applies to whether a true solution, a colloidal dispersion, or a suspension has to be indicated.
Concept Introduction:
- It is a homogeneous mixture of two or more solutes and solvent.
- It is composed of particles having diameters less than one nanometer.
- Through filtration, solute particles cannot be obtained.
Colloidal dispersion:
- It is a heterogeneous system formed of a dispersed phase and a dispersion medium.
- It is composed of particles having diameters from one-hundred nanometers.
- Particles do not diffuse through parchment paper, but easily diffuse through filter paper.
Suspension:
- It is a mixture in which the solute does not get dissolved, but will be suspended in the liquid and float freely.
- The nature of solution will be heterogeneous.
- It is composed of particles having diameters greater than 1000 nanometers.
- Particles do not diffuse through parchment paper or through filter paper.
(d)
Interpretation Introduction
Interpretation:
The characteristic of large particles present in dispersed phase applies to whether a true solution, a colloidal dispersion, or a suspension has to be indicated.
Concept Introduction:
- It is a homogeneous mixture of two or more solutes and solvent.
- It is composed of particles having diameters less than one nanometer.
- Through filtration, solute particles cannot be obtained.
Colloidal dispersion:
- It is a heterogeneous system formed of a dispersed phase and a dispersion medium.
- It is composed of particles having diameters from one-hundred nanometers.
- Particles do not diffuse through parchment paper, but easily diffuse through filter paper.
Suspension:
- It is a mixture in which the solute does not get dissolved, but will be suspended in the liquid and float freely.
- The nature of solution will be heterogeneous.
- It is composed of particles having diameters greater than 1000 nanometers.
- Particles do not diffuse through parchment paper or through filter paper.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
I would like my graphs checked please. Do they look right? Do I have iodine and persulfate on the right axis ?
Reaction Fill-ins Part 2! Predict the
product(s) OR starting material of the
following reactions. Remember,
Hydride shifts are possible if/when a
more stable carbocation can exist
(depending on reaction mechanism)!
Put your answers in the indicated
boxes d.
d.
ง
HCI
A cylinder contains 12 L of water vapour at 150˚C and 5 atm. The temperature of the water vapour is raised to 175˚C, and the volume of the cylinder is reduced to 8.5 L. What is the final pressure of the gas in atmospheres?
assume that the gas is ideal
Chapter 8 Solutions
General, Organic, and Biological Chemistry
Ch. 8.1 - In a solution containing 15 mL of water and 25 mL...Ch. 8.1 - Prob. 2QQCh. 8.1 - Which of the following statements about solutions...Ch. 8.2 - Which of the following statements concerning a...Ch. 8.2 - Prob. 2QQCh. 8.2 - Prob. 3QQCh. 8.3 - When an ionic solute dissolves in water, the water...Ch. 8.3 - Which of the following does not affect the rate at...Ch. 8.3 - Prob. 3QQCh. 8.4 - The word like in the solubility rule like...
Ch. 8.4 - The rule like dissolves like is not adequate when...Ch. 8.4 - Prob. 3QQCh. 8.4 - Chlorides, bromides, and iodides are soluble in...Ch. 8.5 - Prob. 1QQCh. 8.5 - Prob. 2QQCh. 8.5 - Prob. 3QQCh. 8.5 - Prob. 4QQCh. 8.5 - Prob. 5QQCh. 8.5 - Prob. 6QQCh. 8.6 - The defining equation for the molarity...Ch. 8.6 - For which of the following solutions is the...Ch. 8.6 - Prob. 3QQCh. 8.7 - When 60.0 mL of a 1.00 M solution is diluted by...Ch. 8.7 - Prob. 2QQCh. 8.7 - Prob. 3QQCh. 8.8 - A colloidal dispersion differs from a true...Ch. 8.8 - Prob. 2QQCh. 8.8 - Prob. 3QQCh. 8.9 - Adding a nonvolatile solute to a pure solvent...Ch. 8.9 - Prob. 2QQCh. 8.9 - Prob. 3QQCh. 8.9 - Which of the following solutions would have a...Ch. 8.10 - Prob. 1QQCh. 8.10 - The osmolarity of a 0.40 molar NaCl solution is a....Ch. 8.10 - Prob. 3QQCh. 8.10 - Which of the following solutions is hypertonic...Ch. 8.10 - Which of the following solutions is isotonic with...Ch. 8 - Prob. 8.1EPCh. 8 - Prob. 8.2EPCh. 8 - Prob. 8.3EPCh. 8 - Identify the solute and the solvent in solutions...Ch. 8 - For each of the following pairs of solutions,...Ch. 8 - For each of the following pairs of solutions,...Ch. 8 - Classify each of the following solutions as...Ch. 8 - Classify each of the following solutions as...Ch. 8 - A solution is made by dissolving 34.0 g of NaCl in...Ch. 8 - A solution is made by dissolving 0.455 g of PbBr2...Ch. 8 - A compound has a solubility in water of 35 g/L at...Ch. 8 - A compound has a solubility in water of 40 g/L at...Ch. 8 - Match each of the following statements about the...Ch. 8 - Prob. 8.14EPCh. 8 - Prob. 8.15EPCh. 8 - Prob. 8.16EPCh. 8 - Prob. 8.17EPCh. 8 - Prob. 8.18EPCh. 8 - Prob. 8.19EPCh. 8 - Methanol is a polar solvent and heptane is a...Ch. 8 - Using Table 8-2, classify each of the following...Ch. 8 - Using Table 8-2, classify each of the following...Ch. 8 - Prob. 8.23EPCh. 8 - Using Table 8-2, indicate whether each of the...Ch. 8 - Using Table 8-2, indicate whether each of the...Ch. 8 - Using Table 8-2, indicate whether each of the...Ch. 8 - Indicate whether or not the two members of each of...Ch. 8 - Indicate whether or not the two members of each of...Ch. 8 - A compound has a solubility in water of 250 mg/L...Ch. 8 - A compound has a solubility in water of 750 mg/L...Ch. 8 - The following diagrams show varying amounts of the...Ch. 8 - The following diagrams show varying amounts of the...Ch. 8 - Prob. 8.33EPCh. 8 - Prob. 8.34EPCh. 8 - Prob. 8.35EPCh. 8 - Prob. 8.36EPCh. 8 - How many grams of glucose must be added to 275 g...Ch. 8 - How many grams of lactose must be added to 655 g...Ch. 8 - Calculate the mass, in grams, of K2SO4 needed to...Ch. 8 - Calculate the mass, in grams, of KCl needed to...Ch. 8 - Prob. 8.41EPCh. 8 - Prob. 8.42EPCh. 8 - Prob. 8.43EPCh. 8 - Prob. 8.44EPCh. 8 - Prob. 8.45EPCh. 8 - Prob. 8.46EPCh. 8 - Prob. 8.47EPCh. 8 - Prob. 8.48EPCh. 8 - Prob. 8.49EPCh. 8 - How many grams of Na2S2O3 are needed to prepare...Ch. 8 - How many grams of NaCl are present in 50.0 mL of a...Ch. 8 - Prob. 8.52EPCh. 8 - Prob. 8.53EPCh. 8 - Prob. 8.54EPCh. 8 - Prob. 8.55EPCh. 8 - Prob. 8.56EPCh. 8 - Prob. 8.57EPCh. 8 - Prob. 8.58EPCh. 8 - Prob. 8.59EPCh. 8 - Prob. 8.60EPCh. 8 - Prob. 8.61EPCh. 8 - Prob. 8.62EPCh. 8 - Prob. 8.63EPCh. 8 - Prob. 8.64EPCh. 8 - Prob. 8.65EPCh. 8 - Prob. 8.66EPCh. 8 - Prob. 8.67EPCh. 8 - Prob. 8.68EPCh. 8 - Prob. 8.69EPCh. 8 - Prob. 8.70EPCh. 8 - Prob. 8.71EPCh. 8 - Prob. 8.72EPCh. 8 - What is the molarity of the solution prepared by...Ch. 8 - What is the molarity of the solution prepared by...Ch. 8 - Prob. 8.75EPCh. 8 - Prob. 8.76EPCh. 8 - Prob. 8.77EPCh. 8 - Prob. 8.78EPCh. 8 - Prob. 8.79EPCh. 8 - Prob. 8.80EPCh. 8 - Prob. 8.81EPCh. 8 - How are the boiling point and freezing point of...Ch. 8 - Prob. 8.83EPCh. 8 - How does the freezing point of seawater compare...Ch. 8 - Prob. 8.85EPCh. 8 - Assume that you have identical volumes of two...Ch. 8 - What is the boiling point of a solution that...Ch. 8 - What is the boiling point of a solution that...Ch. 8 - Prob. 8.89EPCh. 8 - What is the freezing point of a solution that...Ch. 8 - Prob. 8.91EPCh. 8 - Which member of each of the following pairs of...Ch. 8 - What would be the freezing point of a solution...Ch. 8 - Prob. 8.94EPCh. 8 - Indicate whether the osmotic pressure of a 0.1 M...Ch. 8 - Indicate whether the osmotic pressure of a 0.1 M...Ch. 8 - Prob. 8.97EPCh. 8 - Prob. 8.98EPCh. 8 - What is the osmolarity of each of the following...Ch. 8 - Prob. 8.100EPCh. 8 - Prob. 8.101EPCh. 8 - Prob. 8.102EPCh. 8 - Will red blood cells swell, remain the same size,...Ch. 8 - Will red blood cells swell, remain the same size,...Ch. 8 - Will red blood cells crenate, hemolyze, or remain...Ch. 8 - Will red blood cells crenate, hemolyze, or remain...Ch. 8 - Prob. 8.107EPCh. 8 - Prob. 8.108EPCh. 8 - Prob. 8.109EPCh. 8 - Will red blood cells swell, remain the same size,...Ch. 8 - Will red blood cells crenate, hemolyze, or remain...Ch. 8 - Will red blood cells crenate, hemolyze, or remain...Ch. 8 - Consider two solutions, A and B, separated by an...Ch. 8 - Consider two solutions, A and B, separated by an...Ch. 8 - Prob. 8.115EPCh. 8 - Prob. 8.116EPCh. 8 - Which of the following aqueous solutions would...Ch. 8 - Which of the following aqueous solutions would...
Knowledge Booster
Similar questions
- On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 minarrow_forwardd. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…arrow_forwardf. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?arrow_forward
- Liquid chromatography has been used to track the concentration of remdesivir (a broad-spectrum antiviral drug, structure shown at right) in COVID patients undergoing experimental treatments. Intensity The authors provide the following details regarding standard solutions preparation: HN CN HO OH NH2 Remdesivir (RDV) stock solution (5000 µg/mL) was prepared by dissolving RDV drug powder using the mixture of DMSO: MeOH (30:70 v/v). The RDV working standard solutions for calibration and quality controls were prepared using methanol in concentrations of 100, 10, 1, 0.1, 0.01 µg/mL. 1, 2.5, 5, 7.5, 10, 25, 50, 75, 100, 250, 500, 1000, and 5000 ng/mL sample solutions were prepared freshly by spiking calibration standard solutions into the blank human plasma samples for method calibration. a) What type of calibration method is being described? Why do you think the authors chose this method as opposed to another? b) Based on the details provided in part a, describe an appropriate method blank…arrow_forwardRecent advancements in liquid chromatography include the development of ultrahigh pressure liquid chromatography (UHPLC) and an increased use of capillary columns that had previously only been used with gas chromatography. Both of these advances have made the development of portable LC systems possible. For example, Axcend Corp. makes a portable system that uses a capillary column with an internal diameter of 150-μm-that is packed with 1.7-um stationary phase particles. In contrast, a traditional LC column has a 4.6 mm internal diameter and utilizes 5-um stationary phase particles. a) Explain one advantage that is afforded by the use of a capillary column in liquid chromatographic separation. Explain one disadvantage of capillary columns. b) Explain how the use of smaller stationary phase particles can improve the resolution of a separation. Include any relevant equations that support your explanation. c) A scientist at Rowan University is using the Axcend LC to conduct analyses of F…arrow_forwardThis paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and COZ. A. 10A OM B. - Figure 1. Idealized drawing of the cross-section of a pore inside a silica particle, showing the relative densities of aminopropylsilyl (red/green) and fullerene (blue) groups: (A) full cross- section; (B) detailed view of covalent bonding of fullerene to the silica surface. Surface densities of silyl and fullerene groups were inferred from elemental composition results obtained at each stage of the synthesis (see Table 1). Absorbance (mAU, 220 nm) 700 600 500 400 300 200 100 a. Define selectivity, a, with words and an equation. b. Explain how the choice of stationary phase affects selectivity. c. Calculate the resolution of the nitrobenzene and toluene peaks in…arrow_forward
- Normalized Intensity (a. u.) 0.5 1.0 A 3D-printed GC column (shown below) was created for use with "micro" gas chromatography applications. To prove its utility, it was used to separate a mixture of alkanes (C9-C18, C22, C24). For the separation shown below, the column temperature was ramped from 40 °C to 250 °C at a rate of 30 °C per minute. (a) 9 10 = 1 mm 12 13 15 22 0.0 0 100 200 300 400 Time (sec) a) What detector would you use for this analysis? Justify your selection. b) Explain how the chromatogram would change if the separation was run isothermally. c) Explain how the chromatogram would change if the temperature ramp were increased to 50 °C per minute.arrow_forwardDevise a synthesis of each compound from the indicated starting material. You may also use any organic compounds with one or two carbons and any needed inorganic reagents. a. Brarrow_forwardPlease help me with #2b & #3 using the data.arrow_forward
- Heparin is used as an anti-coagulant. A risk of heparin use is thrombocytopenia, or low platelet count. This risk is minimized with the use of low molecular weight heparins (LMWH), therefore it is desirable to separate LMWH from higher molecular weight heparins. The method of choice to do this is molecular exclusion chromatography. Below is a chromatogram from a molecular exclusion chromatographic run. Peaks ranging from A to J are clearly distinguishable. The heparin mixture that was analyzed had anywhere from 6 to 30 repeat units of monomer (where the heparin with 30 repeat units would be roughly five times the size of the heparin with six repeat units). a. Which letter most likely represents the peak with 6 repeat units given these heparin polymers were separated with molecular exclusion chromatography? b. Explain your reasoning describing the mechanism of retention in molecular exclusion chromatography. 100 80 60 60 Relative Abundance 40 40 E GH 20 20 B A 36 38 40 42 44 46 48 50 50…arrow_forwardHELP NOW PLEASE ! URGENT!arrow_forwardHELP NOW PLEASE ! URGENT!arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning