The faster reaction should be determined using the reaction coordinate diagram. Concept introduction: Reaction coordinate diagram is an abstract one dimensional coordinate which represents progress along a reaction pathway. The mathematical relationship between enthalpy (H) and free energy (G) is, ΔG 0 = ΔH 0 - TΔS Reactant: These are the substances initially present in a chemical reaction . Product: These are the substances produced from reactants after a successful reaction. Transition state: It is a hypothetical state that occurs in the space between the reactant and products in a chemical reaction. Intermediate: It is a molecular entity formed from the reactants and reacts further to give the products. More stable reactant forms the more stable carbocation intermediate. Conjugated double bonded compounds are always more stable than the compounds having isolated double bonds.

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Chapter 8, Problem 105P

Interpretation Introduction

Interpretation: The faster reaction should be determined using the reaction coordinate diagram.

Concept introduction:

Reaction coordinate diagram is an abstract one dimensional coordinate which represents progress along a reaction pathway.

The mathematical relationship between enthalpy (H) and free energy (G) is,
ΔG0 = ΔH0- TΔS

Reactant: These are the substances initially present in a chemical reaction.

Product: These are the substances produced from reactants after a successful reaction.

Transition state: It is a hypothetical state that occurs in the space between the reactant and products in a chemical reaction.

Intermediate: It is a molecular entity formed from the reactants and reacts further to give the products.

More stable reactant forms the more stable carbocation intermediate.

Conjugated double bonded compounds are always more stable than the compounds having isolated double bonds.

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