The contribution of resonance structure to resonance hybrid of the given following has to be investigated. Concept Introduction: Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure. Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds. Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 1

Question

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

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Answer 2

Question

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 3

Question

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 4

Question

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 5

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 6

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 7

Chapter 8, Problem 71P

(a)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The contribution of resonance structure to resonance hybrid of the given following has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 14

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Answer 15

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Answer 17

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author analyzes the contribution of resonance structure to resonance hybrid of the given following.

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