Concept explainers
Interpretation:
- The decreasing order of delocalization energy to be investigated.
Concept Introduction:
Delocalization energy: It is a measure of how much more stable a compound with delocalized electrons is than it would be if its electrons were localized. The greater the number of relatively stable resonance contributors, the greater the delocalization energy.
Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.
Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.
Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.
Want to see the full answer?
Check out a sample textbook solutionChapter 8 Solutions
EBK ORGANIC CHEMISTRY
- Statement 1: The boiling point of compound2 is lower because of the number of bondingregions present Statement 2: Moreover the increased no. of sigmabonds result to more difficult distortion resulting to a stronger attractive force within the atoms prensent Which is true? Statement 1, 2, both, or nonearrow_forwardHow many nodes are in the highest energy molecular orbital of benzene?arrow_forwardWhich is the most stabilized by electron delocalization ? А. В. С. D.arrow_forward
- Can these be convertible to one another through ring flips? What type of relationship do the two have? Which has higher potential energy, why?arrow_forwardSolve for the delocalization and overall electronic energy for C4H4 (considering a single p orbital on each carbon) ? How does this compare to benzene?arrow_forwardAnswer the following questions for 1,3,5- hexatriene, the conjugated triene containing six carbons. Which MOs are the frontier molecular orbitals?arrow_forward
- Which of the following statements is true? O The highest occupied molecular orbital for 022+ is aT orbital. The lowest occupied molecular orbital for 022- is a m* orbital. The highest occupied molecular orbital for 022- is a m orbital. The highest occupied molecular orbital for 022+ is a m* orbital.arrow_forward1. Palar Expianation 2. Nen-polar planation:arrow_forwardAnswer thisarrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning