Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 8CTQ

(a)

Interpretation Introduction

Interpretation:

The relationship of given compound with the compound in Figure 7.3 should be stated.

Concept Introduction:

The compounds that have same molecular formula but have different arrangement of atoms in a space are known as isomers.

Conformers are obtained by the interconvertion of a molecule without breaking the bond through the rotation about a single bond. Consitutional isomers have same molecule formula but have different connectivity of atoms. The compounds that have same molecular formula and also have the connectivity of atoms but cannot be converted into one another by rotation about a single bond are known as configuratiol stereoisomers.

(b)

Interpretation Introduction

Interpretation:

The purpose behind to dermine the name of each molecule before to identify reactionship of each molecule with cis-1,2-dimethylcyclohexane should be predicted.

Concept Introduction:

The compounds that have same molecular formula but have different arrangement of atoms in a space are known as isomers.

Conformers are obtained by the interconvertion of a molecule without breaking the bond through the rotation about a single bond. Consitutional isomers have same molecule formula but have different connectivity of atoms. The compounds that have same molecular formula and also have the connectivity of atoms but cannot be converted into one another by rotation about a single bond are known as configuratiol stereoisomers.

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6. Use the molecule below to answer the following questions. a) Name the following molecule. b) Why is it necessary to provide R or S designation in order to clearly communicate molecular structure for this molecule? c) How many stereoisomers of this molecule are possible? Which of them are enantiomers to each other? Which are diastereomers? SH ICN
a. For each disubstituted cyclohexane below, draw its ring-flip isomer. Circle the most stable conformation and label the substituent groups as axial or equatorial. ( see image) b.Draw and name the seven constitutional isomers (all contain a ring of some size) for cycloalkane, C6H12.
Sight along the C2-Cl bond of 2-methylpropane (isobutane). a. Draw a Newman projection of the most stable conformation. b. Draw a Newman projection of the least stable conformation. c. Make a graph of energy versus angle of rotation around the C2-Cl bond. d. Assign relative values to the maxima and minima in your graph, given that an H↔H eclipsing interaction costs 0 kJ/mol and an H↔CH3 eclipsing interaction costs 6.0  kJ/mol.
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