Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 15E

(a)

Interpretation Introduction

Interpretation: In the given structure, the relationship between X and H1 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  1

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  2

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(b)

Interpretation Introduction

Interpretation: In the given structure, the relationship between X and Z group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  3

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  4

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(c)

Interpretation Introduction

Interpretation: In the given structure, the relationship between Y and Z group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  5

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  6

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(d)

Interpretation Introduction

Interpretation: In the given structure, the relationship between H2 and H3 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  7

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  8

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(e)

Interpretation Introduction

Interpretation: In the given structure, the relationship between Z and H3 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  9

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  10

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(f)

Interpretation Introduction

Interpretation: In the given structure, the relationship between Z and H4 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  11

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  12

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(g)

Interpretation Introduction

Interpretation: In the given structure, the relationship between Y and H3 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  13

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  14

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

(h)

Interpretation Introduction

Interpretation: In the given structure, the relationship between H3 and H4 group needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  15

Here, the substituted groups in the chair conformation are represented as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 7, Problem 15E , additional homework tip  16

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

In the chair conformation of the cyclohexane, if two groups are pointing in same direction, it is cis conformation and if the two groups are pointing in opposite direction then it is trans conformation.

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