Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 20CTQ
Which stereoisomer in the previous question is lower in PE? Explain your reasoning.
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Glucose is a simple sugar with five substituents bonded to a sixmembered ring.
a.) Using a chair representation, draw the most stable arrangement of these substituents on the six-membered ring.b.) Convert this representation to one that uses a hexagon with wedges and dashed wedges.c.) Draw a constitutional isomer of glucose.d.) Draw a stereoisomer that has an axial OH group on one carbon
Glucose is a simple sugar with five substituents bonded to a sixmembered ring.a.Using a chair representation, draw the most stable arrangement of these substituents on the six-membered ring.
b.Convert this representation to one that uses a hexagon with wedges and dashed wedges.
c.Draw a constitutional isomer of glucose.
d.Draw a stereoisomer that has an axial OH group on one carbon.
Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different
conformations of the same compound, or the same conformation of a compound viewed from a different perspective.
Note that cis, trans isomers are an example of stereoisomers.
CH3
CH3
CI
CI
H
H
H.
H
CH3
H.
H'
H.
CH3
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Chapter 7 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 7 - Prob. 1CTQCh. 7 - Prob. 2CTQCh. 7 - Prob. 3CTQCh. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQCh. 7 - Prob. 7CTQCh. 7 - Prob. 8CTQCh. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ
Ch. 7 - Prob. 11CTQCh. 7 - Fill in the blanks: cis-1,3-Dimethylcyclohexane...Ch. 7 - Prob. 13CTQCh. 7 - Prob. 14CTQCh. 7 - Prob. 15CTQCh. 7 - Prob. 16CTQCh. 7 - Prob. 17CTQCh. 7 - Prob. 18CTQCh. 7 - Draw chair representations of...Ch. 7 - Which stereoisomer in the previous question is...Ch. 7 - Prob. 21CTQCh. 7 - Prob. 1ECh. 7 - Label each of the following as cis, trans or...Ch. 7 - Which pair has more in common with one another?Ch. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Fill in the table by drawing a representation of a...Ch. 7 - Prob. 9ECh. 7 - True or False: If you perform a chair flip on...Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Draw trans-1-tert-butyl-3-methylcyclohexane in its...Ch. 7 - Build a model of methylcyclohexane, and use the...
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