General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 7, Problem 7.41SP
Interpretation Introduction
Interpretation:
The strong electrolytic character of molecular compounds should be explained.
Concept introduction:
Strongest electrolyte:
The compound that dissolved in water and completely dissociates to produce the ions into the solution is known as strongest electrolyte.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 7 Solutions
General Chemistry: Atoms First
Ch. 7.1 - What is the molar concentration of Br ions in a...Ch. 7.1 - Three different substances, A2X, A2Y, and A2Z, are...Ch. 7.2 - Prob. 7.3PCh. 7.3 - Write net ionic equations for the following...Ch. 7.4 - Predict whether each of the following compounds is...Ch. 7.4 - Predict whether a precipitation reaction will...Ch. 7.4 - How might you use a precipitation reaction to...Ch. 7.4 - An aqueous solution containing an anion,...Ch. 7.5 - Prob. 7.9PCh. 7.5 - Give likely chemical formulas corresponding to the...
Ch. 7.5 - Write a balanced ionic equation and net ionic...Ch. 7.5 - The following pictures represent aqueous solutions...Ch. 7.6 - Assign an oxidation number to each atom in the...Ch. 7.7 - Prob. 7.14PCh. 7.7 - In each of the following reactions, tell which...Ch. 7.8 - Predict whether the following reactions will...Ch. 7.8 - Element B will reduce the cation of element A (A+)...Ch. 7.8 - Use the following reactions to arrange the...Ch. 7.9 - Write unbalanced half-reactions for the following...Ch. 7.9 - Balance the following net ionic equation by the...Ch. 7.9 - Balance the following equation by the...Ch. 7.10 - What is the molar concentration of Fe2+ ion in an...Ch. 7.10 - In the common lead storage battery used in...Ch. 7.10 - Many dozens of different solvents are used in...Ch. 7 - Prob. 7.25CPCh. 7 - Assume that an aqueous solution of a cation,...Ch. 7 - Assume that an aqueous solution of OH, represented...Ch. 7 - Prob. 7.28CPCh. 7 - Prob. 7.29CPCh. 7 - Prob. 7.30CPCh. 7 - Prob. 7.31CPCh. 7 - Prob. 7.32SPCh. 7 - Prob. 7.33SPCh. 7 - Write net ionic equations for the reactions listed...Ch. 7 - Prob. 7.35SPCh. 7 - Prob. 7.36SPCh. 7 - Prob. 7.37SPCh. 7 - Prob. 7.38SPCh. 7 - Prob. 7.39SPCh. 7 - Classify each of the following substances as...Ch. 7 - Prob. 7.41SPCh. 7 - What is the total molar concentration of ions in...Ch. 7 - What is the total molar concentration of ions in...Ch. 7 - Which of the following substances are likely to be...Ch. 7 - Which of the following substances are likely to be...Ch. 7 - Predict whether a precipitation reaction will...Ch. 7 - Predict whether a precipitation reaction will...Ch. 7 - Prob. 7.48SPCh. 7 - Prob. 7.49SPCh. 7 - Prob. 7.50SPCh. 7 - How would you prepare the following substances by...Ch. 7 - What is the mass and the identity of the...Ch. 7 - What is the mass and the identity of the...Ch. 7 - Prob. 7.54SPCh. 7 - Prob. 7.55SPCh. 7 - Prob. 7.56SPCh. 7 - Assume that you have an aqueous solution of an...Ch. 7 - Prob. 7.58SPCh. 7 - Prob. 7.59SPCh. 7 - Prob. 7.60SPCh. 7 - Write balanced ionic equations for the following...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.63SPCh. 7 - If the following solutions are mixed, is the...Ch. 7 - Prob. 7.65SPCh. 7 - How many milliliters of 1.00 M KOH must be added...Ch. 7 - How many milliliters of 2.00 M HCl must be added...Ch. 7 - Where in the periodic table are the best reducing...Ch. 7 - Prob. 7.69SPCh. 7 - In each of the following instances, tell whether...Ch. 7 - Prob. 7.71SPCh. 7 - Prob. 7.72SPCh. 7 - Prob. 7.73SPCh. 7 - Prob. 7.74SPCh. 7 - Prob. 7.75SPCh. 7 - Prob. 7.76SPCh. 7 - Prob. 7.77SPCh. 7 - Prob. 7.78SPCh. 7 - Neither strontium (Sr) nor antimony (Sb) is shown...Ch. 7 - Prob. 7.80SPCh. 7 - Prob. 7.81SPCh. 7 - Prob. 7.82SPCh. 7 - Prob. 7.83SPCh. 7 - Prob. 7.84SPCh. 7 - Balance the half-reactions in Problem 7.83,...Ch. 7 - Prob. 7.86SPCh. 7 - Prob. 7.87SPCh. 7 - Balance the following half-reactions: (a) (acidic)...Ch. 7 - Prob. 7.89SPCh. 7 - Write balanced net ionic equations for the...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.93SPCh. 7 - Prob. 7.94SPCh. 7 - Prob. 7.95SPCh. 7 - Prob. 7.96SPCh. 7 - Prob. 7.97SPCh. 7 - Prob. 7.98SPCh. 7 - Standardized solutions of KBrO3 are frequently...Ch. 7 - Prob. 7.100SPCh. 7 - Prob. 7.101SPCh. 7 - Prob. 7.102SPCh. 7 - Calcium levels in blood can be determined by...Ch. 7 - Balance the equations for the following reactions...Ch. 7 - Prob. 7.105CHPCh. 7 - Prob. 7.106CHPCh. 7 - Balance the equations for the following reactions...Ch. 7 - Prob. 7.108CHPCh. 7 - Prob. 7.109CHPCh. 7 - Prob. 7.110CHPCh. 7 - Prob. 7.111CHPCh. 7 - Prob. 7.112CHPCh. 7 - Succinic acid, an intermediate in the metabolism...Ch. 7 - How could you use a precipitation reaction to...Ch. 7 - How could you use a precipitation reaction to...Ch. 7 - Write a balanced net ionic equation for each of...Ch. 7 - A 100.0 mL solution containing aqueous HCl and HBr...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.119CHPCh. 7 - Prob. 7.120CHPCh. 7 - When 75.0 mL of a 0.100 M lead(II) nitrate...Ch. 7 - Prob. 7.122CHPCh. 7 - Prob. 7.123CHPCh. 7 - Hydrogen peroxide can be either an oxidizing or...Ch. 7 - Prob. 7.125CHPCh. 7 - Iron content in ores can be determined by a redox...Ch. 7 - A mixture of FeCl2 and NaCl is dissolved in water,...Ch. 7 - Prob. 7.128MPCh. 7 - The following three solutions are mixed: 100.0 mL...Ch. 7 - Prob. 7.130MPCh. 7 - Prob. 7.131MPCh. 7 - Prob. 7.132MPCh. 7 - Prob. 7.133MPCh. 7 - Brass is an approximately 4:1 alloy of copper and...Ch. 7 - Prob. 7.135MPCh. 7 - Prob. 7.136MP
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