General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 7.4, Problem 7.7P
How might you use a precipitation reaction to prepare a sample of Ca3(PO4)2? Write the net ionic equation.
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3. Refer to the data below to answer the following questions:
Isoelectric point
Amino Acid
Arginine
10.76
Glutamic Acid
3.22
Tryptophan
5.89
A. Define isoelectric point.
B. The most basic amino acid is
C. The most acidic amino acid is
sidizo zo
3. A gas mixture contains 50 mol% H2 and 50 mol% He.
1.00-L samples of this gas mixture are mixed with
variable volumes of O2 (at 0 °C and 1 atm). A spark is
introduced to allow the mixture to undergo complete
combustion. The final volume is measured at 0 °C and 1
atm. Which graph best depicts the final volume as a
function of the volume of added O2?
(A)
2.00
1.75
Final Volume, L
1.50
1.25
1.00
0.75
0.50
0.25
0.00
0.00
0.25
0.50
2.00
(B)
1.75
1.50
Final Volume, L
1.25
1.00
0.75
0.50-
0.25
0.00
0.75
1.00
0.00
0.25
Volume O₂ added, L
2
0.50
0.75
1.00
Volume O₂ added, L
2
2.00
2.00
(C)
(D)
1.75
1.75
1.50
1.50
Final Volume, L
1.25
1.00
0.75
0.50
Final Volume, L
1.25
1.00
0.75
0.50
0.25
0.25
0.00
0.00
0.00
0.25
0.50
0.75
1.00
0.00
0.25
Volume O₂ added, L
0.50
0.75
1.00
Volume O₂ added, L
2
Leucine is an essential amino acid with the systematic name 2-amino-3-methylpentanoic acid. It has pai
2.36 and pKa2 = 9.60.
H2N-C(R)H-COOH and R is -CH2-CH(CH3)2
A. Draw the condensed structure for leucine, and label all chirality centers with an asterisk.
B. How many possible stereoisomers of leucine are there?
C. Draw a Fischer projection of L-leucine and label the chirality center(s) as R or S.
D. What is the p/ of leucine?
E. Draw the structure of the predominant form of leucine at 10.00.
F.
Draw the structure of the predominant form of leucine at pH = 1.50.
G. Leucine is described as an essential amino acid. What does this mean?
H. Show the alkyl halide you would use to prepare leucine by the amidomalonate method.
=
Chapter 7 Solutions
General Chemistry: Atoms First
Ch. 7.1 - What is the molar concentration of Br ions in a...Ch. 7.1 - Three different substances, A2X, A2Y, and A2Z, are...Ch. 7.2 - Prob. 7.3PCh. 7.3 - Write net ionic equations for the following...Ch. 7.4 - Predict whether each of the following compounds is...Ch. 7.4 - Predict whether a precipitation reaction will...Ch. 7.4 - How might you use a precipitation reaction to...Ch. 7.4 - An aqueous solution containing an anion,...Ch. 7.5 - Prob. 7.9PCh. 7.5 - Give likely chemical formulas corresponding to the...
Ch. 7.5 - Write a balanced ionic equation and net ionic...Ch. 7.5 - The following pictures represent aqueous solutions...Ch. 7.6 - Assign an oxidation number to each atom in the...Ch. 7.7 - Prob. 7.14PCh. 7.7 - In each of the following reactions, tell which...Ch. 7.8 - Predict whether the following reactions will...Ch. 7.8 - Element B will reduce the cation of element A (A+)...Ch. 7.8 - Use the following reactions to arrange the...Ch. 7.9 - Write unbalanced half-reactions for the following...Ch. 7.9 - Balance the following net ionic equation by the...Ch. 7.9 - Balance the following equation by the...Ch. 7.10 - What is the molar concentration of Fe2+ ion in an...Ch. 7.10 - In the common lead storage battery used in...Ch. 7.10 - Many dozens of different solvents are used in...Ch. 7 - Prob. 7.25CPCh. 7 - Assume that an aqueous solution of a cation,...Ch. 7 - Assume that an aqueous solution of OH, represented...Ch. 7 - Prob. 7.28CPCh. 7 - Prob. 7.29CPCh. 7 - Prob. 7.30CPCh. 7 - Prob. 7.31CPCh. 7 - Prob. 7.32SPCh. 7 - Prob. 7.33SPCh. 7 - Write net ionic equations for the reactions listed...Ch. 7 - Prob. 7.35SPCh. 7 - Prob. 7.36SPCh. 7 - Prob. 7.37SPCh. 7 - Prob. 7.38SPCh. 7 - Prob. 7.39SPCh. 7 - Classify each of the following substances as...Ch. 7 - Prob. 7.41SPCh. 7 - What is the total molar concentration of ions in...Ch. 7 - What is the total molar concentration of ions in...Ch. 7 - Which of the following substances are likely to be...Ch. 7 - Which of the following substances are likely to be...Ch. 7 - Predict whether a precipitation reaction will...Ch. 7 - Predict whether a precipitation reaction will...Ch. 7 - Prob. 7.48SPCh. 7 - Prob. 7.49SPCh. 7 - Prob. 7.50SPCh. 7 - How would you prepare the following substances by...Ch. 7 - What is the mass and the identity of the...Ch. 7 - What is the mass and the identity of the...Ch. 7 - Prob. 7.54SPCh. 7 - Prob. 7.55SPCh. 7 - Prob. 7.56SPCh. 7 - Assume that you have an aqueous solution of an...Ch. 7 - Prob. 7.58SPCh. 7 - Prob. 7.59SPCh. 7 - Prob. 7.60SPCh. 7 - Write balanced ionic equations for the following...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.63SPCh. 7 - If the following solutions are mixed, is the...Ch. 7 - Prob. 7.65SPCh. 7 - How many milliliters of 1.00 M KOH must be added...Ch. 7 - How many milliliters of 2.00 M HCl must be added...Ch. 7 - Where in the periodic table are the best reducing...Ch. 7 - Prob. 7.69SPCh. 7 - In each of the following instances, tell whether...Ch. 7 - Prob. 7.71SPCh. 7 - Prob. 7.72SPCh. 7 - Prob. 7.73SPCh. 7 - Prob. 7.74SPCh. 7 - Prob. 7.75SPCh. 7 - Prob. 7.76SPCh. 7 - Prob. 7.77SPCh. 7 - Prob. 7.78SPCh. 7 - Neither strontium (Sr) nor antimony (Sb) is shown...Ch. 7 - Prob. 7.80SPCh. 7 - Prob. 7.81SPCh. 7 - Prob. 7.82SPCh. 7 - Prob. 7.83SPCh. 7 - Prob. 7.84SPCh. 7 - Balance the half-reactions in Problem 7.83,...Ch. 7 - Prob. 7.86SPCh. 7 - Prob. 7.87SPCh. 7 - Balance the following half-reactions: (a) (acidic)...Ch. 7 - Prob. 7.89SPCh. 7 - Write balanced net ionic equations for the...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.93SPCh. 7 - Prob. 7.94SPCh. 7 - Prob. 7.95SPCh. 7 - Prob. 7.96SPCh. 7 - Prob. 7.97SPCh. 7 - Prob. 7.98SPCh. 7 - Standardized solutions of KBrO3 are frequently...Ch. 7 - Prob. 7.100SPCh. 7 - Prob. 7.101SPCh. 7 - Prob. 7.102SPCh. 7 - Calcium levels in blood can be determined by...Ch. 7 - Balance the equations for the following reactions...Ch. 7 - Prob. 7.105CHPCh. 7 - Prob. 7.106CHPCh. 7 - Balance the equations for the following reactions...Ch. 7 - Prob. 7.108CHPCh. 7 - Prob. 7.109CHPCh. 7 - Prob. 7.110CHPCh. 7 - Prob. 7.111CHPCh. 7 - Prob. 7.112CHPCh. 7 - Succinic acid, an intermediate in the metabolism...Ch. 7 - How could you use a precipitation reaction to...Ch. 7 - How could you use a precipitation reaction to...Ch. 7 - Write a balanced net ionic equation for each of...Ch. 7 - A 100.0 mL solution containing aqueous HCl and HBr...Ch. 7 - Write balanced net ionic equations for the...Ch. 7 - Prob. 7.119CHPCh. 7 - Prob. 7.120CHPCh. 7 - When 75.0 mL of a 0.100 M lead(II) nitrate...Ch. 7 - Prob. 7.122CHPCh. 7 - Prob. 7.123CHPCh. 7 - Hydrogen peroxide can be either an oxidizing or...Ch. 7 - Prob. 7.125CHPCh. 7 - Iron content in ores can be determined by a redox...Ch. 7 - A mixture of FeCl2 and NaCl is dissolved in water,...Ch. 7 - Prob. 7.128MPCh. 7 - The following three solutions are mixed: 100.0 mL...Ch. 7 - Prob. 7.130MPCh. 7 - Prob. 7.131MPCh. 7 - Prob. 7.132MPCh. 7 - Prob. 7.133MPCh. 7 - Brass is an approximately 4:1 alloy of copper and...Ch. 7 - Prob. 7.135MPCh. 7 - Prob. 7.136MP
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