Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 7, Problem 7.22P
Draw an energy diagram for the reaction in Problem 7.21a. Label the axes, the starting material, the product, and the transition state. Assume the reaction is exothermic. Label ∆H° and Ea.
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For the gas phase reaction Cl(g) + HBr(g) → HCl(g) + Br(g), Ea(fwd) = 7 kJ and Ea(rev)= 72 kJ. Draw a reaction energy diagram; include a predicted structure for the transition state and the value of ∆Hrxn.
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○ KINETICS AND EQUILIBRIUM
Drawing the reaction energy diagram of a catalyzed reaction
Sketch a qualitative reaction energy diagram for a chemical reaction with and without a catalyst. Assume the uncatalyzed reaction is exothermic.
Note: Because the sketches are only qualitative, the energies in them don't have to be exact. They only have to have the right relationship to each other. For
example, if one energy is less than another, that fact should be clear in your sketch.
energy
Uncatalyzed reaction
reactants
Ea
reaction coordinate
products
energy
Catalyzed reaction
reactants
Ea
reaction coordinate
0/3
products
The following reaction occurs by a 1 step mechanism and is overall endothermic.
CH3CH₂OH + H₂SO4 → CH3CH₂OH₂+ + HSO4
Draw a potential energy diagram for this reaction. Label all parts including: the reactants, the products, TS, Eaf, Ear, enthalpy, etc.
Chapter 7 Solutions
Organic Chemistry-Package(Custom)
Ch. 7 - Classify each alkyl halide as 1 , 2, or 3.Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Draw the structure of an alkyl bromide with...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.5PCh. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.7PCh. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.9PCh. 7 - Prob. 7.10P
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Does the equilibrium favor the reactants or...Ch. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Classify each solvent as protic or aprotic. a. b....Ch. 7 - Prob. 7.17PCh. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - Draw an energy diagram for the reaction in Problem...Ch. 7 - Draw the product of each SN2 reaction and indicate...Ch. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - What happens to the rate of an SN1 reaction under...Ch. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Classify each carbocation as 1,2, or 3. a. b. c....Ch. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Which alkyl halide in each pair reacts faster in...Ch. 7 - Prob. 7.32PCh. 7 - Problem 7.30 For each alkyl halide and...Ch. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Give the IUPAC name for each compound, including...Ch. 7 - Draw the products formed when each alkyl halide is...Ch. 7 - Give the IUPAC name for each compound. a. c....Ch. 7 - Prob. 7.45PCh. 7 - Classify each alkyl halide in Problem 7.44 as 1 ,...Ch. 7 - Draw the eight constitutional isomers having the...Ch. 7 - Prob. 7.48PCh. 7 - Draw the substitution product that results when...Ch. 7 - Draw the products of each nucleophilic...Ch. 7 - Prob. 7.51PCh. 7 - Rank the species in each group in order of...Ch. 7 - Which of the following nucleophilic substitution...Ch. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7.53 Consider the following reaction.
Draw a...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Draw the products of each SN2 reaction and...Ch. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - Consider the following SN1 reaction. a.Draw a...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Diphenhydramine, the antihistamine in Benadryl,...Ch. 7 - Draw a stepwise, detailed mechanism for the...Ch. 7 - When a single compound contains both a nucleophile...Ch. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Draw a stepwise, detailed mechanism f or the...Ch. 7 - Prob. 7.76PCh. 7 - Fill in the appropriate reagent or starting...Ch. 7 - Devise a synthesis of each compound from an alkyl...Ch. 7 - Prob. 7.79PCh. 7 - Suppose you have compounds A-D at y our disposal....Ch. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - 7.80 As we will learn in Chapter 9, an epoxide is...Ch. 7 - Prob. 7.86PCh. 7 - In some nucleophilic substitutions under SN1...
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- Which of the following endothermic reactions will always be nonspontaneous? O CH4(g) + CO₂(g) →→2CO(g) + 2H₂(g) Ⓒ2H₂O(g) →→ 2H₂(g) + O₂(g) O2SO3(g) 2SO2(g) + O₂(g) O N₂(g) + 2O2(g) →→→ 2NO₂(g) O CaCO3(s) ) CaO(s) + CO,(g)arrow_forwardThe following reaction occurs by a 1 step mechanism and is overall exothermic. CH3CH2Br + NaOCH3 CH2CH2 + CH3OH + NaBr Draw a potential energy diagram for this reaction. Label all parts including: the reactants, the products, TS, Eaf, Ear, enthalpy, etc.arrow_forwardFor each of the following reactions, identify whether the reactants or the products would have more potential energy. + C(s) + 2H₂O(g) + 90.1 kJ → 2CO2(g) + 2H₂(9) CO(g) + H₂O(g) - 2CO₂(g) + 2H₂(g) + 41.2 kJ C₂H₂OH(I) + 30₂(9) - 2C0₂(g) + 3H₂O(g) C3H8(9) + 6H₂O(g) → 3CO₂(g) + 10H₂(g) Use the following to answer the next 3 questions. The smelting of iron occurs in a blast furnace, as represented by the following overall equation. Step I 3Fe2O3(s) + CO(g) - CO₂(g) + 2Fe3O4(s) A+H° = -47.2 kJ Step II Fe₂O4(s) + CO(g) - CO₂(g) + 3FeO(s) A,H+19.4 kJ Step III FeO(s) + CO(g) - CO₂(g) + Fe(s) AH = -11.0 kJ The molar enthalpy of reaction for Fe₂O3(s) in the reaction represented by Step I is Record your 3-digit answer. Include sign; do not include units. Potential Energy (kJ) AH-514.1 kJ Reactants ACH° +374.1 kJ Which steps in the above process can be represented by the following potential energy diagram? Select one: O Step II only O Steps I and III O Steps I, II and III O None of the above…arrow_forward
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