(a) Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity. Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high p K a value.

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Answer 1

Question

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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E17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.

10.

Answer 2

Question

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 3

Question

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 4

Question

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 5

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 6

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 7

Chapter 7, Problem 7.18P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Classify each alkyl halide as 1 , 2, or 3.Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Draw the structure of an alkyl bromide with...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.5P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.7P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the nucleophilicity of a group depends upon its basicity.

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Chapter 7 Solutions