Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Textbook Question
Chapter 7, Problem 7.112E
A salt solution has a molarity of
a.
b.
c.
d.
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
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mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 7 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 7 - Many solutions are found in the home. Some are...Ch. 7 - Prob. 7.2ECh. 7 - Classify the following as being a solution or not...Ch. 7 - Classify the following as being a solution or not...Ch. 7 - Use the term soluble, insoluble, or immiscible to...Ch. 7 - Use the term soluble, insoluble, or immiscible to...Ch. 7 - Define the term miscible. It is not defined in the...Ch. 7 - Classify the following solutions as unsaturated,...Ch. 7 - Prob. 7.9ECh. 7 - Prob. 7.10E
Ch. 7 - Prob. 7.11ECh. 7 - Classify each of the following solutes into the...Ch. 7 - Prob. 7.13ECh. 7 - Prob. 7.14ECh. 7 - Prob. 7.15ECh. 7 - Prob. 7.16ECh. 7 - Prob. 7.17ECh. 7 - Prob. 7.18ECh. 7 - Prob. 7.19ECh. 7 - Prob. 7.20ECh. 7 - Prob. 7.21ECh. 7 - Prob. 7.22ECh. 7 - Calculate the molarity of the following solutions:...Ch. 7 - Prob. 7.24ECh. 7 - Prob. 7.25ECh. 7 - Calculate: a. How many grams of solid would be...Ch. 7 - Prob. 7.27ECh. 7 - Prob. 7.28ECh. 7 - Calculate the concentration in (w/w) of the...Ch. 7 - Calculate the concentration in (w/w) of the...Ch. 7 - Prob. 7.31ECh. 7 - Calculate the concentration in (w/w) of the...Ch. 7 - Prob. 7.33ECh. 7 - Calculate the concentration in (v/v) of the...Ch. 7 - Calculate the concentration in (v/v) of the...Ch. 7 - Consider the blood volume of an adult to be 5.0L....Ch. 7 - Prob. 7.37ECh. 7 - Calculate the concentration in (w/v) of the...Ch. 7 - Calculate the concentration in (w/v) of the...Ch. 7 - Prob. 7.40ECh. 7 - Prob. 7.41ECh. 7 - Prob. 7.42ECh. 7 - Explain how you would prepare the following...Ch. 7 - Prob. 7.44ECh. 7 - Prob. 7.45ECh. 7 - Calculate the following: a. The number of grams of...Ch. 7 - Prob. 7.47ECh. 7 - Explain how you would prepare the following dilute...Ch. 7 - Prob. 7.49ECh. 7 - Prob. 7.50ECh. 7 - Prob. 7.51ECh. 7 - How many grams of solid Na2CO3 will react with...Ch. 7 - Prob. 7.53ECh. 7 - Prob. 7.54ECh. 7 - Prob. 7.55ECh. 7 - Prob. 7.56ECh. 7 - How many milliliters of 0.124MNaOH solution will...Ch. 7 - How many milliliters of 0.124MNaOH solution will...Ch. 7 - How many milliliters of 0.115MNaOH solution will...Ch. 7 - Stomach acid is essentially 0.10MHCl. An active...Ch. 7 - Prob. 7.61ECh. 7 - Prob. 7.62ECh. 7 - Prob. 7.63ECh. 7 - Calculate the boiling and freezing points of water...Ch. 7 - Calculate the boiling and freezing points of water...Ch. 7 - Prob. 7.66ECh. 7 - Prob. 7.67ECh. 7 - Prob. 7.68ECh. 7 - Calculate the osmolarity for the following...Ch. 7 - Prob. 7.70ECh. 7 - Calculate the osmotic pressure of a 0.125M...Ch. 7 - Prob. 7.72ECh. 7 - Prob. 7.73ECh. 7 - Calculate the osmotic pressure of a solution that...Ch. 7 - Prob. 7.75ECh. 7 - Prob. 7.77ECh. 7 - Prob. 7.78ECh. 7 - Prob. 7.79ECh. 7 - Suppose an osmotic membrane separates a 5.00 sugar...Ch. 7 - Prob. 7.81ECh. 7 - Prob. 7.82ECh. 7 - Suppose you have a bag made of a membrane like...Ch. 7 - Prob. 7.84ECh. 7 - Prob. 7.85ECh. 7 - Prob. 7.86ECh. 7 - Prob. 7.87ECh. 7 - Prob. 7.88ECh. 7 - Prob. 7.89ECh. 7 - When a patient has blood cleansed by hemodialysis,...Ch. 7 - Prob. 7.91ECh. 7 - Prob. 7.92ECh. 7 - Prob. 7.93ECh. 7 - Prob. 7.94ECh. 7 - Prob. 7.95ECh. 7 - Strips of fresh meat can be preserved by drying....Ch. 7 - If a salt is added to water, which of the...Ch. 7 - Prob. 7.98ECh. 7 - Prob. 7.99ECh. 7 - Prob. 7.100ECh. 7 - Which one of the following compounds is a...Ch. 7 - Prob. 7.102ECh. 7 - Prob. 7.103ECh. 7 - Prob. 7.104ECh. 7 - Prob. 7.105ECh. 7 - Prob. 7.106ECh. 7 - Prob. 7.107ECh. 7 - Prob. 7.108ECh. 7 - Prob. 7.109ECh. 7 - Prob. 7.110ECh. 7 - In a dilute solution of sodium chloride in water,...Ch. 7 - A salt solution has a molarity of 1.5M. How many...Ch. 7 - Prob. 7.113ECh. 7 - Prob. 7.114ECh. 7 - Prob. 7.115ECh. 7 - Prob. 7.116ECh. 7 - Prob. 7.117ECh. 7 - Prob. 7.118ECh. 7 - Prob. 7.119ECh. 7 - Prob. 7.120ECh. 7 - Prob. 7.121ECh. 7 - Prob. 7.122E
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY